Anomalous Nernst and Hall effects in magnetized platinum and palladium

We study the anomalous Nernst effect (ANE) and anomalous Hall effect (AHE) in proximity-induced ferromagnetic palladium and platinum which is widely used in spintronics, within the Berry phase formalism based on the relativistic band structure calculations. We find that both the anomalous Hall ($\sigma_{xy}^A$) and Nernst ($\alpha_{xy}^A$) conductivities can be related to the spin Hall conductivity ($\sigma_{xy}^S$) and band exchange-splitting ($\Delta_{ex}$) by relations $\sigma_{xy}^A =\Delta_{ex}\frac{e}{\hbar}\sigma_{xy}^S(E_F)'$ and $\alpha_{xy}^A = -\frac{\pi^2}{3}\frac{k_B^2T\Delta_{ex}}{\hbar}\sigma_{xy}^s(\mu)"$, respectively. In particular, these relations would predict that the $\sigma_{xy}^A$ in the magnetized Pt (Pd) would be positive (negative) since the $\sigma_{xy}^S(E_F)'$ is positive (negative). Furthermore, both $\sigma_{xy}^A$ and $\alpha_{xy}^A$ are approximately proportional to the induced spin magnetic moment ($m_s$) because the $\Delta_{ex}$ is a linear function of $m_s$. Using the reported $m_s$ in the magnetized Pt and Pd, we predict that the intrinsic anomalous Nernst conductivity (ANC) in the magnetic platinum and palladium would be gigantic, being up to ten times larger than, e.g., iron, while the intrinsic anomalous Hall conductivity (AHC) would also be significant.Comment: Accepted for publication in the Physical Review

Nuclear β+\beta^+/EC decays in covariant density functional theory and the impact of isoscalar proton-neutron pairing

Self-consistent proton-neutron quasiparticle random phase approximation based on the spherical nonlinear point-coupling relativistic Hartree-Bogoliubov theory is established and used to investigate the $\beta^+$/EC-decay half-lives of neutron-deficient Ar, Ca, Ti, Fe, Ni, Zn, Cd, and Sn isotopes. The isoscalar proton-neutron pairing is found to play an important role in reducing the decay half-lives, which is consistent with the same mechanism in the $\beta$ decays of neutron-rich nuclei. The experimental $\beta^+$/EC-decay half-lives can be well reproduced by a universal isoscalar proton-neutron pairing strength.Comment: 12 pages, 4 figure

Numerical simulation of two-phase cross flow in the gas diffusion layer microstructure of proton exchange membrane fuel cells

The cross flow in the under-land gas diffusion layer (GDL) between 2 adjacent channels plays an important role on water transport in proton exchange membrane fuel cell. A 3-dimensional (3D) two-phase model that is based on volume of fluid is developed to study the liquid water-air cross flow within the GDL between 2 adjacent channels. By considering the detailed GDL microstructures, various types of air-water cross flows are investigated by 3D numerical simulation. Liquid water at 4 locations is studied, including droplets at the GDL surface and liquid at the GDL-catalyst layer interface. It is found that the water droplet at the higher-pressure channel corner is easier to be removed by cross flow compared with droplets at other locations. Large pressure difference Δp facilitates the faster water removal from the higher-pressure channel. The contact angle of the GDL fiber is the key parameter that determines the cross flow of the droplet in the higher-pressure channel. It is observed that the droplet in the higher-pressure channel is difficult to flow through the hydrophobic GDL. Numerical simulations are also performed to investigate the water emerging process from different pores of the GDL bottom. It is found that the amount of liquid water removed by cross flow mainly depends on the pore's location, and the water under the land is removed entirely into the lower-pressure channel by cross flow

Study on QoS support in 802.11e-based multi-hop vehicular wireless ad hoc networks

Multimedia communications over vehicular ad hoc networks (VANET) will play an important role in the future intelligent transport system (ITS). QoS support for VANET therefore becomes an essential problem. In this paper, we first study the QoS performance in multi-hop VANET by using the standard IEEE 802.11e EDCA MAC and our proposed triple-constraint QoS routing protocol, Delay-Reliability-Hop (DeReHQ). In particular, we evaluate the DeReHQ protocol together with EDCA in highway and urban areas. Simulation results show that end-to-end delay performance can sometimes be achieved when both 802.11e EDCA and DeReHQ extended AODV are used. However, further studies on cross-layer optimization for QoS support in multi-hop environment are required

Quantization and Corrections of Adiabatic Particle Transport in a Periodic Ratchet Potential

We study the transport of an overdamped particle adiabatically driven by an asymmetric potential which is periodic in both space and time. We develop an adiabatic perturbation theory after transforming the Fokker-Planck equation into a time-dependent hermitian problem, and reveal an analogy with quantum adiabatic particle transport. An analytical expression is obtained for the ensemble average of the particle velocity in terms of the Berry phase of the Bloch states. Its time average is shown to be quantized as a Chern number in the deterministic or tight-binding limit, with exponentially small corrections. In the opposite limit, where the thermal energy dominates the ratchet potential, a formula for the average velocity is also obtained, showing a second order dependence on the potential.Comment: 8 page

Carbon nanotube reinforced nanocomposites for energy conversion and storage

This is the final version. Available from Elsevier via the DOI in this record.CNT-reinforced foams comprised of three-dimensional (3D) interconnected macropores with uniform mesoporous walls were developed as multifunctional nanocomposites and tested for electrochemical energy conversion and storage. Multi-walled CNTs grown on the wall surface of the interconnected scaffold structure of carbon foams were found to improve the surface area and electrochemical properties of the nanocomposites. The lightweight CNT-reinforced nanocomposites not only exhibit high structural flexibility, but also possess enhanced electrocatalytic performance for HER at current density of 10 mA cm−2 with overpotentials of 240 mV. In addition, these nanocomposites can be used as flexible, electric double layer capacitor electrodes, and have achieved a specific capacitance of 776 F g−1, with excellent durability and stability after 1000 cycles.Engineering and Physical Sciences Research CouncilLeverhulme Trus