Relevant Influence of Limestone Crystallinity on CO 2

We analyze the role of limestone crystallinity on its CO2 capture performance when subjected to carbonation/calcination cycles at conditions mimicking the Ca-looping (CaL) technology for postcombustion CO 2 capture. The behavior of raw and pretreated limestones (milled and thermally annealed) is investigated by means of thermogravimetric analysis (TGA) tests under realistic sorbent regeneration conditions, which necessarily involve high CO2 partial pressure in the calciner and quick heating rates. The pretreatments applied lead to contrasting effects on the solid crystal structure and, therefore, on its resistance to solid-state diffusion. Our results show that decarbonation at high CO2 partial pressure is notably promoted by decreasing solid crystallinity. CaO regeneration is fully achieved under high CO2 partial pressure at 900 °C in short residence times for the milled limestone whereas complete regeneration for raw limestone requires a minimum calcination temperature of about 950 °C. Such a reduction of the calcination temperature and the consequent mitigation of multicyclic capture capacity decay would serve to enhance the efficiency of the CaL technology. On the other hand, the results of our study suggest that the use of highly crystalline limestones would be detrimental since excessively high calcination temperatures should be required to attain full decarbonation at realistic conditions.Junta de Andalucía FQM-5735, TEP-7858Ministerio de Economía y Competitividad FIS2011-25161, CTQ2011-2762

Maturation of critical technologies for the DEMO balance of plant systems

The Pre-Concept Design (PCD) of the Balance of Plant (BoP) systems of the EU-DEMO power plant is described in this paper for both breeding blanket (BB) concepts under assessment, namely the Water Cooled Lithium Lead (WCLL) BB and the Helium Cooled Pebble Bed (HCPB) BB. Moreover, the results of a preliminary evaluation of a number of BoP variants are discussed. This paper outlines the steps of the BoP design development, highlighting the project objectives and the strategy for their achievement under the very challenging requirements which include, among others, the intermittent nature of the DEMO plasma heat source. The main achievements during the PCD Phase will be reported together with the development plan for the Concept Design (CD) Phase to reach a mature (feasible) BoP concept for DEMO

Maturation of critical technologies for the DEMO balance of plant systems

The Pre-Concept Design (PCD) of the Balance of Plant (BoP) systems of the EU-DEMO power plant is described in this paper for both breeding blanket (BB) concepts under assessment, namely the Water Cooled Lithium Lead (WCLL) BB and the Helium Cooled Pebble Bed (HCPB) BB. Moreover, the results of a preliminary evaluation of a number of BoP variants are discussed. This paper outlines the steps of the BoP design development, highlighting the project objectives and the strategy for their achievement under the very challenging requirements which include, among others, the intermittent nature of the DEMO plasma heat source. The main achievements during the PCD Phase will be reported together with the development plan for the Concept Design (CD) Phase to reach a mature (feasible) BoP concept for DEMO.peer-reviewe