10 research outputs found
ΠΠΎΠ΄Π΅Π»ΠΈΡΠΎΠ²Π°Π½ΠΈΠ΅ Π»ΠΎΠ½Π΄ΠΎΠ½ΡΠΊΠΎΠ³ΠΎ ΡΠ΅ΠΊΡΡΠ° Π² ΠΏΠΎΠ²Π΅ΡΡΠΈ Π. Π. ΠΠ°ΠΌΡΡΠΈΠ½Π° "ΠΡΡΡΠΎΠ²ΠΈΡΡΠ½Π΅"
Π‘ΡΠ°ΡΡΡ ΠΏΠΎΡΠ²ΡΡΠ΅Π½Π° Π°Π½Π°Π»ΠΈΠ·Ρ Π»ΠΎΠ½Π΄ΠΎΠ½ΡΠΊΠΎΠ³ΠΎ ΡΠ΅ΠΊΡΡΠ° ΡΡΡΡΠΊΠΎΠΉ ΠΊΡΠ»ΡΡΡΡΡ ΠΏΠ΅ΡΠ²ΠΎΠΉ ΠΏΠΎΠ»ΠΎΠ²ΠΈΠ½Ρ Π₯Π₯ Π². Π½Π° ΠΌΠ°ΡΠ΅ΡΠΈΠ°Π»Π΅ ΠΏΠΎΠ²Π΅ΡΡΠΈ Π. Π. ΠΠ°ΠΌΡΡΠΈΠ½Π° "ΠΡΡΡΠΎΠ²ΠΈΡΡΠ½Π΅". ΠΠΏΠ΅ΡΠ²ΡΠ΅ ΠΎΠ±ΡΠ°Π· Π³ΠΎΡΠΎΠ΄Π° ΡΠ°ΡΡΠΌΠ°ΡΡΠΈΠ²Π°Π΅ΡΡΡ ΡΠΊΠ²ΠΎΠ·Ρ ΠΏΡΠΈΠ·ΠΌΡ ΠΌΠΎΠ΄Π΅ΡΠ½ΠΈΡΡΡΠΊΠΎΠΉ ΠΏΠΎΡΡΠΈΠΊΠΈ. ΠΠΎΠ½Π΄ΠΎΠ½ ΠΊΠ°ΠΊ ΡΠ΅Π½ΡΡ Π½Π°ΡΡΠ½ΠΎΠ³ΠΎ, ΡΠ°ΡΠΈΠΎΠ½Π°Π»ΠΈΡΡΠΈΡΠ΅ΡΠΊΠΎΠ³ΠΎ ΠΌΠ΅ΡΠΎΠ΄Π° ΠΏΠΎΠ·Π½Π°Π½ΠΈΡ ΡΡΠ°Π½ΠΎΠ²ΠΈΡΡΡ Π²ΠΎΠΏΠ»ΠΎΡΠ΅Π½ΠΈΠ΅ΠΌ ΠΈΠ΄Π΅ΠΎΠ»ΠΎΠ³ΠΈΠΈ ΠΌΠΎΠ΄Π΅ΡΠ½ΠΈΠ·ΠΌΠ°. ΠΡΠΎ Π΄Π°Π΅Ρ Π²ΠΎΠ·ΠΌΠΎΠΆΠ½ΠΎΡΡΡ Π³ΠΎΠ²ΠΎΡΠΈΡΡ ΠΎ ΠΌΠ½ΠΎΠ³ΠΎΡΡΠΎΠ²Π½Π΅Π²ΠΎΠΉ ΡΡΡΡΠΊΡΡΡΠ΅ Π²ΠΎΡΠΏΡΠΈΡΡΠΈΡ Π³ΠΎΡΠΎΠ΄Π° Π² ΡΠ°ΠΌΠΊΠ°Ρ
ΡΡΡΡΠΊΠΎΠΉ ΠΌΠ΅Π½ΡΠ°Π»ΡΠ½ΠΎΡΡΠΈ. Π ΡΡΠ°ΡΡΠ΅ ΠΏΠΎΠΊΠ°Π·ΡΠ²Π°Π΅ΡΡΡ, ΠΊΠ°ΠΊ ΠΎΠ±ΡΠ°Π· ΡΡΠΎΠ»ΠΈΡΡ Π·Π°ΠΏΠ°Π΄Π½ΠΎΠΉ ΡΠΈΠ²ΠΈΠ»ΠΈΠ·Π°ΡΠΈΠΈ ΡΡΠ²Π°ΠΈΠ²Π°Π΅ΡΡΡ ΡΡΡΡΠΊΠΈΠΌ ΡΠΎΠ·Π½Π°Π½ΠΈΠ΅ΠΌ ΠΈ Π²ΠΊΠ»ΡΡΠ°Π΅ΡΡΡ Π² ΠΎΠ±ΡΠ΅ΡΡΡΡΠΊΠΈΠΉ Π»ΠΈΡΠ΅ΡΠ°ΡΡΡΠ½ΡΠΉ ΠΈ ΠΊΡΠ»ΡΡΡΡΠ½ΡΠΉ ΠΊΠΎΠ½ΡΠ΅ΠΊΡΡ
Natural gum-assisted phthalocyanine immobilization in electroactive nanocomposites: Physicochemical characterization and sensing applications
Natural gums have been traditionally applied in cosmetics and the food industry, mainly as emulsification agents. Due to their biodegradability and excellent mechanical properties, new technological applications have been proposed involving their use with conventional polymers forming blends and composites. In this study, we take advantage of the polyelectrolyte character exhibited by the natural gum Chicha (Sterculia striata), extracted in the Northeastern region of Brazil, to produce electroactive nanocomposites. The nanocomposites were fabricated in the form of ultrathin films by combining a metallic phthalocyanine (nickel tetrasulfonated phthalocyanine, NiTsPc) and the Chicha gum in a tetralayer architecture, in conjunction with conventional polyelectrolytes. The presence of the gum led to an efficient adsorption of the phthalocyanine and enhanced the electrochemical response of the films. Upon combining the electrochemical and UV-vis absorption data, energy diagrams of the Chicha/NiTsPc-based system were obtained. Furthermore, modified electrodes based on gum/phthalocyanine films were able to detect dopamine at concentrations as low as 10(-5) M