10,740 research outputs found
Comparison of Material Properties and Microstructure of Specimens Built Using the 3D Systems Vanguard HS and Vanguard HiQ+HSSLS Systems
The HiQ upgrade to the 3D Systems Vanguard selective laser sintering (SLS) machine incorporates a revised thermal calibration system and new control software. The paper compares
the tensile modulus, tensile strength, elongation at break, flexural modulus, Izod impact resistance and microstructure of two batteries of standard specimens built from recycled Duraform
PA (Nylon 12). The first set is built on a Vanguard HS system and the second on the same
system with the HiQ upgrade installed. The upgrade reduces user intervention, decreases total build time and improves surface finish. However, using the default processing parameters,
tensile, flexure and impact properties are all found to decline after the upgrade is installed.Mechanical Engineerin
Time-dependent perturbation theory for vibrational energy relaxation and dephasing in peptides and proteins
Without invoking the Markov approximation, we derive formulas for vibrational
energy relaxation (VER) and dephasing for an anharmonic system oscillator using
a time-dependent perturbation theory. The system-bath Hamiltonian contains more
than the third order coupling terms since we take a normal mode picture as a
zeroth order approximation. When we invoke the Markov approximation, our theory
reduces to the Maradudin-Fein formula which is used to describe VER properties
of glass and proteins. When the system anharmonicity and the renormalization
effect due to the environment vanishes, our formulas reduce to those derived by
Mikami and Okazaki invoking the path-integral influence functional method [J.
Chem. Phys. 121 (2004) 10052]. We apply our formulas to VER of the amide I mode
of a small amino-acide like molecule, N-methylacetamide, in heavy water.Comment: 16 pages, 5 figures, 5 tables, submitted to J. Chem. Phy
Acoustically evoked potentials in two cephalopods inferred using the auditory brainstem response (ABR) approach
It is still a matter of debate whether cephalopods can detect sound frequencies above 400 Hz. So far there is no proof for the detection of underwater sound above 400 Hz via a physiological approach. The controversy of whether cephalopods have a sound detection ability above 400 Hz was tested using the auditory brainstem response (ABR) approach, which has been successfully applied in fish, crustaceans, amphibians, reptiles and birds. Using ABR we found that auditory evoked potentials can be obtained in the frequency range 400 to 1500 Hz (Sepiotheutis lessoniana) and 400 to 1000 Hz (Octopus vulgaris), respectively. The thresholds of S. lessoniana were generally lower than those of O. vulgaris
Influence of oxygen vacancy on the electronic structure of HfO film
We investigated the unoccupied part of the electronic structure of the
oxygen-deficient hafnium oxide (HfO) using soft x-ray absorption
spectroscopy at O and Hf edges. Band-tail states beneath the
unoccupied Hf 5 band are observed in the O -edge spectra; combined with
ultraviolet photoemission spectrum, this indicates the non-negligible
occupation of Hf 5 state. However, Hf -edge magnetic circular dichroism
spectrum reveals the absence of a long-range ferromagnetic spin order in the
oxide. Thus the small amount of electron gained by the vacancy formation
does not show inter-site correlation, contrary to a recent report [M.
Venkatesan {\it et al.}, Nature {\bf 430}, 630 (2004)].Comment: 5 pages, 4 figures, submitted to Phys. Rev.
Path integrals and symmetry breaking for optimal control theory
This paper considers linear-quadratic control of a non-linear dynamical
system subject to arbitrary cost. I show that for this class of stochastic
control problems the non-linear Hamilton-Jacobi-Bellman equation can be
transformed into a linear equation. The transformation is similar to the
transformation used to relate the classical Hamilton-Jacobi equation to the
Schr\"odinger equation. As a result of the linearity, the usual backward
computation can be replaced by a forward diffusion process, that can be
computed by stochastic integration or by the evaluation of a path integral. It
is shown, how in the deterministic limit the PMP formalism is recovered. The
significance of the path integral approach is that it forms the basis for a
number of efficient computational methods, such as MC sampling, the Laplace
approximation and the variational approximation. We show the effectiveness of
the first two methods in number of examples. Examples are given that show the
qualitative difference between stochastic and deterministic control and the
occurrence of symmetry breaking as a function of the noise.Comment: 21 pages, 6 figures, submitted to JSTA
Scaling for Interfacial Tensions near Critical Endpoints
Parametric scaling representations are obtained and studied for the
asymptotic behavior of interfacial tensions in the \textit{full} neighborhood
of a fluid (or Ising-type) critical endpoint, i.e., as a function \textit{both}
of temperature \textit{and} of density/order parameter \textit{or} chemical
potential/ordering field. Accurate \textit{nonclassical critical exponents} and
reliable estimates for the \textit{universal amplitude ratios} are included
naturally on the basis of the ``extended de Gennes-Fisher'' local-functional
theory. Serious defects in previous scaling treatments are rectified and
complete wetting behavior is represented; however, quantitatively small, but
unphysical residual nonanalyticities on the wetting side of the critical
isotherm are smoothed out ``manually.'' Comparisons with the limited available
observations are presented elsewhere but the theory invites new, searching
experiments and simulations, e.g., for the vapor-liquid interfacial tension on
the two sides of the critical endpoint isotherm for which an amplitude ratio
is predicted.Comment: 42 pages, 6 figures, to appear in Physical Review
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Flame Retardant Intumescent Polyamide 11 Nanocomposites – Further Study
The objective of this research is to develop improved polyamide 11 and 12 polymers with
enhanced flame retardancy, thermal, and mechanical properties for selective laser sintering
(SLS) rapid manufacturing (RM). In the present study, a nanophase was introduced into the
polyamide 11 and combine with a conventional intumescent flame retardant (FR) additive via
twin screw extrusion. Arkema Rilsan® polyamide 11 molding polymer pellets were used with
two types of nanoparticles such as: chemically modified montmorillonite (MMT) organoclays
and carbon nanofibers (CNFs). Two types of Clariant’s Exolit® OP 1311 and 1312 intumescent
FR additives were used to generate a family of FR intumescent polyamide 11 nanocomposites
with anticipated synergism.Mechanical Engineerin
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Intumescent Flame Retardant Polyamide 11 Nanocomposites
Current polyamide 11 and 12 are lacking in fire retardancy and high strength/high heat
resistance characteristics for a plethora of fabricated parts that are desired and required
for performance driven applications. The introduction of selected nanoparticles such as
surface modified montmorillonite (MMT) clay or carbon nanofibers (CNFs), combined
with a conventional intumescent flame retardant (FR) additive into the polyamide
11/polyamide 12 (PA11/PA12) by melt processing conditions has resulted in the
preparation of a family of intumescent polyamide nanocomposites. These intumescent
polyamide 11 and 12 nanocomposites exhibit enhanced polymer performance
characteristics, i.e., fire retardancy, high strength and high heat resistance and are
expected to expand the market opportunities for polyamide 11 and polyamide 12 polymer
manufacturers.
The objective of this research is to develop improved polyamide 11 and 12 polymers with
enhanced flame retardancy, thermal, and mechanical properties for selective laser
sintering (SLS) rapid manufacturing (RM). In the present study, a nanophase was
introduced into the polyamide 11 and combining it with a conventional intumescent FR
additive via twin screw extrusion. Arkema RILSAN® polyamide 11 molding polymer
pellets were examined with two types of nanoparticles: chemically modified
montmorillonite (MMT) organoclays, and carbon nanofibers (CNFs); and Clairant’s
Exolit® OP 1230 intumescent FR additive were used to create a family of FR
intumescent polyamide 11 nanocomposites.
Transmission electron microscopy (TEM) was used to determine the degree of
nanoparticles dispersion. Injection molded specimens were fabricated for physical,
thermal, and flammability measurements. Thermal stability of these intumescent
polyamide 11 nanocomposites was examined by TGA. Flammability properties were
obtained using the Cone Calorimeter at an external heat flux of 35 kW/m
2
and UL 94
Test Method. Heat deflection temperatures (HDT) were also measured. TEM
micrographs, physical, thermal, and flammability properties are presented. FR
intumescent polyamide 11 nanocomposites properties are compared with polyamide 11
baseline polymer. Based on flammability and mechanical material performance, selective
polymers including polyamide 11 nanocomposites and control polyamide 11 will be
cryogenically ground into fine powders for SLS RM processing. SLS specimens will be
fabricated for thermal, flammability, and mechanical properties characterization.Mechanical Engineerin
Analysis of Laser ARPES from BiSrCaCuO in superconductive state: angle resolved self-energy and fluctuation spectrum
We analyze the ultra high resolution laser angle resolved photo-emission
spectroscopy (ARPES) intensity from the slightly underdoped
BiSrCaCuO in the superconductive (SC) state. The
momentum distribution curves (MDC) were fitted at each energy \w employing
the SC Green's function along several cuts perpendicular to the Fermi surface
with the tilt angle with respect to the nodal cut. The clear
observation of particle-hole mixing was utilized such that the complex
self-energy as a function of is directly obtained from the fitting.
The obtained angle resolved self-energy is then used to deduce the Eliashberg
function \alpha^2 F^{(+)}(\th,\w) in the diagonal channel by inverting the
d-wave Eliashberg equation using the maximum entropy method. Besides a broad
featureless spectrum up to the cutoff energy , the deduced exhibits two peaks around 0.05 eV and 0.015 eV. The former and the broad
feature are already present in the normal state, while the latter emerges only
below . Both peaks become enhanced as is lowered or the angle
moves away from the nodal direction. The implication of these findings are
discussed.Comment: 7 pages, 5 figures, summited to PR
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Polyamide 11-Carbon Nanotubes Nanocomposites: Preliminary Investigation
The objective of this research is to develop an improved polyamide 11 (PA11) polymer with
enhanced flame retardancy, thermal, and mechanical properties for selective laser sintering
(SLS) rapid manufacturing. In the present study, a nanophase was introduced into polyamide 11
via twin screw extrusion. Arkema Rilsan® polyamide 11 molding polymer pellets were used
with 1, 3, 5, and 7 wt% loadings of Arkema’s GraphistrengthTM multi-wall carbon nanotubes
(MWNTs) to create a family of PA11-MWNT nanocomposites.
Transmission electron microscopy and scanning electron microscopy were used to determine
the degree and uniformity of dispersion. Injection molded test specimens were fabricated for
physical, thermal, mechanical properties, and flammability measurements. Thermal stability of
these polyamide 11-MWNT nanocomposites was examined by TGA. Mechanical properties such
as ultimate tensile strength, rupture tensile strength, and elongation at rupture were measured.
Flammability properties were also obtained using the UL 94 test method. All these different
methods and subsequent polymer characteristics are discussed in this paper.Mechanical Engineerin
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