Extremely strong-coupling superconductivity and anomalous lattice properties in the beta-pyrochlore oxide KOs2O6

Superconducting and normal-state properties of the beta-pyrochlore oxide KOs2O6 are studied by means of thermodynamic and transport measurements. It is shown that the superconductivity is of conventional s-wave type and lies in the extremely strong-coupling regime. Specific heat and resistivity measurements reveal that there are characteristic low-energy phonons that give rise to unusual scattering of carriers due to strong electron-phonon interactions. The entity of the low-energy phonons is ascribed to the heavy rattling of the K ion confined in an oversized cage made of OsO6 octahedra. It is suggested that this electron-rattler coupling mediates the Cooper pairing, resulting in the extremely strong-coupling superconductivity.Comment: 17 pages (only 4 pages included here. go to http://hiroi.issp.u-tokyo.ac.jp/Published%20papers/K-SC6.pdf for full pages), to be published in PR

Effects of Rattling Phonons on the Quasiparticle Excitation and Dynamics in the Superconducting β\beta-Pyrochlore KOs2_2O6_6

Microwave penetration depth $\lambda$ and surface resistance at 27 GHz are measured in high quality crystals of KOs$_2$O$_6$. Firm evidence for fully-gapped superconductivity is provided from $\lambda(T)$. Below the second transition at $T_{\rm p}\sim 8$ K, the superfluid density shows a step-like change with a suppression of effective critical temperature $T_{\rm c}$. Concurrently, the extracted quasiparticle scattering time shows a steep enhancement, indicating a strong coupling between the anomalous rattling motion of K ions and quasiparticles. The results imply that the rattling phonons help to enhance superconductivity, and that K sites freeze to an ordered state with long quasiparticle mean free path below $T_{\rm p}$.Comment: 5 pages, 5 figures, to be published in Phys. Rev. Let

Non-magnetic pair-breaking effect on La(Fe_{1-x}Zn_{x})AsO_{0.85} studied by NMR and NQR

$^{75}$As and $^{139}$La NMR and nuclear quadrupole resonance (NQR) studies on Zn-substituted LaFeAsO$_{0.85}$ have been performed to investigate the Zn-impurity effects microscopically. Although superconductivity in LaFeAsO$_{0.85}$ disappears by 3% Zn substitution, we found that NMR/NQR spectra and NMR physical quantities in the normal state are hardly changed, indicating that the crystal structure and electronic states are not modified by Zn substitution. Our results suggest that the suppression of superconductivity by Zn substitution is not due to the change of the normal-state properties, but due to strong non-magnetic pair-breaking effect to superconductivity.Comment: 5 pages, 4 figures, This paper was chosen as "Paper of Editors' Suggestion

Vortex Redistribution below the First-Order Transition Temperature in the \beta-Pyrochlore Superconductor KOs_2O_6

A miniature Hall sensor array was used to detect magnetic induction locally in the vortex states of the $\beta$-pyrochlore superconductor KOs$_2$O$_6$. Below the first-order transition at $T_{\rm p}\sim 8$ K, which is associated with a change in the rattling motion of K ions, the lower critical field and the remanent magnetization both show a distinct decrease, suggesting that the electron-phonon coupling is weakened below the transition. At high magnetic fields, the local induction shows an unexpectedly large jump at $T_{\rm p}$ whose sign changes with position inside the sample. Our results demonstrate a novel redistribution of vortices whose energy is reduced abruptly below the first-order transition at $T_{\rm p}$.Comment: 5 pages, 4 figures, to be published in Phys. Rev. Let

Structural Phase Transition in the Superconducting Pyrochlore Oxide Cd2Re2O7

We report a structural phase transition found at Ts = 200 K in a pyrochlore oxide Cd2Re2O7 which shows superconductivity at Tc = 1.0 K. X-ray diffractionexperiments indicate that the phase transition is of the second order, from a high-temperature phase with the ideal cubic pyrochlore structure (space group Fd-3m) to a low-temperature phase with another cubic structure (space group F-43m). It is accompanied by a dramatic change in the resistivity and magnetic susceptibility and thus must induce a significant change in the electronic structure of Cd2Re2O7.Comment: 4 pages, 4figures, proceeding for ISSP