492 research outputs found

    Importance of adequate sample sizes in fatty acid intervention trials

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    Abstract not availableLisa N. Yelland, Maria Makrides, Andrew J. McPhee, Julie Quinlivan, Robert A. Gibso

    Wind, convection and fetch dependence of gas transfer velocity in an Arctic sea‐ice lead determined from eddy covariance CO 2 flux measurements

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    The air‐water exchange of trace gases such as CO2 is usually parameterized in terms of a gas transfer velocity, which can be derived from direct measurements of the air‐sea gas flux. The transfer velocity of poorly soluble gases is driven by near‐surface ocean turbulence, which may be enhanced or suppressed by the presence of sea ice. A lack of measurements means that air‐sea fluxes in polar regions, where the oceanic sink of CO2 is poorly known, are generally estimated using open‐ocean transfer velocities scaled by ice fraction. Here, we describe direct determinations of CO2 gas transfer velocity from eddy covariance flux measurements from a mast fixed to ice adjacent to a sea‐ice lead during the summer‐autumn transition in the central Arctic Ocean. Lead water CO2 uptake is determined using flux footprint analysis of water‐atmosphere and ice‐atmosphere flux measurements made under conditions (low humidity and high CO2 signal) that minimise errors due to humidity cross‐talk. The mean gas transfer velocity is found to have a quadratic dependence on wind speed: k660 = 0.179 U102 which is 30% lower than commonly used open‐ocean parameterizations. As such, current estimates of polar ocean carbon uptake likely overestimate gas exchange rates in typical summertime conditions of weak convective turbulence. Depending on the footprint model chosen, the gas transfer velocities also exhibit a dependence on the dimension of the lead, via its impact on fetch length and hence sea state. Scaling transfer velocity parameterizations for regional gas exchange estimates may therefore require incorporating lead width data

    Experimental investigation of NO reburning during oxy-coal burner staging

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    This study presents an investigation into the impact of varied burner staging environments on an oxy-fuel flame and the rate of the NO formation and destruction processes. The experimental data was extracted from the use of a 250 kWth down-fired combustion test facility with a scaled-down model of an industrial low-NOx burner (LNB). Two oxy-coal combustion regimes were investigated by varying a fixed flow of oxidant between the secondary and tertiary registers, so as to impact the stoichiometry in the fuel-rich region and flame structure, and using various NO recycling regimes, to test the impact of these different burner configurations on NO reburning. The data was collected by monitoring key emissions in the flue gas and in the flame, as well as temperatures throughout the furnace and the unburned carbon content of the ash. A detailed investigation encompassing the impact of secondary oxidant proportion for different oxidants on NO emissions, together with the quantification of recycled NO destruction, is discussed. This investigation finds that 85 % to 95 % of the recycled NO is destroyed at a range of burner configurations using OF 27 and OF 30 at 170 kWth. In addition to this, NO formation and carbon burnout are found to be significantly affected with changing burner configurations. Further to this, OF 30 flames appear to be more sensitive to burner configuration than OF 27 flames with regards to both NO formation and destruction, possibly due to the decreased density of the OF 30 oxidant. Radial profiles of two burner configurations at OF 27 and OF 30, as well as an axial profile of two burner configurations at OF 30, are analysed. The profiles appear to show that burner staging aids in controlling the products of NO reburning, hence maximising the destruction of recycled NO

    Comparison of two closed-path cavity-based spectrometers for measuring air-water CO<inf>2</inf> and CH<inf>4</inf> fluxes by eddy covariance

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    In recent years several commercialised closed-path cavity-based spectroscopic instruments designed for eddy covariance flux measurements of carbon dioxide (CO2), methane (CH4), and water vapour (H2O) have become available. Here we compare the performance of two leading models - the Picarro G2311-f and the Los Gatos Research (LGR) Fast Greenhouse Gas Analyzer (FGGA) at a coastal site. Both instruments can compute dry mixing ratios of CO2 and CH4 based on concurrently measured H2O, temperature, and pressure. Additionally, we used a high throughput Nafion dryer to physically remove H2O from the Picarro airstream. Observed air-sea CO2 and CH4 fluxes from these two analysers, averaging about 12 and 0.12 mmol m-2 day-1 respectively, agree within the measurement uncertainties. For the purpose of quantifying dry CO2 and CH4 fluxes downstream of a long inlet, the numerical H2O corrections appear to be reasonably effective and lead to results that are comparable to physical removal of H2O with a Nafion dryer in the mean. We estimate the high-frequency attenuation of fluxes in our closed-path set-up, which was relatively small (≀ 10 %) for CO2 and CH4 but very large for the more polar H2O. The Picarro showed significantly lower noise and flux detection limits than the LGR. The hourly flux detection limit for the Picarro was about 2 mmol m-2 day-1 for CO2 and 0.02 mmol m-2 day-1 for CH4. For the LGR these detection limits were about 8 and 0.05 mmol m-2 day-1. Using global maps of monthly mean air-sea CO2 flux as reference, we estimate that the Picarro and LGR can resolve hourly CO2 fluxes from roughly 40 and 4 % of the world's oceans respectively. Averaging over longer timescales would be required in regions with smaller fluxes. Hourly flux detection limits of CH4 from both instruments are generally higher than the expected emissions from the open ocean, though the signal to noise of this measurement may improve closer to the coast

    Superconductivity induced by spark erosion in ZrZn2

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    We show that the superconductivity observed recently in the weak itinerant ferromagnet ZrZn2 [C. Pfleiderer et al., Nature (London) 412, 58 (2001)] is due to remnants of a superconducting layer induced by spark erosion. Results of resistivity, susceptibility, specific heat and surface analysis measurements on high-quality ZrZn2 crystals show that cutting by spark erosion leaves a superconducting surface layer. The resistive superconducting transition is destroyed by chemically etching a layer of 5 microns from the sample. No signature of superconductivity is observed in rho(T) of etched samples at the lowest current density measured, J=675 Am-2, and at T < 45 mK. EDX analysis shows that spark-eroded surfaces are strongly Zn depleted. The simplest explanation of our results is that the superconductivity results from an alloy with higher Zr content than ZrZn2.Comment: Final published versio

    Ferromagnetic Properties of ZrZn2_2

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    The low Curie temperature (T_C approx 28K) and small ordered moment (M_0 approx 0.17 mu_B f.u.^-1) of ZrZn2 make it one of the few examples of a weak itinerant ferromagnet. We report results of susceptibility, magnetization, resistivity and specific heat measurements made on high-quality single crystals of ZrZn2. From magnetization scaling in the vicinity of T_C (0.001<|T-T_C|/T_C<0.08), we obtain the critical exponents beta=0.52+/-0.05 and delta=3.20+/-0.08, and T_C=27.50+/-0.05K. Low-temperature magnetization measurements show that the easy axis is [111]. Resistivity measurements reveal an anomaly at T_C and a non-Fermi liquid temperature dependence rho(T)=rho_0+AT^n, where n=1.67+/-0.02, for 1<T<14K. The specific heat measurements show a mean-field-like anomaly at T_C. We compare our results to various theoretical models.Comment: submitted to PR

    Shubnikov-de Haas oscillations in YBa_2Cu_4O_8

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    We report the observation of Shubnikov-de Haas oscillations in the underdoped cuprate superconductor YBa2_2Cu4_4O8_8 (Y124). For field aligned along the c-axis, the frequency of the oscillations is 660±30660\pm 30 T, which corresponds to ∌2.4\sim 2.4 % of the total area of the first Brillouin zone. The effective mass of the quasiparticles on this orbit is measured to be 2.7±0.32.7\pm0.3 times the free electron mass. Both the frequency and mass are comparable to those recently observed for ortho-II YBa2_2Cu3_3O6.5_{6.5} (Y123-II). We show that although small Fermi surface pockets may be expected from band structure calculations in Y123-II, no such pockets are predicted for Y124. Our results therefore imply that these small pockets are a generic feature of the copper oxide plane in underdoped cuprates.Comment: v2: Version of paper accepted for publication in Physical Review Letters. Only minor changes to the text and reference

    Does n-3 LCPUFA supplementation during pregnancy increase the IQ of children at school age? Follow-up of a randomised controlled trial

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    Introduction Despite recommendations that pregnant women increase their docosahexaenoic acid (DHA) intake to support fetal brain development, a recent systematic review found a lack of high-quality data to support the long-term effects of DHA supplementation on children's neurodevelopment. Methods and analysis We will assess child neurodevelopment at 7 years of age in follow-up of a multicentre double-blind randomised controlled trial of DHA supplementation in pregnancy. In 2010–2012, n=2399 Australian women with a singleton pregnancy <21 weeks’ gestation were randomised to receive 3 capsules daily containing a total dose of 800 mg DHA/day or a vegetable oil placebo until birth. N=726 children from Adelaide (all n=97 born preterm, random sample of n=630 born at term) were selected for neurodevelopmental follow-up and n=638 (preterm n=85) are still enrolled at 7 years of age. At the 7-year follow-up, a psychologist will assess the primary outcome, IQ, with the Wechsler Abbreviated Scale of Intelligence, Second Edition. Specific measures of executive functioning (Fruit Stroop and the Rey Complex Figure), attention (Test of Everyday Attention for Children), memory and learning (Rey Auditory Verbal Learning Test), language (Clinical Evaluation of Language Fundamentals, Fourth Edition) and basic educational skills (Wide Range Achievement Test, Fourth Edition) will also be administered. Caregivers will be asked to complete questionnaires measuring behaviour and executive functioning. Families, clinicians and research personnel are blinded to group assignment with the exception of families who requested unblinding prior to the follow-up. All analyses will be conducted according to the intention-to-treat principal. Ethics and dissemination All procedures will be approved by the relevant institutional ethics committees prior to start of the study. The results of this study will be disseminated in peer-reviewed journal publications and academic presentations. Trial registration numbers ACTRN12605000569606 and ACTRN12614000770662.Jacqueline F Gould, Karli Treyvaud, Lisa N Yelland, Peter J Anderson, Lisa G Smithers, Robert A Gibson, Andrew J McPhee, Maria Makride
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