185 research outputs found
Crossover from Electronic to Atomic Shell Structure in Alkali Metal Nanowires
After making a cold weld by pressing two clean metal surfaces together, upon
gradually separating the two pieces a metallic nanowire is formed, which
progressively thins down to a single atom before contact is lost. In previous
experiments [1,2] we have observed that the stability of such nanowires is
influenced by electronic shell filling effects, in analogy to shell effects in
metal clusters [3]. For sodium and potassium at larger diameters there is a
crossover to crystalline wires with shell-closings corresponding to the
completion of additional atomic layers. This observation completes the analogy
between shell effects observed for clusters and nanowires.Comment: 4 page
Point-contact study of the LuNi2B2C borocarbide superconducting film
We present point-contact (PC) Andreev-reflection measurements of a
superconducting epitaxial c-axis oriented nickel borocarbide film LuNi2B2C
(Tc=15.9 K). The averaged value of the superconducting gap is found to be 2.6
+/-0.2 meV in the one-gap approach, whereas the two-gap approach results in
2.14+/-0.36 meV and 3.0+/-0.27 meV. The better fit of the Andreev-reflection
spectra for the LuNi2B2C - Cu PC obtained by the two-gap approach provides
evidence for multiband superconductivity in LuNi2B2C. For the first time, PC
electron-phonon interaction (EPI) spectra have been measured for this compound.
They demonstrate pronounced phonon maximum at 8.5+/-0.4meV and a second shallow
one at 15.8+/-0.6 meV. The electron-phonon coupling constant estimated from the
PC EPI spectra turned out to be small (~ 0.1), like in other superconducting
rare-earth nickel borocarbides. Possible reasons for this are discussed.Comment: 5 pages, 5 figures, V2: figs. 2 & 5 captions are corrected, and new
Refs. 4, 6, 12, 13, 14 are adde
Rietveld refinement of the crystal structures of hexagonal Y6Cr4+xAl43−x (x=2.57) and tetragonal YCr4−xAl8+x (x=1.22)
Y6Cr4+xAl43−x (x = 2.57); space group P63/mcm, a = 10.8601(1) Å, c = 17.6783(3) Å, V= 1805.7(1) Å3, Z=2; isostructural to Yb6Cr4+xAl43−x, (x=1.76) with two aluminium sites partially occupied by chromium (44% and 27% Cr). YCr4−xAl8+x (x=1.22); space group I4/mmm, a = 9.0299(2) Å, c = 5.1208(2) Å, V=417.55(3) Å3, Z=2, disordered variant of CeMn4Al8 with one chromium site (8f) partially occupied by aluminium (33% Al); X-ray powder diffraction data were collected on a well-crystallized multiphase sample containing 43 wt.% of Y6Cr4+xAl43−x, 27 wt.% of Y2Cr8−xAl16+x, 16 wt.% of Al, 13 wt.% of YAl3, and traces of Y2O3. Structure refinement converged at Rwp = 2.0% and RB = 3.5, 3.6% resp. for a total of 78 parameters and 1190 reflection
Observation of anisotropic effect of antiferromagnetic ordering on the superconducting gap in ErNi2B2C
The point-contact (PC) spectra of the Andreev reflection dV/dI curves of the
superconducting rare-earth nickel borocarbide ErNi2B2C (Tc=11 K) have been
analyzed in the "one-gap" and "two-gap" approximations using the generalized
Blonder-Tinkham-Klapwijk (GBTK) model and the Beloborod'ko (BB) model allowing
for the pair-breaking effect of magnetic impurities. Experimental and
calculated curves have been compared not only in shape, but in magnitude as
well, which provide more reliable data for determining the temperature
dependence of the energy gap (or superconducting order parameter) \Delta(T).
The anisotropic effect of antiferromagnetic ordering at T_N =6 K on the
superconducting gap/order parameter has been determined: as the temperature is
lowered, \Delta(T) decreases by 25% in the c-direction and only by 4% in the
ab-plane. It is found that the pair-breaking parameter increases in the
vicinity of the magnetic transitions, the increase being more pronounced in the
c-direction. The efficiency of the models was tested for providing \Delta(T)
data for ErNi2B2C from Andreev reflection spectra.Comment: 16 two column pages, 20 figs., will be published in Fiz. Nizk. Temp.
N10, 2010; V2: added - "Acknowledgement" & "Note added in proof
High-bias stability of monatomic chains
For the metals Au, Pt and Ir it is possible to form freely suspended
monatomic chains between bulk electrodes. The atomic chains sustain very large
current densities, but finally fail at high bias. We investigate the breaking
mechanism, that involves current-induced heating of the atomic wires and
electromigration forces. We find good agreement of the observations for Au
based on models due to Todorov and coworkers. The high-bias breaking of atomic
chains for Pt can also be described by the models, although here the parameters
have not been obtained independently. In the limit of long chains the breaking
voltage decreases inversely proportional to the length.Comment: 7 pages, 5 figure
Landing and catalytic characterization of individual nanoparticles on electrode surfaces
We demonstrate a novel and versatile pipet-based approach to study the landing of individual nanoparticles (NPs) on various electrode materials without any need for encapsulation or fabrication of complex substrate electrode structures, providing great flexibility with respect to electrode materials. Because of the small electrode area defined by the pipet dimensions, the background current is low, allowing for the detection of minute current signals with good time resolution. This approach was used to characterize the potential-dependent activity of Au NPs and to measure the catalytic activity of a single NP on a TEM grid, combining electrochemical and physical characterization at the single NP level for the first time. Such measurements open up the possibility of studying the relation between the size, structure and activity of catalyst particles unambiguously
Point-contact spectroscopy of the antiferromagnetic superconductor HoNi2B2C in the normal and superconducting state
Point-contact (PC) spectroscopy measurements on antiferromagnetic (AF)
(T_N=5.2K) HoNi2B2C single crystals in the normal and two different
superconducting (SC) states (T_c=8.5K and T_c^*=5.6K<T_c, with 2\Delta/kT_c^*=3.9. The strong coupling
Eliashberg analysis of the low-temperature SC phase with T_c^*=5.6K =T_N,
coexisting with the commensurate AF structure, suggests a sizable value of the
EPI constant \lambda_s=0.93. We also provide strong support for the recently
proposed by us ''Fermi surface (FS) separation'' scenario for the coexistence
of magnetism and superconductivity in magnetic borocarbides, namely, that the
superconductivity in the commensurate AF phase survives at a special (nearly
isotropic) FS sheet without an admixture of Ho 5d states. Above T_c^* the SC
features in the PC characteristics are strongly suppressed pointing to a
specific weakened SC state between T_c* and T_c.Comment: 11 pages, 8 figs, to be published in PRB, Vol.75, Iss.2
Anatomy of point-contact Andreev reflection spectroscopy from the experimental point of view (review)
We review application of point-contact Andreev-reflection spectroscopy to
study elemental superconductors, where theoretical conditions for the smallness
of the point-contact size with respect to the characteristic lengths in the
superconductor can be satisfied. We discuss existing theoretical models and
identify new issues that have to be solved, especially when applying this
method to investigate more complex superconductors. We will also demonstrate
that some aspects of point-contact Andreev-reflection spectroscopy still need
to be addressed even when investigating ordinary metals.Comment: 20 pages, 18 figs. V2: Ref.60 and footnote 3 are added, a number of
minor fixe
Electron-phonon interaction in transition metal diborides TB_2 (T=Zr, Nb, Ta) studied by point-contact spectroscopy
The electron-phonon interaction (EPI) in transition metal diborides TB_2
(T=Zr, Nb, Ta) is investigated by point-contact (PC) spectroscopy. The PC EPI
functions were recovered and the EPI parameters lambda<0.1 were estimated for
all three compounds. Common and distinctive features between the EPI functions
for those diborides are discussed also in connection with the superconductivity
in MgB_2.Comment: V2: minor changes, Ref.[21] added, publ. in PR
Spin Diode Based on Fe/MgO Double Tunnel Junction
We demonstrate a spin diode consisting of a semiconductor free nano-scale
Fe/MgO-based double tunnel junction. The device exhibits a near perfect
spin-valve effect combined with a strong diode effect. The mechanism consistent
with our data is resonant tunneling through discrete states in the middle
ferromagnetic layer sandwiched by tunnel barriers of different spin-dependent
transparency. The observed magneto-resistance is record high, ~4000%,
essentially making the structure an on/off spin-switch. This, combined with the
strong diode effect, ~100, offers a new device that should be promising for
such technologies as magnetic random access memory and re-programmable logic.Comment: 14 page
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