Reentrant Superfluidity and Pair Density Wave in Single Component Dipolar Fermi Gases

We study the superfluidity of single component dipolar Fermi gases in three dimensions within a pairing fluctuation theory. The transition temperature $T_{c}$ for the dominant $p_z$ wave superfluidity exhibits a remarkable re-entrant behavior as a function of the pairing strength induced by the dipole-dipole interaction (DDI), which leads to an anisotropic pair dispersion. The anisotropy and the long range nature of the DDI cause $T_c$ to vanish for a narrow range of intermediate interaction strengths, where a pair density wave state emerges as the ground state. The superfluid density and thermodynamics below $T_{c}$, along with the density profiles in a harmonic trap, are investigated as well, throughout the BCS-BEC crossover. Implications for experiments are discussed.Comment: 6 pages, 6 color figures; replaced with the final published versio

First-principles Study of High-Pressure Phase Stability and Superconductivity of Bi4I4

Bismuth iodide Bi4I4 exhibits intricate crystal structures and topological insulating states that are highly susceptible to influence by environments, making its physical properties highly tunable by external conditions. In this work, we study the evolution of structural and electronic properties of Bi4I4 at high pressure using an advanced structure search method in conjunction with first-principles calculations. Our results indicate that the most stable ambient-pressure monoclinic α−Bi4I4 phase in C2/m symmetry transforms to a trigonal P31c structure (ɛ−Bi4I4) at 8.4 GPa, then to a tetragonal P4/mmm structure (ζ−Bi4I4) above 16.6 GPa. In contrast to the semiconducting nature of ambient-pressure Bi4I4, the two high-pressure phases are metallic, in agreement with reported electrical measurements. The ɛ−Bi4I4 phase exhibits distinct ionic states of Iδ− and (Bi4I3)δ + (δ=0.4123 e), driven by a pressure-induced volume reduction. We show that both ɛ- and ζ−Bi4I4 are superconductors, and the emergence of pressure-induced superconductivity might be intimately linked to the underlying structural phase transitions

Smooth Flow in Diamond: Atomistic Ductility and Electronic Conductivity

Diamond is the quintessential superhard material widely known for its stiff and brittle nature and large electronic band gap. In stark contrast to these established benchmarks, our first-principles studies unveil surprising intrinsic structural ductility and electronic conductivity in diamond under coexisting large shear and compressive strains. These complex loading conditions impede brittle fracture modes and promote atomistic ductility, triggering rare smooth plastic flow in the normally rigid diamond crystal. This extraordinary structural change induces a concomitant band gap closure, enabling smooth charge flow in deformation created conducting channels. These startling soft-and-conducting modes reveal unprecedented fundamental characteristics of diamond, with profound implications for elucidating and predicting diamond’s anomalous behaviors at extreme conditions

Rare Helium-Bearing Compound FeO2He Stabilized at Deep-Earth Conditions

There is compelling geochemical evidence for primordial helium trapped in Earth’s lower mantle, but the origin and nature of the helium source remain elusive due to scarce knowledge on viable helium-bearing compounds that are extremely rare. Here we explore materials physics underlying this prominent challenge. Our structure searches in conjunction with first-principles energetic and thermodynamic calculations uncover a remarkable helium-bearing compound FeO2He at high pressure-temperature conditions relevant to the core-mantle boundary. Calculated sound velocities consistent with seismic data validate FeO2He as a feasible constituent in ultralow velocity zones at the lowermost mantle. These mutually corroborating findings establish the first and hitherto only helium-bearing compound viable at pertinent geophysical conditions, thus providing vital physics mechanisms and materials insights for elucidating the enigmatic helium reservoir in deep Earth

The measurement and modeling of a P2P streaming video service

Most of the work on grid technology in the video area has been generally restricted to aspects of resource scheduling and replica management. The traffic of such a service has a lot of characteristics in common with that of the traditional video service. However the architecture and user behavior in grid networks are quite different from those of the traditional Internet. Considering the potential of grid networks and video sharing services, measuring and analyzing P2P IPTV traffic are important and fundamental works in the field of grid networks. This paper investigates the features of PPLive, the most popular streaming service in China and based on P2P technology. Through monitoring and analyzing PPLive traffic streams, the characteristics of P2P streaming services have been studied. The analyses are carried out in respect of bearing protocols, geographical distribution and the self-similarity properties of the traffic. A streaming service traffic model has been created and verified with the simulation. The simulation results indicate that the proposed streaming service traffic model complies well with the real IPTV streaming service. It can also function as a step towards studying video-sharing services on grids

CGMP: cloud-assisted green multimedia processing

With continued advancements of mobile computing and communications, emerging novel multimedia services and applications have attracted lots of attention and been developed for mobile users, such as mobile social network, mobile cloud medical treatment, mobile cloud game. However, because of limited resources on mobile terminals, it is of great challenge to improve the energy efficiency of multimedia services. In this paper, we propose a cloud-assisted green multimedia processing architecture (CGMP) based on mobile cloud computing. Specifically, the tasks of multimedia processing with energy-extensive consumption can be offloaded to the cloud, and the face recognition algorithm with improved principal component analysis and nearest neighbor classifier is realized on CGMP based cloud platform. Experimental results show that the proposed scheme can effectively save the energy consumption of the equipment

Chemical and Electrochemical Studies of Cl\u3csub\u3e2\u3c/sub\u3eFeS\u3csub\u3e2\u3c/sub\u3eMS\u3csub\u3e2\u3c/sub\u3eFeCl\u3csub\u3e2\u3c/sub\u3e\u3csup\u3e\u3cem\u3en\u3c/em\u3e-\u3c/sup\u3e Clusters [M = Mo (n = \u3cem\u3e2\u3c/em\u3e), W (\u3cem\u3en\u3c/em\u3e = 2), V (\u3cem\u3en\u3c/em\u3e = 3)]

The electrochemistry and spectroelectrochemistry of [Cl2FeS2MS2FeCl2]n- clusters (where n = 2 for M = Mo and W and n = 3 for M = V; Ia, Ib, and Ic, respectively) and the dimetal complex [Cl2FeS2MoS2]2- (IIIa) were examined in order to characterize the structures and properties of the one-electron-reduced complexes. A stable reduction product for Ia was observed spectroelectrochemically at −1.05 V, which could be oxidized back to the starting complex. Reduction at more negative potentials caused complete bleaching of the spectrum, and the starting complex could not be obtained by reoxidation. Similar behavior was observed for the tungsten complex, Ib, but the dimetal complex [Cl2FeS2WS2]2- was formed upon reoxidation. Chemical and electrochemical reduction of Ia and Ib both led to the same products (IIa and IIb), but by different mechanisms. Borohydride reduction of Ia and Ib led to the initial formation of the dimetal complex, while the electrochemical reduction of Ia proceeded by way of the formation of [Cl2FeS2MoS2FeCl2]3-. Spectral changes were observed in the reduction of Ic, but they were not reversible. Resonance Raman spectroscopy of the reduced complexes was carried out in order to characterize the reduction product. Two polarized bands in the sulfur bridging region were observed in the resonance Raman spectra of electrochemically and chemically generated IIa and IIb. The relative intensities of these bands were dependent upon the excitation frequency. Reduction of Ic led to the loss of all resonance Raman bands. Reduction of IIIa gave rise to a complex (IVa) that was spectrally quite similar to IIa. These results, along with the previously reported result that the reduction complex was diamagnetic, indicate that the complex IIa is a dimeric species. The most likely structure consistent with these data is a Mo2Fe2S4 cubane structure

Ionic high-pressure form of elemental boron

Boron is an element of fascinating chemical complexity. Controversies have shrouded this element since its discovery was announced in 1808: the new 'element' turned out to be a compound containing less than 60-70 percent of boron, and it was not until 1909 that 99-percent pure boron was obtained. And although we now know of at least 16 polymorphs, the stable phase of boron is not yet experimentally established even at ambient conditions. Boron's complexities arise from frustration: situated between metals and insulators in the periodic table, boron has only three valence electrons, which would favour metallicity, but they are sufficiently localized that insulating states emerge. However, this subtle balance between metallic and insulating states is easily shifted by pressure, temperature and impurities. Here we report the results of high-pressure experiments and ab initio evolutionary crystal structure predictions that explore the structural stability of boron under pressure and, strikingly, reveal a partially ionic high-pressure boron phase. This new phase is stable between 19 and 89 GPa, can be quenched to ambient conditions, and has a hitherto unknown structure (space group Pnnm, 28 atoms in the unit cell) consisting of icosahedral B12 clusters and B2 pairs in a NaCl-type arrangement. We find that the ionicity of the phase affects its electronic bandgap, infrared adsorption and dielectric constants, and that it arises from the different electronic properties of the B2 pairs and B12 clusters and the resultant charge transfer between them.Comment: Published in Nature 453, 863-867 (2009