MasterChem: Cooking 2D-polymers

2D-polymers are still dominated by graphene and closely related materials such as boron nitride, transition metal sulphides and oxides. However, the rational combination of molecules with suitable design is already showing the high potential of chemistry in this new research field. The aim of this feature article is to illustrate, and provide some perspectives, the current state-of-the-art in the field of synthetic 2D-polymers showing different alternatives to prepare this novel type of polymers based on the rational use of chemistry. This review comprises a brief revision of the essential concepts, the strategies of preparation following the two general approaches, bottom-up and top-down, and a revision of the promising seminal properties showed by some of these nanomaterials.Financial support from Spanish MINECO (MAT2013-46753-C2-1-P and MAT2013-46502-C2-2-P). D. R. thanks the Spanish MECD for a FPU gran

Circumstellar effects on the Rb abundances in O-rich AGB stars

For the first time we explore the circumstellar effects on the Rb (and Zr) abundance determination in O-rich asymptotic giant branch (AGB) stars by considering the presence of a gaseous circumstellar envelope with a radial wind. A modified version of the spectral synthesis code Turbospectrum was used to deal with extended atmosphere models and velocity fields. The Rb and Zr abundances were determined from the resonant 7800A Rb I line and the 6474A ZrO bandhead, respectively, in five representative O-rich AGB stars with different expansion velocity and metallicity. By using our new dynamical models, the Rb I line profile (photospheric and circumstellar components) is very well reproduced. Interestingly, the derived Rb abundances are much lower (by 1-2 dex) in those O-rich AGB stars showing the higher circumstellar expansion velocities. The Zr abundances, however, remain close to the solar values. The Rb abundances and Rb/Zr ratios derived here significantly alleviate the problem of the present mismatch between the observations of intermediate-mass (4-8 solar masses) Rb-rich AGB stars and the AGB nucleosynthesis theoretical predictions.Comment: Accepted for publication in Astronomy & Astrophysics Letters (7 pages, 5 figures, and 2 tables); final version (language corrected

Population Ecology and Reproductive Biology of The Diamondback Watersnake, Nerodia Rhombifer (Serpentes: Colubridae), in Southernmost Texas

Nerodia rhombifer is a polytypic, semi-aquatic snake with a broad geographical distribution ranging from the American Midwest southward to Chiapas, Mexico. Although relatively abundant throughout much of its range, few ecological studies of the species have been conducted. This study provides basic population ecology information in a subtropical habitat. Population data were obtained in a mark-recapture study at Santa Ana National Wildlife Refuge, Hidalgo County, Texas, from August 1995 to December 1998. Specimens taken elsewhere in Hidalgo County provided information on the reproductive biology. This study provides the first absolute density estimates from anywhere within the species’ range. Quantitative information on seasonal activity, growth rates, size dimorphism, population structure, reproductive cycles, and lipid dynamics are presented

A first order Tsallis theory

We investigate first-order approximations to both i) Tsallis' entropy $S_q$ and ii) the $S_q$-MaxEnt solution (called q-exponential functions $e_q$). It is shown that the functions arising from the procedure ii) are the MaxEnt solutions to the entropy emerging from i). The present treatment is free of the poles that, for classic quadratic Hamiltonians, appear in Tsallis' approach, as demonstrated in [Europhysics Letters {\bf 104}, (2013), 60003]. Additionally, we show that our treatment is compatible with extant date on the ozone layer.Comment: 4 figures adde

A GIT interpretration of the Harder-Narasimhan filtration

An unstable torsion free sheaf on a smooth projective variety gives a GIT unstable point in certain Quot scheme. To a GIT unstable point, Kempf associates a "maximally destabilizing" 1-parameter subgroup, and this induces a filtration of the torsion free sheaf. We show that this filtration coincides with the Harder-Narasimhan filtration.Comment: 19 pages; Comments of the referees and references added. The construction for holomorphic pairs (Sections 6 and 7 from previous version) will appear in a further publication. To appear in Rev. Mat Complutens