Weak Magnetic Order in the Bilayered-hydrate Nax_{x}CoO2⋅y_{2}\cdot yH2_{2}O Structure Probed by Co Nuclear Quadrupole Resonance - Proposed Phase Diagram in Superconducting Nax_xCoO2⋅_{2} \cdot yyH2_2O

A weak magnetic order was found in a non-superconducting bilayered-hydrate Na$_{x}$CoO$_{2}\cdot y$H$_{2}$O sample by a Co Nuclear Quadrupole Resonance (NQR) measurement. The nuclear spin-lattice relaxation rate divided by temperature $1/T_1T$ shows a prominent peak at 5.5 K, below which a Co-NQR peak splits due to an internal field at the Co site. From analyses of the Co NQR spectrum at 1.5 K, the internal field is evaluated to be $\sim$ 300 Oe and is in the $ab$-plane. The magnitude of the internal field suggests that the ordered moment is as small as $\sim 0.015$ $\mu_B$ using the hyperfine coupling constant reported previously. It is shown that the NQR frequency $\nu_Q$ correlates with magnetic fluctuations from measurements of NQR spectra and $1/T_1T$ in various samples. The higher-$\nu_Q$ sample has the stronger magnetic fluctuations. A possible phase diagram in Na$_{x}$CoO$_{2}\cdot y$H$_{2}$O is depicted using $T_c$ and $\nu_Q$, in which the crystal distortion along the c-axis of the tilted CoO$_2$ octahedron is considered to be a physical parameter. Superconductivity with the highest $T_c$ is seemingly observed in the vicinity of the magnetic phase, suggesting strongly that the magnetic fluctuations play an important role for the occurrence of the superconductivity.Comment: 5 pages, 6 figures, submitted to J. Phys. Soc. Jp

Measurement of Internal Friction for Tungsten by the Curve Vibrating Method with Variation of Voltage and Temperature

Application of a curved vibrating wire method (CVM) to measure gas viscosity has been widely used. A fine Tungsten wire with 50 mm of diameter is bent into a semi-circular shape and arranged symmetrically in a magnetic field of about 0.2 T. The frequency domain is used for calculating the viscosity as a response for forced oscillation of the wire. Internal friction is one of the parameter in the CVM which is has to be measured beforeahead. Internal friction coefficien for the wire material which is the inverse of the quality factor has to be measured in a vacuum condition. The term involving internal friction actually represents the effective resistance of motion due to all non-viscous damping phenomena including internal friction and magnetic damping. The testing of internal friction measurement shows that at different induced voltage and elevated temperature at a vacuum condition, it gives the value of internal friction for Tungsten is around 1 to 4 10-4

Unconventional Superconductivity and Nearly Ferromagnetic Spin Fluctuations in Nax_xCoO2_2⋅y\cdot yH2_2O

Co NQR studies were performed in recently discovered superconductor Na$_x$CoO$_2$$\cdot y$H$_2$O to investigate physical properties in the superconducting (SC) and normal states. Two samples from the same Na$_x$CoO$_2$ were examined, SC bilayer-hydrate sample with $T_c \sim 4.7$ K and non-SC monolayer-hydrate sample. From the measurement of nuclear-spin lattice relaxation rate $1/T_1$ in the SC sample, it was found that the coherence peak is absent just below $T_c$ and that $1/T_1$ is proportional to temperature far below $T_c$. These results, which are in qualitatively agreement with the previous result by Fujimoto {\it et al.}, suggest strongly that unconventional superconductivity is realized in this compound. In the normal state, $1/T_1T$ of the SC sample shows gradual increase below 100K down to $T_c$, whereas $1/T_1T$ of the non-SC sample shows the Korringa behavior in this temperature range. From the comparison between $1/T_1T$ and $\chi_{\rm bulk}$ in the SC sample, the increase of $1/T_1T$ is attributed to nearly ferromagnetic fluctuations. These remarkable findings suggest that the SC sample possesses nearly ferromagnetic fluctuations, which are possibly related with the unconventional superconductivity in this compound. The implication of this finding is discussed.Comment: 4 pages, 5 figures. submitted to J. Phys. Soc. Jp