Highly stable and active Ni-doped ordered mesoporous carbon catalyst on the steam reforming of ethanol application

AbstractA novel one-step direct synthesis of nickel embedded in an ordered mesoporous carbon catalyst (NiOMC) is done in a basic medium of nonaqueous solution by a solvent evaporation-induced self-assembly process. The NiOMC sample is characterized by a variety of analytical and spectroscopy techniques, e.g., N2 adsorption/desorption isotherm measurement, X-ray diffraction (XRD), transmission electron microscopy (TEM) and temperature-programed reduction (TPR). In this study, the NiOMC catalyst is found to exhibit superior catalytic activity for the steam reforming of ethanol (SRE), showing high hydrogen selectivity and durability. Ethanol can be completely converted at 350°C over the NiOMC catalyst. Also, the durability of the NiOMC catalyst on the SRE reaction exceeds 100h at 450°C, with SH2 approaching 65% and SCO of less than 1%

Poynting vector, energy density and energy velocity in anomalous dispersion medium

The Poynting vector, energy density and energy velocity of light pulses propagating in anomalous dispersion medium (used in WKD-like experiments) are calculated. Results show that a negative energy density in the medium propagates along opposite of incident direction with such a velocity similar to the negative group velocity while the direction of the Poynting vector is positive. In other words, one might say that a positive energy density in the medium would propagate along the positive direction with a speed having approximately the absolute valueof the group velocity. We further point out that neither energy velocity nor group velocity is a good concept to describe the propagation process of light pulse inside the medium in WKD experiment owing to the strong accumulation and dissipation effects.Comment: 6 page

Two dimensional scaling of resistance in flux flow region in Tl2Ba2CaCu2O8Tl_2Ba_2CaCu_2O_8 thin films

The resistance of $Tl_2Ba_2CaCu_2O_8$ thin films has been measured when the angle between the applied fields and $ab$-plane of the film is changed continuously at various temperatures. Under various magnetic fields, the resistance can be well scaled in terms of the c-axis component of the applied fields at the same temperature in the whole angle range. Meanwhile, we show that the measurement of resistance in this way is a complementary method to determine the growth orientation of the anisotropic high-$T_c$ superconductors.Comment: 11 pages, 8 figures. Have been published in Physica

Electronic and magnetic structures of the rare-earth compounds R\u3csub\u3e2\u3c/sub\u3eFe\u3csub\u3e17\u3c/sub\u3eN\u3csub\u3eξ\u3c/sub\u3e

Structural and magnetic properties of the rare-earth compounds R2Fe17Nξ have been studied with neutron-diffraction measurements and self-consistent spin-polarized electronic-structure calculations. The diffraction results indicate for the Nd compound that N goes into two sites in two or more phases of varying fractional N occupations. For the Y compound N occupies only one site. Electronic-structure calculations for Y2Fe17 and Y2Fe17N3 give excellent results for site-dependent Fe moments, and, with spin-fluctuation theory, explain the large change in the Curie temperature on nitrogenation

Therapeutic Antibodies Targeting CSF1 Impede Macrophage Recruitment in a Xenograft Model of Tenosynovial Giant Cell Tumor

Tenosynovial giant cell tumor is a neoplastic disease of joints that can cause severe morbidity. Recurrences are common following local therapy, and no effective medical therapy currently exists. Recent work has demonstrated that all cases overexpress macrophage colony-stimulating factor (CSF1), usually as a consequence of an activating gene translocation, resulting in an influx of macrophages that form the bulk of the tumor. New anti-CSF1 drugs have been developed; however there are no preclinical models suitable for evaluation of drug benefits in this disease. In this paper, we describe a novel renal subcapsular xenograft model of tenosynovial giant cell tumor. Using this model, we demonstrate that an anti-CSF1 monoclonal antibody significantly inhibits host macrophage infiltration into this tumor. The results from this model support clinical trials of equivalent humanized agents and anti-CSF1R small molecule drugs in cases of tenosynovial giant cell tumor refractory to conventional local therapy

Efficient Agrobacterium tumefaciens -mediated transformation of Malus zumi (Matsumura) Rehd using leaf explant regeneration system

Malus zumi is known as an excellent dwarfing apple rootstock occurring in natural or arid/semiarid soil or salina. Gene manipulation of M. zumi through transgenic technology can modify plant feature for further improvement fruit tree production by grafting the scion on a transgenic rootstock. Here, we report the establishment of an efficient, in vitro, shoot regeneration system and Agrobacterium tumefaciens - mediated transformation from the leaf explants for Malus zumi (Matsumura) Rehd. Leaf explants were infected with Agrobacterium strains containing nptII and gus gene. The highest frequency of shoot regeneration was obtained on MS medium containing 500 mg l-1 Lactalbumin hydrolysate, 30 g l-1 fructose, supplemented with 3.0 mg l-1 BA, 0.2 mg l-1 NAA.Using fructose instead of sucrose significantly increases the shoot regeneration and decreases vitrification. This regeneration procedure was incorporated into an Agrobacterium-mediated transformation procedure in M. zumi. Kanamycin was an efficient selective agent for selection. Pre-selection (5 days after co-cultivation) improved the transformation efficiency. The emergence of expected bands by PCR analysis and Southern blot in transgenic plantlets confirmed the transformation of foreign DNA into plant genome

Merging binary black holes formed through double-core evolution

Context. To date, various formation channels of merging events have been heavily explored with the detection of nearly 100 double black hole (BH) merger events reported by the LIGO-Virgo-KAGRA (LVK) Collaboration. In this paper, we systematically investigate an alternative formation scenario: binary BHs (BBHs) formed through double helium stars (hereafter, “double-core evolution channel”). In this scenario, two helium stars (He-rich stars) could be the outcome of the classical isolated binary evolution scenario with and without the common envelope (CE) phase (i.e., CE channel and stable mass transfer channel) or, alternatively, of massive close binaries evolving chemically homogeneously (i.e., CHE channel). Aims. We study the properties (i.e., the chirp masses and the effective spins) of BBHs formed through the double-core evolution and investigate the impact of different efficiencies of angular momentum transport within massive He-rich stars on double-core evolution. Methods. We performed detailed stellar structure and binary evolution calculations that take into account internal rotation and mass loss of He-rich stars as well as tidal interactions in binaries. We systematically studied the parameter space of initial binary He-rich stars, including the initial mass and metallicity of He-rich stars as well as initial orbital periods. Apart from direct core collapse with mass and angular momentum conserved, we also follow the framework in Batta & Ramirez-Ruiz (2019, ArXiv e-prints [arXiv:1904.04835]) to estimate the mass and spin of the resulting BHs. Results. We show that the radii of massive He-rich stars decrease as a function of time, which comes mainly from mass loss and mixing in high metallicity and from mixing in low metallicity. For double He-rich stars with equal masses in binaries, we find that tides start to be at work on the zero age helium main sequence (i.e., the time when a He-rich star starts to burn helium in the core, which is analogous to zero age main sequence for core hydrogen burning) for initial orbital periods not longer than 1.0 day, depending on the initial metallicities. In addition to the stellar mass-loss rate and tidal interactions in binaries, we find that the role of the angular momentum transport efficiency in determining the resulting BH spins becomes stronger when considering BH progenitors originated from a higher metal-metallicity environment. We highlight that the double-core evolution scenario does not always produce fast-spinning BBHs and compare the properties of the BBHs reported from the LVK with our modeling. Conclusions. After detailed binary calculations of double-core evolution, we have confirmed that the spin of the BH is not only determined by the interplay of the binary’s different initial conditions (metallicity, mass, and orbital period) but is also dependent on the angular momentum transport efficiency within its progenitor. We predict that with the sensitivity improvements to the LVK’s next observing run (O4), the sample of merging BBHs will contain more sources with positive but moderate (even high) χeff and part of the events will likely show to have been formed through the double-core evolution channel

Edge states and topological orders in the spin liquid phases of star lattice

A group of novel materials can be mapped to the star lattice, which exhibits some novel physical properties. We give the bulk-edge correspondence theory of the star lattice and study the edge states and their topological orders in different spin liquid phases. The bulk and edge-state energy structures and Chern number depend on the spin liquid phases and hopping parameters because the local spontaneous magnetic flux in the spin liquid phase breaks the time reversal and space inversion symmetries. We give the characteristics of bulk and edge energy structures and their corresponding Chern numbers in the uniform, nematic and chiral spin liquids. In particular, we obtain analytically the phase diagram of the topological orders for the chiral spin liquid states SL[\phi,\phi,-2\phi], where \phi is the magnetic flux in two triangles and a dodecagon in the unit cell. Moreover, we find the topological invariance for the spin liquid phases, SL[\phi_{1},\phi_{2},-(\phi_{1}+\phi_{2})] and SL[\phi_{2},\phi_{1},-(\phi_{1}+\phi_{2})]. The results reveal the relationship between the energy-band and edge-state structures and their topological orders of the star lattice.Comment: 7 pages, 8 figures, 1 tabl

Correlation between muonic levels and nuclear structure in muonic atoms

A method that deals with the nucleons and the muon unitedly is employed to investigate the muonic lead, with which the correlation between the muon and nucleus can be studied distinctly. A "kink" appears in the muonic isotope shift at a neutron magic number where the nuclear shell structure plays a key role. This behavior may have very important implications for the experimentally probing the shell structure of the nuclei far away from the $\beta$-stable line. We investigate the variations of the nuclear structure due to the interaction with the muon in the muonic atom and find that the nuclear structure remains basically unaltered. Therefore, the muon is a clean and reliable probe for studying the nuclear structure. In addition, a correction that the muon-induced slight change in the proton density distribution in turn shifts the muonic levels is investigated. This correction to muonic level is as important as the Lamb shift and high order vacuum polarization correction, but is larger than anomalous magnetic moment and electron shielding correction.Comment: 2 figure