Luffa aegyptiaca (Gourd) Fruit Juice as a Source of Peroxidase

Peroxidases have turned out to be potential biocatalyst for a variety of organic reactions. The research work reported in this communication was done with the objective of finding a convenient rich source of peroxidase which could be used as a biocatalyst for organic synthetic reactions. The studies made have shown that Luffa aegyptiaca (gourd) fruit juice contains peroxidase activity of the order of 180 enzyme unit/mL. The Km values of this peroxidase for the substrates guaiacol and hydrogen peroxide were 2.0 and 0.2 mM, respectively. The pH and temperature optima were 6.5 and 60°C, respectively. Like other peroxidases, it followed double displacement type mechanism. Sodium azide inhibited the enzyme competitively with Ki value of 3.35 mM

Simulations Show that Vortex Flows could Heat the Chromosphere in Solar Plage

The relationship between vortex flows at different spatial scales and their contribution to the energy balance in the chromosphere is not yet fully understood. We perform three-dimensional (3D) radiation-magnetohydrodynamic (MHD) simulations of a unipolar solar plage region at a spatial resolution of 10 km using the MURaM code. We use the swirling-strength criterion that mainly detects the smallest vortices present in the simulation data. We additionally degrade our simulation data to smooth-out the smaller vortices, so that also the vortices at larger spatial scales can be detected. Vortex flows at various spatial scales are found in our simulation data for different effective spatial resolutions. We conclude that the observed large vortices are likely clusters of much smaller ones that are not yet resolved by observations. We show that the vertical Poynting flux decreases rapidly with reduced effective spatial resolutions and is predominantly carried by the horizontal plasma motions rather than vertical flows. Since the small-scale horizontal motions or the smaller vortices carry most of the energy, the energy transported by vortices deduced from low resolution data is grossly underestimated. In full resolution simulation data, the Poynting flux contribution due to vortices is more than adequate to compensate for the radiative losses in plage, indicating their importance for chromospheric heating.Comment: 8 pages, 5 figures, accepted in ApJ

Superconductivity at 5.2 K in ZrTe3 polycrystals and the effect of Cu, Ag intercalation

We report the occurrence of superconductivity in polycrystalline samples of ZrTe3 at 5.2 K temperature at ambient pressure. The superconducting state coexists with the charge density wave (CDW) phase, which sets in at 63K. The intercalation of Cu or Ag, does not have any bearing on the superconducting transition temperature but suppresses the CDW state. The feature of CDW anomaly in these compounds is clearly seen in the DC magnetization data. Resistivity data is analysed to estimate the relative loss of carriers and reduction in the nested Fermi surface area upon CDW formation in the ZrTe3 and the intercalated compounds.Comment: 5 pages, 8 figure

Determination of Delay in Detonation of a Sandwiched Explosive Impacted by a Shaped Charge Jet

A simple analytical model has been developed to determine delay in detonation of an explosive sandwiched between two metal plates and impacted by a shaped charge jet. The analytical model consists of a relation between detonation delay and depth of jet penetration in a target kept in contact across the explosive sandwich. This relation is derived by expressing depth of jet penetration P as a function of detonation delay Tdx and duration Tw of free passage of the jet through the hole in the top plate of the sandwich. One more relation between Tdx and Tw has been obtained from the theory of expansion of hole produced in a metal plate by jet impact. These two relations have been solved simultaneously to get values of both these parameters as a function of jet penetration. It is proposed that this analytical model can be used in two ways. First, this model can be used to calculate detonation delay by experimental measurement of jet penetration in a target. The detonation delay thus determined can be used to calculate insensitivity constant Aj of an explosive. Second, this model can be used to theoretically calculate jet penetrations obtained by different shaped charge warheads when using a sandwich of explosive with a given insensitivity. Both uses of this analytical model are illustrated using numerical examples

Supercriticality to subcriticality in dynamo transitions

Evidence from numerical simulations suggest that the nature of dynamo transition changes from supercritical to subcritical as the magnetic Prandtl number is decreased. To explore this interesting crossover we first use direct numerical simulations to investigate the hysteresis zone of a subcritical Taylor-Green dynamo. We establish that a well defined boundary exists in this hysteresis region which separates dynamo states from the purely hydrodynamic solution. We then propose simple dynamo models which show similar crossover from supercritical to subcritical dynamo transition as a function of the magnetic Prandtl number. Our models show that the change in the nature of dynamo transition is connected to the stabilizing or de-stabilizing influence of governing non-linearities.Comment: Version 3 note: Found a sign-error in an equation which propagated further. Section 4 and Fig. 3,4,5 are updated in Version 3 (final form

Synthesis of novel 3-arylcyclopenta[c]quinolines via acid-induced domino cyclization of 2-arylamino-2-methylthioethenyl 2-arylcyclopropyl ketones

A novel acid-induced domino cyclization of N,S-anilinoacetals of type 3 derived from 2- arylcyclopropyl ketones, is reported which yields a wide range of substituted- and fused- 3- arylcyclopenta[c]quinolines 6 with concomitant formation of a cyclopentane and a quinoline ring

Effect of pressure cycling on Iron: Signatures of an electronic instability and unconventional superconductivity

High pressure electrical resistivity and x-ray diffraction experiments have been performed on Fe single crystals. The crystallographic investigation provides direct evidence that in the martensitic $bcc \rightarrow hcp$ transition at 14 GPa the $\lbrace 110\rbrace_{bcc}$ become the $\lbrace 002\rbrace_{hcp}$ directions. During a pressure cycle, resistivity shows a broad hysteresis of 6.5 GPa, whereas superconductivity, observed between 13 and 31 GPa, remains unaffected. Upon increasing pressure an electronic instability, probably a quantum critical point, is observed at around 19 GPa and, close to this pressure, the superconducting $T_{c}$ and the isothermal resistivity ($0<T<300\,$K) attain maximum values. In the superconducting pressure domain, the exponent $n = 5/3$ of the temperature power law of resistivity and its prefactor, which mimics $T_{c}$, indicate that ferromagnetic fluctuations may provide the glue for the Cooper pairs, yielding unconventional superconductivity

The possibility of determining open-cluster parameters from BVRI photometry

In the last decades we witnessed an increase in studies of open clusters of the Galaxy, especially because of the good determination for a wide range of values of parameters such as age, distance, reddening, and proper motion. The reliable determination of the parameters strongly depends on the photometry available and especially on the U filter, which is used to obtain the color excess E(B-V) through the color-color diagram (U-B) by (B-V) by fitting a zero age main-sequence. Owing to the difficulty of performing photometry in the U band, many authors have tried to obtain E(B-V) without the filter. But because of the near linearity of the color-color diagrams that use the other bands, combined with the fact that most fitting procedures are highly subjective (many done "by eye") the reliability of those results has always been questioned. Our group has recently developed, a tool that performs isochrone fitting in open-cluster photometric data with a global optimization algorithm, which removes the need to visually perform the fits and thus removes most of the related subjectivity. Here we apply our method to a set of synthetic clusters and two observed open clusters (Trumpler 1 and Melotte 105) using only photometry for the BVRI bands. Our results show that, considering the cluster structural variance caused only by photometric and Poisson sampling errors, our method is able to recover the synthetic cluster parameters with errors of less than 10% for a wide range of ages, distances, and reddening, which clearly demonstrates its potential. The results obtained for Trumpler 1 and Melotte 105 also agree well with previous literature values.Comment: 5 pages, 5 figures, accepted for publication in Astronomy&Astrophysic