1,497 research outputs found

    Enhanced hydrogen sensing properties of graphene by introducing a mono-atom-vacancy

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    To facilitate the dissociative adsorption of H2 molecules on pristine graphene, the addition of a mono-atom-vacancy to graphene is proposed. This leads to reduction of the dissociative energy barrier for a H2 molecule on graphene from 3.097 to 0.805 eV for the first H2 and 0.869 eV for the second, according to first principles calculations. As a result, two H2 molecules can be easily dissociatively adsorbed on this defected graphene at room temperature. The electronic structure and conductivity of the graphene change significantly after H2 adsorption. In addition, the related dissociative adsorption phase diagrams under different temperatures and partial pressures show that this dissociative adsorption at room temperature is very sensitive (10-35 mol L -1). Therefore, this defected graphene is promising for ultra-sensitive room temperature hydrogen sensing. © 2013 the Owner Societies

    Coherent quantum transport in ferromagnet/superconductor/ferromagnet structures

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    The Blonder-Tinkham-Klapwijk (BTK) approach is extended to study coherent quantum transport in ferromagnet/superconductor/ferromagnet (FM/SC/SM) double tunnel junctions. In order to guarantee current conservation it is necessary to simultaneously consider spin-polarized electron currents along one direction and spin-polarized hole currents along the opposite direction, and to determine self-consistently the chemical potential in SC. It is found that all the reflection and transmission coefficients'in BTK theory as well as conductance spectra oscillate with energy, exhibiting different behavior in the metallic and tunnel limits.published_or_final_versio

    Genome Sequence of Erythromelalgia-Related Poxvirus Identifies it as an Ectromelia Virus Strain

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    Erythromelagia is a condition characterized by attacks of burning pain and inflammation in the extremeties. An epidemic form of this syndrome occurs in secondary students in rural China and a virus referred to as erythromelalgia-associated poxvirus (ERPV) was reported to have been recovered from throat swabs in 1987. Studies performed at the time suggested that ERPV belongs to the orthopoxvirus genus and has similarities with ectromelia virus, the causative agent of mousepox. We have determined the complete genome sequence of ERPV and demonstrated that it has 99.8% identity to the Naval strain of ectromelia virus and a slighly lower identity to the Moscow strain. Small DNA deletions in the Naval genome that are absent from ERPV may suggest that the sequenced strain of Naval was not the immediate progenitor of ERPV

    Inhibitory mechanism of 3-hydroxypropionaldehyde accumulation in 1,3-propanediol synthesis with Klebsiella pneumoniae

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    3-Hydroxypropionaldehyde accumulation may cause the cessation of 1,3-propanediol sustained production with glycerol by Klebsiella pneumoniae. The impeller tip speed shift from higher to lower speed at glycerol excess or the pulsed glycerol feeding could lead to an abrupt increase of the 3- hydroxypropionaldehyde concentration (up to 10 mmol/l) in 10 min. The intracellular consequence of the 3-hydroxypropionaldehyde accumulation has not yet been elucidated. The rapid accumulation of 3- hydroxypropionaldehyde relying on the impeller tip speed shift was employed to investigate the influences of 3-hydroxypropionaldehyde to the activities of nine key enzymes related to glycerol metabolism, CO2 and O2 levels in off-gas, cell growth and 1,3-propanediol synthesis. Compared with that at 1.19 mmol/l 3-hydroxypropionaldehyde in broth, the residual enzymatic activities of the nine key enzymes ranged from 9.44 to 74.68% in the cultures at 7.5 mmol/l 3-hydroxypropionaldehyde in broth. The inhibitions of cell growth and the 1,3-propanediol synthesis were unnoticeable at the low level of 3- hydroxypropionaldehyde. By contrast, the CO2 and O2 levels changes in off-gas response to the 3- hydroxypropionaldehyde accumulation were less than 15 min. These results suggest that 3- hydroxypropionaldehyde inhibited the growth and metabolism of K. pneumoniae in a more complicated manner.Keywords: Fermentation, glycerol, 3-hydroxypropionaldehyde, Klebsiella pneumoniae, 1,3-propanediol

    Adopting Team-Based Learning for In-Service Teachers: A Case Study

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    Team-based learning (TBL) is an instructional pedagogy that has gained recent popularity due to its effectiveness in disciplines such as medicine and business. However, TBL has not been widely adopted in teacher education based on reviews of research and practitioner based literature. The purpose of this case study was to assess the implementation and effectiveness of TBL in a Singapore teaching institute with thirty in-service teachers. Quantitative and qualitative data was collected from teachers about their experience learning through TBL. Research findings revealed that 1) teachers generally perceived TBL to be a positive experience, although several areas for improvement were suggested; 2) quality of scores through TBL was high, with team scores being significantly higher than individual scores. The findings from this study have the potential to guide the design of future TBL courses in education

    Ultrasound palpation sensor for tissue thickness and elasticity measurement - assessment of transverse carpal ligament

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    Author name used in this publication: Y. P. ZhengAuthor name used in this publication: A. P. C. ChoiAuthor name used in this publication: M. H. LuAuthor name used in this publication: X. ChenAuthor name used in this publication: Q. H. Huang2006-2007 > Academic research: refereed > Publication in refereed journalAccepted ManuscriptPublishe

    An implementation of ultrasonic tissue elastography in a conventional ultrasound scanner

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    2010-2011 > Academic research: refereed > Publication in refereed journalVersion of RecordPublishe

    Meta-analysis of scalp acupuncture for acute hypertensive intracerebral hemorrhage

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    Objectives: Scalp acupuncture (SA) is a commonly used therapeutic approach for primary intracerebral hemorrhage (ICH) in Traditional Chinese Medicine (TCM), but the efficacy and safety of SA therapy are still undetermined. The aim of this study is to systematically evaluate the efficacy and safety of SA therapy for the treatment of acute hypertensive ICH. Methods: Literature reports with randomized controlled clinical trials and controlled clinical trials on SA therapy for acute hypertensive ICH were searched, and the efficacy and safety of SA therapy were evaluated by using the Cochrane systematic review methods. The primary outcome measures were death or dependency at the end of long-term follow-up (at least 3 months) and adverse events. The secondary outcome measure was neurological deficit improvement at the end of the treatment course. Results: Seven (7) independent trials (230 patients) were included in this study. All trials described the methods of randomization in which four trials had adequate concealment of randomization at the level of grade A, but no trial included sham acupuncture as a control group. None of the trials included "death or dependency" as a primary outcome measure. Four (4) trials contained safety assessments and stated that no adverse event was found, whereas the other three trials did not provide the information about adverse events. By using random effects statistical model, it was found that patients with acute hypertensive ICH who received SA therapy had significantly improved neurological deficit scores (Z=4.97, p<0.01). Conclusions: Although SA therapy is widely used to treat acute hypertensive ICH in TCM, the efficacy and safety of SA therapy remain to be further determined. No evidence is available on whether SA therapy can be used to treat acute ICH according to the primary outcome measure. However, SA therapy appears to be able to improve neurological deficit in patients with acute hypertensive ICH. © 2011, Mary Ann Liebert, Inc.published_or_final_versio

    Graph attention neural network for water network partitioning

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    Partitioning a water distribution network into several district metered areas is beneficial for its management. Partitioning a network according to its node features and connections remains a challenge. A recent study has realized water network partitioning based on node features or pipe connections individually. This study proposes an unsupervised clustering method for nodes based on a graph neural network, which uses graph attention technology to update node features based on the connections and a neural network to cluster nodes. The similarity between nodes located in each area and the balance of the total water demand between areas are optimized, and the importance of the boundary pipes is calculated to determine the installation position of flowmeters and valves. Three water distribution networks with different structures and sizes are used to verify the proposed model. The results show that the average location differences (LocDiffs) within the areas of the three networks completed by partitioning are 0.12, 0.07, and 0.06, and the total demand differences (DemDiffs) between areas are 0.13, 0.27, and 0.29, respectively. The LocDiff and DemDiff of the proposed method decreased by 6% and 55%, respectively, when compared to the traditional clustering method. Additionally, the proposed method for calculating the importance of boundaries provides an objective basis for boundary closure. When the same number of boundaries are closed, the comprehensive impact of the proposed method on the pipe network decreases by 17.1%. The proposed method can be used in practical applications because it ensures a highly reliable and interpretive water distribution network partitioning method
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