Effect of activated alloys on hydrogen discharge kinetics of MgH2 nanocrystals

This is the post-print version of the final paper published in Journal of Alloys and Compounds. The published article is available from the link below. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. Copyright @ 2007 Elsevier B.V.Activated alloys synthesized by arc-melting were examined as catalysts for improving the hydrogen sorption characteristics of nanostructured magnesium hydride, proposed as a reversible hydrogen storage material. The MgH2-catalyst absorbing materials were prepared by ball milling of pure MgH2 with hydrided Zr47Ni53, Zr9Ni11, and other investigated alloys. The nanostructured MgH2-intermetallic systems were tested at 250 °C and catalyst addition of eutectoid Zr47Ni53 resulted in the fastest desorption time and highest initial desorption rate. Also, the catalyzed Mg-hydride with activated Zr9Ni11 and Zr7Ni10 phases showed fast desorption kinetics. Moreover, the results demonstrated that the composition of dispersed ZrxNiy catalysts has a strong influence on the amount of accumulated hydrogen and desorption rate of Mg-nanocomposite.National Research Council Canad

Experimental study on a metal hydride based hydrogen compressor

This is the post-print version of the final paper published in Journal of Alloys and Compounds. The published article is available from the link below. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. Copyright @ 2008 Elsevier B.V.A three-stage metal hydride based hydrogen compressor prototype was built. It has been designed for a hydrogen production facility using a low-pressure alkaline electrolyser. The compression system should transfer heat recovered from the electrolyser into the hydride beds to allow hydrogen desorption flow. The three-stage compressor achieves a compression ratio of 20:1 atm. It performs a thermal cycling of three AB5 hydrides between 20 and 80 °C. Its flow rate, for 25 g of each hydride bed, reaches about 20 l (NTP) of hydrogen per hour. The prototype is now operational. Some improvements in the heat transfer management system are also carried out before proceeding to the interconnection with the electrolyser and to the extent that the hydrogen produced satisfies the high purity requirement of the hydrides used in the compressor.Natural Resources Canada(NRCan), Ministère des Ressources Naturelles et de la Faune du Québec (MRNF), and Natural Sciences and Engineering Research Council of Canada

Photovoltaic cells energy performance enhancement with down-converting photoluminescence phosphors

Phosphors, synthesized by the urea homo-precipitation method, were examined as ultraviolet-spectral down conversion materials for improving the light absorption and electrical characteristics of commercial single-junction silicon solar cells. The photovoltaic (PV) cells were coated with erbium and terbium doped gadolinium oxysulfide phosphors encapsulated in ethyl vinyl-acetate binder using blade screen printing technique, and the optimum concentration of phosphor in the composite resulted in the largest light conversion, and superior electrical output and energy transfer efficiency. Moreover, the results demonstrated that the composition of dispersed phosphors has a strong influence on the amount of ultraviolet-light converted and electron transition capacity of PV cells. The experimental results showed in an optimized PV cell, an enhancement of 0.54% (from 12.11% to 12.65%) in the energy conversion of a Si-based PV cell was achieved.Mr. Ben Parker of LOT-QuantumDesig

Optimal Design and Analysis of a Hybrid Hydrogen Energy Storage System for an Island-Based Renewable Energy Community

Data Availability Statement: Data will be made available on request.Copyright © 2023 by the authors. Installations of decentralised renewable energy systems (RES) are becoming increasing popular as governments introduce ambitious energy policies to curb emissions and slow surging energy costs. This work presents a novel model for optimal sizing for a decentralised renewable generation and hybrid storage system to create a renewable energy community (REC), developed in Python. The model implements photovoltaic (PV) solar and wind turbines combined with a hybrid battery and regenerative hydrogen fuel cell (RHFC). The electrical service demand was derived using real usage data from a rural island case study location. Cost remuneration was managed with an REC virtual trading layer, ensuring fair distribution among actors in accordance with the European RED(III) policy. A multi-objective genetic algorithm (GA) stochastically determines the system capacities such that the inherent trade-off relationship between project cost and decarbonisation can be observed. The optimal design resulted in a levelized cost of electricity (LCOE) of 0.15 EUR/kWh, reducing costs by over 50% compared with typical EU grid power, with a project internal rate of return (IRR) of 10.8%, simple return of 9.6%/year, and return on investment (ROI) of 9 years. The emissions output from grid-only use was reduced by 72% to 69 gCO2e/kWh. Further research of lifetime economics and additional revenue streams in combination with this work could provide a useful tool for users to quickly design and prototype future decentralised REC systems.This research is sponsored by the EU Horizon 2020 research and innovation program under the grant agreement No 957852: Virtual Power Plant for Interoperable and Smart isLANDS—VPP4ISLANDS. More information is available at https://cordis.europa.eu/project/id/957852 (accessed on 30 August 2023)

A comparative analysis of the effectiveness of aquifer thermal energy storage in Expeditionary Campaign Infrastructure

A comparative study was undertaken to predict the energy savings associated with the employment of aquifer thermal energy storage in combination with a commercial water to air heat pump when used in Expeditionary Campaign Infrastructure against the climatic demands of Helmand Province, Afghanistan. Energy usage was predicted using EnergyPlus and the thermal response of the aquifer modelled using Processing SHEMAT based on predicted energy usage. The resulting analysis suggests a 22% reduction in fuel usage against an existing air to air heat pump with a CO2 reduction of 39 tonnes per annum. Although thermal stability of the aquifer could not be ensured without mitigation measures being undertaken, financially the analysis predicts a £335,000 per annum fuel saving assuming that the fully burdened cost of fuel is $11.98 per litre thus offering a payback period of less than 2 years operation

Effective MgO‐doped TiO2 nanoaerogel coating for crystalline silicon solar cells improvement

This study looks at investigating the influence of high surface area TiO2 and MgO‐doped TiO2 aerogel nanomaterials to improve the photovoltaic performance of monocrystalline silicon (mono‐Si) solar cells. TiO2 and MgO‐doped TiO2 anatase nanoaerogels were synthesized via a single‐step colloidal homogeneous precipitation sol‐gel method in a compact high‐pressure hydrogen reactor. TiO2‐based nanoparticles were encapsulated in ethylene vinyl acetate resins, and the obtained composite solutions were screen printed on the textured surface of the cells. The specific surface area, microstructural, composition, and optical properties of the nanoaerogels were characterized by Brunaur‐Emmett‐Teller, X‐ray powder diffractometer, energy‐dispersive X‐ray spectroscopy, field emission transmission electron microscope, field emission scanning electron microscope, and ultraviolet‐visible spectrophotometry. We observed that the MgO‐doped TiO2 (2% mol) nanoaerogel exhibited a much superior specific surface area (231 m2/g) compared with the undoped TiO2 (154 m2/g). Experimental results showed that the calculated relative power conversion efficiency increased by 4.6% for the MgO‐doped TiO2 coating and 3.4% for the undoped TiO2 under a simulated one‐sun illumination

Microbial electrolysis cells for decentralisedwastewater treatment: The next steps

Traditional wastewater treatment methods have become aged and inefficient, meaning alternative methods are essential to protect the environment and ensure water and energy security worldwide. The use of microbial electrolysis cells (MEC) for wastewater treatment provides an innovative alternative, working towards circular wastewater treatment for energy production. This study evaluates the factors hindering industrial adoption of this technology and proposes the next steps for further research and development. Existing pilot-scale investigations are studied to critically assess the main limitations, focusing on the electrode material, feedstock, system design and inoculation and what steps need to be taken for industrial adoption of the technology. It was found that high strength influents lead to an increase in energy production, improving economic viability; however, large variations in waste streams indicated that a homogenous solution to wastewater treatment is unlikely with changes to the MEC system specific to different waste streams. The current capital cost of implementing MECs is high and reducing the cost of the electrodes should be a priority. Previous pilot-scale studies have predominantly used carbon-based materials. Significant reductions in relative performance are observed when electrodes increase in size. Inoculation time was found to be a significant barrier to quick operational performance. Economic analysis of the technology indicated that MECs offer an attractive option for wastewater treatment, namely greater energy production and improved treatment efficiency. However, a significant reduction in capital cost is necessary to make this economically viable. MEC based systems should offer improvements in system reliability, reduced downtime, improved treatment rates and improved energy return. Discussion of the merits of H2 or CH4 production indicates that an initial focus on methane production could provide a stepping-stone in the adoption of this technology while the hydrogen market matures.Engineering and Physical Sciences Research Council; London South Bank University and the European Regional Development Fun

Optical properties of MgH2 measured in situ in a novel gas cell for ellipsometry/spectrophotometry

The dielectric properties of alpha-MgH2 are investigated in the photon energy range between 1 and 6.5 eV. For this purpose, a novel sample configuration and experimental setup are developed that allow both optical transmission and ellipsometric measurements of a transparent thin film in equilibrium with hydrogen. We show that alpha-MgH2 is a transparent, colour neutral insulator with a band gap of 5.6 +/- 0.1 eV. It has an intrinsic transparency of about 80% over the whole visible spectrum. The dielectric function found in this work confirms very recent band structure calculations using the GW approximation by Alford and Chou [J.A. Alford and M.Y. Chou (unpublished)]. As Pd is used as a cap layer we report also the optical properties of PdHx thin films.Comment: REVTeX4, 15 pages, 12 figures, 5 table

Application of transcritical CO<inf>2</inf> heat pumps to boiler replacement in low impact refurbishment projects

Data availability: The principal results data can be found at https://www.dropbox.com/scl/fo/9lssdybg6tdik8y4knxd0/h?rlkey=j35o9cym4z6vfkalhu3rmrp6z&dl=0. The models, simulation data inputs and outputs can also be made available. Multiple model runs were used to generate the data at both sub-system and system level. Explanations can be provided to ensure the most appropriate data is provided. To obtain further data please contact the first mentioned author.80% of current UK housing stock is expected to still be in use in 2050. Difficult, intrusive and expensive, refurbishment measures are required to achieve the level of insulation required for current low temperature heat pumps. Transcritical CO2 heat pumps can achieve higher efficiencies, with higher output temperatures, than current, Carnot limited, synthetic gas heat pumps, with less environmental impact. Widely deployed in water heating and supermarket chilling systems, CO2 heat pumps need heating return temperatures of 30 °C or less to function effectively. This has impeded their adoption with hydronic heating systems which have high return temperatures. This study identified system modifications external to the refrigeration cycle that address return temperatures. It modelled a transcritical CO2 air source heat pump with a hydronic heating system in a solid wall semi-detached house. Full year system coefficients of performance over 3 were achieved in four UK locations by using space heating return fluids to defrost the air source heat exchanger and to pre-heat inlet water, recovering any remaining excess return fluid heat as a source for the heat pump. Solar panels boosted this to 5.1. The levelized cost of energy for the system was calculated (with heat pump grant) at 22p/kWh, lower than a gas boiler, with 9.45 tonnes CO2 emission savings over a fifteen-year life