1,154 research outputs found
Improvement of interation in and properties of PMMA-MWNT nanocomposites through microwave assisted acid treatment of MWNT
Soluble derivatives of multi-walled carbon nanotubes (MWNT) embedded in a poly(methylmethacrylate) (PMMA) matrix forming thick, homogeneous and transparent nanocomposites, were prepared and characterized. A new photo-assisted method using microwaves, to purify the MWNTs from amorphous carbon and synthesis catalyst clusters, was tested in a sulphonitric mix. This method shortened the processing time compared to other methods. Pristine and functionalized MWNTs were introduced into the MMA, then in situ photo-polymerized. Transmission electron microscopy (TEM) and X-ray diffractometry (XRD), as well as Fourier-transform infrared (FTIR), Raman and nuclear magnetic resonance (NMR) spectroscopy were used to monitor the effects of the treatment on the different components. The thermal properties of the composites were determined through differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The short, microwave treated and polyethylene glycol (PEG) functionalized MWNTs showed the best dispersion in and interaction with PMMA, and had the most significant influence on the thermal properties of this polymer
Macro-micro relationship in nanostructured functional composites
This paper examines the results of the characterization of two functional composites: Poly(methyl methacrylate)
(PMMA)-Ce:YAG (yttrium aluminium garnet doped with cerium) and PMMA-cobalt hexacyanoferrate (CoHCF). The
composites were prepared as possible emitters in the fields of lighting thermal sensors. The prepared composites were characterized
using transmission electron microscopy (TEM), nuclear magnetic resonance (NMR) spectroscopy, thermogravimetric
analysis (TGA), differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA) analyses to study
the correlation between micro and macro characteristics. We found that the molecular interactions of the two different
fillers with the matrix were localized in different sites of the polymer chains. Moreover, the composites showed an
increased thermal strength and stiffness, in particular the PMMA-Ce:YAG composite
Granulometria do milho em dietas para suinos nas fases de crescimento e crescimento-terminacao.
bitstream/item/58413/1/CUsersPiazzonDocuments232.pd
Mechanical mode engineering with orthotropic metamaterial membranes
Metamaterials are structures engineered at a small scale with respect to the
wavelength of the excitations they interact with. These structures behave as
artificial materials whose properties can be chosen by design, mocking and even
outperforming natural materials and making them the quintessential tool for
manipulation of wave systems. In this Letter we show how the acoustic
properties of a silicon nitride membrane can be affected by nanopatterning. The
degree of asymmetry in the pattern geometry induces an artificial anisotropic
elasticity, resulting in the splitting of otherwise degenerate mechanical
modes. The artificial material we introduce has a maximum Ledbetter-Migliori
anisotropy of 1.568, favorably comparing to most bulk natural crystals. With an
additional freedom in defining arbitrary asymmetry axes by pattern rotation,
our approach can be useful for fundamental investigation of material properties
as well as for devising improved sensors of light, mass or acceleration based
on micromechanical resonators
High frequency mechanical excitation of a silicon nanostring with piezoelectric aluminum nitride layers
A strong trend for quantum based technologies and applications follows the
avenue of combining different platforms to exploit their complementary
technological and functional advantages. Micro and nano-mechanical devices are
particularly suitable for hybrid integration due to the easiness of fabrication
at multi-scales and their pervasive coupling with electrons and photons. Here,
we report on a nanomechanical technological platform where a silicon chip is
combined with an aluminum nitride layer. Exploiting the AlN piezoelectricity,
Surface Acoustic Waves are injected in the Si layer where the material has been
localy patterned and etched to form a suspended nanostring. Characterizing the
nanostring vertical displacement induced by the SAW, we found an external
excitation peak efficiency in excess of 500 pm/V at 1 GHz mechanical frequency.
Exploiting the long term expertise in silicon photonic and electronic devices
as well as the SAW robustness and versatility, our technological platform
represents a strong candidate for hybrid quantum systems
Granulometria do milho em rações para engorda de suĂnos.
O que e granulometria e como medi-la?; Importância da granulometria do milho para suĂnos; Granulometria e valor energĂ©tico do milho; Granulometria e desempenho de suĂnos; Granulometria e ulcera esĂ´fago-gástrica; Recomendações da granulometria do milho para suĂnos; Cuidados para obtenção de uma boa granulometria.bitstream/item/59505/1/CUsersPiazzonDocuments9.pd
Metamaterial-enabled asymmetric negative refraction of GHz mechanical waves
Known examples of negative refraction in metamaterials do not distinguish between positive and negative angles of incidence. Here, the authors show that it is possible to break this symmetry using an asymmetric unit cell, and demonstrate it using a mechanical metamaterial working at GHz frequencies. Wave refraction at an interface between different materials is a basic yet fundamental phenomenon, transversal to several scientific realms - electromagnetism, gas and fluid acoustics, solid mechanics, and possibly also matter waves. Under specific circumstances, mostly enabled by structuration below the wavelength scale, i.e., through the metamaterial approach, waves undergo negative refraction, eventually enabling superlensing and transformation optics. However, presently known negative refraction systems are symmetric, in that they cannot distinguish between positive and negative angles of incidence. Exploiting a metamaterial with an asymmetric unit cell, we demonstrate that the aforementioned symmetry can be broken, ultimately relying on the specific shape of the Bloch mode isofrequency curves. Our study specialized upon a mechanical metamaterial operating at GHz frequency, which is by itself a building block for advanced technologies such as chip-scale hybrid optomechanical and electromechanical devices. However, the phenomenon is based on general wave theory concepts, and it applies to any frequency and time scale for any kind of linear waves, provided that a suitable shaping of the isofrequency contours is implemented
Nutrição é uma das bases da evolução da avicultura de corte no Brasil.
Projeto: 11.11.11.111
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