Outstanding supercapacitive properties of Mn-doped TiO2 micro/nanostructure porous film prepared by anodization method.

Mn-doped TiO2 micro/nanostructure porous film was prepared by anodizing a Ti-Mn alloy. The film annealed at 300 °C yields the highest areal capacitance of 1451.3 mF/cm(2) at a current density of 3 mA/cm(2) when used as a high-performance supercapacitor electrode. Areal capacitance retention is 63.7% when the current density increases from 3 to 20 mA/cm(2), and the capacitance retention is 88.1% after 5,000 cycles. The superior areal capacitance of the porous film is derived from the brush-like metal substrate, which could greatly increase the contact area, improve the charge transport ability at the oxide layer/metal substrate interface, and thereby significantly enhance the electrochemical activities toward high performance energy storage. Additionally, the effects of manganese content and specific surface area of the porous film on the supercapacitive performance were also investigated in this work

Causal algebras on chain event graphs with informed missingness for system failure

Graph-based causal inference has recently been successfully applied to explore system reliability and to predict failures in order to improve systems. One popular causal analysis following Pearl and Spirtes et al. to study causal relationships embedded in a system is to use a Bayesian network (BN). However, certain causal constructions that are particularly pertinent to the study of reliability are difficult to express fully through a BN. Our recent work demonstrated the flexibility of using a Chain Event Graph (CEG) instead to capture causal reasoning embedded within engineers’ reports. We demonstrated that an event tree rather than a BN could provide an alternative framework that could capture most of the causal concepts needed within this domain. In particular, a causal calculus for a specific type of intervention, called a remedial intervention, was devised on this tree-like graph. In this paper, we extend the use of this framework to show that not only remedial maintenance interventions but also interventions associated with routine maintenance can be well-defined using this alternative class of graphical model. We also show that the complexity in making inference about the potential relationships between causes and failures in a missing data situation in the domain of system reliability can be elegantly addressed using this new methodology. Causal modelling using a CEG is illustrated through examples drawn from the study of reliability of an energy distribution network

Graph Neural Networks Boosted Personalized Tag Recommendation Algorithm

Personalized tag recommender systems recommend a set of tags for items based on users’ historical behaviors, and play an important role in the collaborative tagging systems. However, traditional personalized tag recommendation methods cannot guarantee that the collaborative signal hidden in the interactions among entities is effectively encoded in the process of learning the representations of entities, resulting in insufficient expressive capacity for characterizing the preferences or attributes of entities. In this paper, we proposed a graph neural networks boosted personalized tag recommendation model, which integrates the graph neural networks into the pairwise interaction tensor factorization model. Specifically, we consider two types of interaction graph (i.e. the user-tag interaction graph and the item-tag interaction graph) that is derived from the tag assignments. For each interaction graph, we exploit the graph neural networks to capture the collaborative signal that is encoded in the interaction graph and integrate the collaborative signal into the learning of representations of entities by transmitting and assembling the representations of entity neighbors along the interaction graphs. In this way, we explicitly capture the collaborative signal, resulting in rich and meaningful representations of entities. Experimental results on real world datasets show that our proposed graph neural networks boosted personalized tag recommendation model outperforms the traditional tag recommendation models

Online predicting conformance of business process with recurrent neural networks

Conformance Checking is a problem to detect and describe the differences between a given process model representing the expected behaviour of a business process and an event log recording its actual execution by the Process-aware Information System (PAIS). However, such existing conformance checking techniques are offline and mainly applied for the completely executed process instances, which cannot provide the real-time conformance-oriented process monitoring for an on-going process instance. Therefore, in this paper, we propose three approaches for online conformance prediction by constructing a classification model automatically based on the historical event log and the existing reference process model. By utilizing Recurrent Neural Networks, these approaches can capture the features that have a decisive effect on the conformance for an executed case to build a prediction model and then use this model to predict the conformance of a running case. The experimental results on two real datasets show that our approaches outperform the state-of-the-art ones in terms of prediction accuracy and time performance

Bootstrap procedures for detecting multiple persistence shifts in heteroskedastic time series

This article proposes new bootstrap procedures for detecting multiple persistence shifts in a time series driven by non‐stationary volatility. The assumed volatility process can accommodate discrete breaks, smooth transition variation as well as trending volatility. We develop wild bootstrap sup‐Wald tests of the null hypothesis that the process is either stationary [I(0)] or has a unit root [I(1)] throughout the sample. We also propose a sequential procedure to estimate the number of persistence breaks based on ordering the regime‐specific bootstrap p‐values. The asymptotic validity of the advocated procedures is established both under the null of stability and a variety of persistence change alternatives. A comparison with existing tests that assume homoskedasticity illustrates the finite sample improvements offered by our methods. An application to OECD inflation rates highlights the empirical relevance of the proposed approach and weakens the case for persistence change relative to existing procedures.Accepted manuscrip