Van der Waals density functional: Self-consistent potential and the nature of the van der Waals bond

We derive the exchange-correlation potential corresponding to the nonlocal van der Waals density functional [M. Dion, H. Rydberg, E. Schroder, D. C. Langreth, and B. I. Lundqvist, Phys. Rev. Lett. 92, 246401 (2004)]. We use this potential for a self-consistent calculation of the ground state properties of a number of van der Waals complexes as well as crystalline silicon. For the latter, where little or no van der Waals interaction is expected, we find that the results are mostly determined by semilocal exchange and correlation as in standard generalized gradient approximations (GGA), with the fully nonlocal term giving little effect. On the other hand, our results for the van der Waals complexes show that the self-consistency has little effect at equilibrium separations. This finding validates previous calculations with the same functional that treated the fully nonlocal term as a post GGA perturbation. A comparison of our results with wave-function calculations demonstrates the usefulness of our approach. The exchange-correlation potential also allows us to calculate Hellmann-Feynman forces, hence providing the means for efficient geometry relaxations as well as unleashing the potential use of other standard techniques that depend on the self-consistent charge distribution. The nature of the van der Waals bond is discussed in terms of the self-consistent bonding charge.Comment: submitted to Phys. Rev.

How Large is the Intrinsic Flux Noise of a Magnetic Flux Quantum, of Half a Flux Quantum and of a Vortex-Free Superconductor?

This article addresses the question whether the magnetic flux of stationary vortices or of half flux quanta generated by frustrated superconducting rings is noisy. It is found that the flux noise generated intrinsically by a superconductor is, in good approximation, not enhanced by stationary vortices. Half flux quanta generated by $\pi$-rings are characterized by considerably larger noise.Comment: 11 pages, 3 figures. in: A. Bussmann-Holder, H. Keller (Eds.) High Tc Superconductors and Related Transition Metal Oxides, Springer, 237-242; also to be published in: Journal of Superconductivity (2007

Quasiparticle Interface States in Junctions Involving d-Wave Superconductors

Influence of surface pair breaking, barrier transmission and phase difference on quasiparticle bound states in junctions with d-wave superconductors is examined. Based on the quasiclassical theory of superconductivity, an approach is developed to handle interface bound states. It is shown in SIS' junctions that low energy bound states get their energies reduced by surface pair breaking, which can be taken into account by introducing an effective order parameter for each superconductor at the junction barrier. More interestingly, for the interface bound states near the continuous spectrum the effect of surface pair breaking may result in a splitting of the bound states. In the tunneling limit this can lead to a square root dependence of a nonequilibrium Josephson current on the barrier transmision, which means an enhancement as compared to the conventional critical current linear in the transmission. Reduced broadening of bound states in NIS junctions due to surface pair breaking is found.Comment: 27 pages, Latex fil

Universality versus material dependence of fluctuation forces between metallic wires

We calculate the Casimir interaction between two parallel wires and between a wire and a metall plate. The dielectric properties of the objects are described by the plasma, Drude and perfect metal models. We find that at asymptotically large separation interactions involving plasma wires and/or plates are independent of the material properties, but depend on the dc conductivity $\sigma$ for Drude wires. Counterintuitively, at intermediate separations the interaction involving Drude wires can become independent of $\sigma$. At smaller separations, we compute the interaction numerically and observe an approach to the proximity approximation

Orientation-dependent Casimir force arising from highly anisotropic crystals: application to Bi2Sr2CaCu2O8+delta

We calculate the Casimir interaction between parallel planar crystals of Au and the anisotropic cuprate superconductor Bi2Sr2CaCu2O8+delta (BSCCO), with BSCCO's optical axis either parallel or perpendicular to the crystal surface, using suitable generalizations of the Lifshitz theory. We find that the strong anisotropy of the BSCCO permittivity gives rise to a difference in the Casimir force between the two orientations of the optical axis, which depends on distance and is of order 10-20% at the experimentally accessible separations 10 to 5000 nm.Comment: 5 pages, 3 figures. Accepted for publication in Physical Review

Casimir torque

We develop a formalism for the calculation of the flow of angular momentum carried by the fluctuating electromagnetic field within a cavity bounded by two flat anisotropic materials. By generalizing a procedure employed recently for the calculation of the Casimir force between arbitrary materials, we obtain an expression for the torque between anisotropic plates in terms of their reflection amplitude matrices. We evaluate the torque in 1D for ideal and realistic model materials.Comment: 8 pages, 4 figs, Submitted to Proc. of QFEXT'05, to appear in J. Phys.

Dispersion Interactions between Optically Anisotropic Cylinders at all Separations: Retardation Effects for Insulating and Semiconducting Single Wall Carbon Nanotubes

We derive the complete form of the van der Waals dispersion interaction between two infinitely long anisotropic semiconducting/insulating thin cylinders at all separations. The derivation is based on the general theory of dispersion interactions between anisotropic media as formulated in [J. N. Munday, D. Iannuzzi, Yu. S. Barash and F. Capasso, {\sl Phys. Rev. A} {\bf 71}, 042102 (2005)]. This formulation is then used to calculate the dispersion interactions between a pair of single walled carbon nanotubes at all separations and all angles. Non-retarded and retarded forms of the interactions are developed separately. The possibility of repulsive dispersion interactions and non-monotonic dispersion interactions is discussed within the framework of the new formulation

A General Approach to Casimir Force Problems Based on Local Reflection Amplitudes and Huygen's Principle

In this paper we describe an approach to Casimir Force problems that is ultimately generalizable to all fields, boundary conditions, and cavity geometries. This approach utilizes locally defined reflection amplitudes to express the energy per unit area of any Casimir interaction. To demonstrate this approach we solve a number of Casimir Force problems including the case of uniaxial boundary conditions in a parallel-plate cavity.Comment: 9 pages, 5 figures, Equation 18 has been corrected, [v1] contained a typ

Self-consistent interface properties of d and s-wave superconductors

We develop a method to solve the Bogoliubov de Gennes equation for superconductors self-consistently, using the recursion method. The method allows the pairing interaction to be either local or non-local corresponding to s and d-wave superconductivity, respectively. Using this method we examine the properties of various S-N and S-S interfaces. In particular we calculate the spatially varying density of states and order parameter for the following geometries (i) s-wave superconductor to normal metal, (ii) d-wave superconductor to normal metal, (iii) d-wave superconductor to s-wave superconductor. We show that the density of states at the interface has a complex structure including the effects of normal surface Friedel oscillations, the spatially varying gap and Andeev states within the gap, and the subtle effects associated with the interplay of the gap and the normal van Hove peaks in the density of states. In the case of bulk d-wave superconductors the surface leads to mixing of different order parameter symmetries near the interface and substantial local filling in of the gap.Comment: 20 pages, Latex and 8 figure

Collective charge fluctuations and Casimir interactions for quasi one-dimensional metals

We investigate the Casimir interaction between two parallel metallic cylinders and between a metallic cylinder and plate. The material properties of the metallic objects are implemented by the plasma, Drude and perfect metal model dielectric functions. We calculate the Casimir interaction numerically at all separation distances and analytically at large separations. The large-distance asymptotic interaction between one plasma cylinder parallel to another plasma cylinder or plate does not depend on the material properties, but for a Drude cylinder it depends on the dc conductivity $\sigma$. At intermediate separations, for plasma cylinders the asymptotic interaction depends on the plasma wave length $\lambda_{\rm p}$ while for Drude cylinders the Casimir interaction can become independent of the material properties. We confirm the analytical results by the numerics and show that at short separations, the numerical results approach the proximity force approximation