Phase Control on Surface for the Stabilization of High Energy Cathode Materials of Lithium Ion Batteries.

The development of high energy electrode materials for lithium ion batteries is challenged by their inherent instabilities, which become more aggravated as the energy densities continue to climb, accordingly causing increasing concerns on battery safety and reliability. Here, taking the high voltage cathode of LiNi0.5Mn1.5O4 as an example, we demonstrate a protocol to stabilize this cathode through a systematic phase modulating on its particle surface. We are able to transfer the spinel surface into a 30 nm shell composed of two functional phases including a rock-salt one and a layered one. The former is electrochemically inert for surface stabilization while the latter is designated to provide necessary electrochemical activity. The precise synthesis control enables us to tune the ratio of these two phases, and achieve an optimized balance between improved stability against structural degradation without sacrificing its capacity. This study highlights the critical importance of well-tailored surface phase property for the cathode stabilization of high energy lithium ion batteries

A practical path planning methodology for wire and arc additive manufacturing of thin-walled structures

This paper presents a novel methodology to generate deposition paths for wire and arc additive manufacturing (WAAM). The medial axis transformation (MAT), which represents the skeleton of a given geometry, is firstly extracted to understand the geometry. Then a deposition path that is based on the MAT is efficiently generated. The resulting MAT-based path is able to entirely fill any given cross-sectional geometry without gaps. With the variation of step-over distance, material efficiency alters accordingly for both solid and thin-walled structures. It is found that thin-walled structures are more sensitive to step-over distance in terms of material efficiency. The optimal step-over distance corresponding to the maximum material efficiency can be achieved for various geometries, allowing the optimization of the deposition parameters. Five case studies of complex models including solid and thin-walled structures are used to test the developed methodology. Experimental comparison between the proposed MAT-based path patterns and the traditional contour path patterns demonstrate significant improved performance in terms of gap-free cross-sections. The proposed path planning strategy is shown to be particularly beneficial for WAAM of thin-walled structures

Advanced Design for Additive Manufacturing: 3D Slicing and 2D Path Planning

Commercial 3D printers have been increasingly implemented in a variety of fields due to their quick production, simplicity of use, and cheap manufacturing. Software installed in these machines allows automatic production of components from computer-aided design (CAD) models with minimal human intervention. However, there are fewer options provided, with a limited range of materials, limited path patterns, and layer thicknesses. For fabricating metal functional parts, such as laser-based, electron beam-based, and arc-welding-based additive manufacturing (AM) machines, usually more careful process design requires in order to obtain components with the desired mechanical and material properties. Therefore, advanced design for additive manufacturing, particularly slicing and path planning, is necessary for AM experts. This chapter introduces recent achievements in slicing and path planning for AM process

Fabricating superior NiAl bronze components through wire arc additive manufacturing

Cast nickel aluminum bronze (NAB) alloy is widely used for large engineering components in marine applications due to its excellent mechanical properties and corrosion resistance. Casting porosity, as well as coarse microstructure, however, are accompanied by a decrease in mechanical properties of cast NAB components. Although heat treatment, friction stir processing, and fusion welding were implemented to eliminate porosity, improve mechanical properties, and refine the microstructure of as-cast metal, their applications are limited to either surface modification or component repair. Instead of traditional casting techniques, this study focuses on developing NAB components using recently expanded wire arc additive manufacturing (WAAM). Consumable welding wire is melted and deposited layer-by-layer on substrates producing near-net shaped NAB components. Additively-manufactured NAB components without post-processing are fully dense, and exhibit fine microstructure, as well as comparable mechanical properties, to as-cast NAB alloy. The effects of heat input from the welding process and post-weld-heat-treatment (PWHT) are shown to give uniform NAB alloys with superior mechanical properties revealing potential marine applications of the WAAM technique in NAB production

Source-Aware Context Network for Single-Channel Multi-speaker Speech Separation

Deep learning based approaches have achieved promising performance in speaker-dependent single-channel multi-speaker speech separation.However, partly due to the label permutation problem, they may encounter difficulties in speaker-independent conditions. Recent methods address this problem by some assignment operations. Different from them, we propose a novel source-aware context network, which explicitly inputs speech sources as well as mixture signal. By exploiting the temporal dependency and continuity of the same source signal, the permutation order of outputs can be easily determined without any additional post-processing. Furthermore, a Multi-time-step Prediction Training strategy is proposed to address the mismatch between training and inference stages. Experimental results on benchmark WSJ0-2mix dataset revealed that our network achieved comparable or better results than state-of-the-art methods in both closed-set and open-set conditions, in terms of Signal-to-Distortion Ratio (SDR) improvement