Catalytic role of vacancy diffusion in ceria supported atomic gold catalyst

Dynamics of intrinsic defects are considered fundamental in the chemistry of reducible oxides, and their effect on catalytic reactions have been rarely reported. Herein, we propose a new Ov diffusion assisted Langmuir–Hinshelwood mechanism for CO oxidation, which may largely account for the origin of high reactivity of supported atomic gold catalysts

Efecto del estrés producido por la mezcla de sales en la concentración de aldehído malónico, proteínas y enzimas antioxidantes de Leymus chinensis de tres colores foliares diferentes

The mixed salt stress is common in nature. Salt stressalways affects plant growth. Different plant species have different adaptive capacity to salty soil. Leymus chinensis is an herbaceous plant with different leaf colors. However, little research was conducted to explore the different tolerance mechanisms to salt stress among the three different leaf colour genotypes of Leymus chinensis (grey green, transitional color, yellow green). Pot experiments for Leymus chinensis in three leaf colors were conducted under mixed salt treatments in 2010. Malondialdehyde (MDA) and protein concentrations, and the activity of various antioxidant enzymes [i.e., superoxide dismutase (SOD), catalase (CAT), ascorbate peroxidase (APX), glutathione reductase (GR), dehydroascorbate reductase (DHAR) and monodehydroascorbate reductase (MDHAR)] were determined and compared among the three leaf color genotypes of Leymus chinensis. The concentrations of MDA and protein, and the activity of antioxidant enzymes showed an increasing trend with increasing pHs in almost all three leaf colors, and all of them became highest when salt stress and pH values were also highest. Moreover, antioxidant enzymes were the highest in the grey-green leaf color, and the lowest in the yellow green leaf color after exposure to the same pH treatment. The results suggested that all three leaf colors of Leymus chinensis were tolerant to salt stress, and the salt-tolerance declined according to the order of grey green > transitional color > yellow green of Leymus chinensis. This study can give us a better understanding of the intra-species adaptation to mixed salt soils.El estrés causado por mezcla de sales en el suelo es común en la naturaleza. El estrés salino siempre afecta el crecimiento de las plantas. Plantas de especies diferentes difieren en su capacidad de adaptación al estrés por sales en el suelo. Leymus chinensis es una planta herbácea con diferentes colores foliares. Sin embargo, se han conducido pocos estudios tendientes a determinar los diferentes mecanismos de tolerancia al estrés salino entre los tres genotipos de color foliar diferente de L. chinensis (grisáceo verdoso, color intermedio, amarillo verdoso). En 2010, se condujeron experimentos en macetas usando genotipos de L. chinensis de tres colores diferentes de hoja expuestos o no a tratamientos conteniendo una mezcla de sales. Las concentraciones de aldehído malónico (MDA) y proteínas, y la actividad de varias enzimas antioxidantes [es decir, la superóxido dismutasa (SOD), catalasa (CAT), ascórbico peroxidasa (APX), glutatión reductasa (GR), dehidroascórbico reductasa (DHAR) y monodehidroascórbico reductasa (MDHAR)] se determinaron y compararon entre los tres genotipos de color foliar diferente de L. chinensis. Las concentraciones de MDA y proteínas, y la actividad de enzimas antioxidantes mostraron una tendencia a incrementarse a mayores pHs en casi todos los colores foliares, y las tendencias en los tres colores foliares alcanzaron su punto máximo cuando el estrés salino y los valores de pH fueron máximos. Más aún, las concentraciones de las enzimas antioxidantes fueron las más altas en el color grisáceo verdoso, intermedias en el color intermedio, y las más bajas en el color amarillo verdoso después de la exposición al mismo tratamiento de pH. Los resultados sugirieron que los genotipos de los tres colores foliares de L. chinensis fueros tolerantes al estrés salino, y la tolerancia a la sal declinó de acuerdo al orden grisáceo verdoso > color intermedio > amarillo verdoso de L. chinensis. Este estudio puede proveer un mejor entendimiento de la adaptación intraespecífica de L. chinensis a suelos salinos.Fil: Zhou, C.. Chinese Academy of Science; China. Liaoning University; ChinaFil: Busso, Carlos Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Centro de Recursos Naturales Renovables de la Zona Semiárida. Universidad Nacional del Sur. Centro de Recursos Naturales Renovables de la Zona Semiárida; Argentina. Universidad Nacional del Sur. Departamento de Agronomía; ArgentinaFil: Yang, Y. G.. Liaoning University; ChinaFil: Zhang, Z.. Shenyang University; ChinaFil: Wang, Z. W.. Chinese Academy of Science; ChinaFil: Yang, Y. F.. Northeast Normal University; ChinaFil: Han, X. G.. Chinese Academy of Science; Chin

On the Impact of Entity Linking in Microblog Real-Time Filtering

Microblogging is a model of content sharing in which the temporal locality of posts with respect to important events, either of foreseeable or unforeseeable nature, makes applica- tions of real-time filtering of great practical interest. We propose the use of Entity Linking (EL) in order to improve the retrieval effectiveness, by enriching the representation of microblog posts and filtering queries. EL is the process of recognizing in an unstructured text the mention of relevant entities described in a knowledge base. EL of short pieces of text is a difficult task, but it is also a scenario in which the information EL adds to the text can have a substantial impact on the retrieval process. We implement a start-of-the-art filtering method, based on the best systems from the TREC Microblog track realtime adhoc retrieval and filtering tasks , and extend it with a Wikipedia-based EL method. Results show that the use of EL significantly improves over non-EL based versions of the filtering methods.Comment: 6 pages, 1 figure, 1 table. SAC 2015, Salamanca, Spain - April 13 - 17, 201

Ferrimagnetic spin-1/2 chain of alternating Ising and Heisenberg spins in arbitrarily oriented magnetic field

The ferrimagnetic spin-1/2 chain composed of alternating Ising and Heisenberg spins in an arbitrarily oriented magnetic field is exactly solved using the spin-rotation transformation and the transfer-matrix method. It is shown that the low-temperature magnetization process depends basically on a spatial orientation of the magnetic field. A sharp stepwise magnetization curve with a marked intermediate plateau, which emerges for the magnetic field applied along the easy-axis direction of the Ising spins, becomes smoother and the intermediate plateau shrinks if the external field is tilted from the easy-axis direction. The magnetization curve of a polycrystalline system is also calculated by performing powder averaging of the derived magnetization formula. The proposed spin-chain model brings an insight into high-field magnetization data of 3d-4f bimetallic polymeric compound Dy(NO_3)(DMSO)_2Cu(opba)(DMSO)_2, which provides an interesting experimental realization of the ferrimagnetic chain composed of two different but regularly alternating spin-1/2 magnetic ions Dy^{3+} and Cu^{2+} that are reasonably approximated by the notion of Ising and Heisenberg spins, respectively.Comment: 11 pages, 6 figure