Chrome-free Samarium-based Protective Coatings for Magnesium Alloys

AbstractThe microstructure of chrome-free samarium-based conversion coating on magnesium alloy was investigated and the corrosion resistance was evaluated as well. The micro-morphology, transverse section, crystal structure and composition of the coating were observed by scanning electron microscopy (SEM), X-ray diffraction (XRD), energy dispersive spectroscopy (EDS) and X- ray photoelectron spectroscopy (XPS), respectively. The corrosion resistance was evaluated by potentiodynamic polarization curve and electrochemical impedance spectroscopy (EIS). The results reveal that the morphology of samarium conversion coating is of crack-mud structure. Tiny cracks distribute in the compact coating deposited by samarium oxides. XRD, EDS and XPS results characterize that the coating is made of amorphous and trivalent-samarium oxides. The potentiodynamic polarization curve, EIS and OCP indicate that the samarium conversion coating can improve the corrosion resistance of magnesium alloys

A New Soil Sampling Design in Coastal Saline Region Using EM38 and VQT Method

Spatial sampling design based on the variability and distribution of soil properties is an important issue with the progress in precision agriculture and soil ecology. Electromagnetic induction (type EM38) and variance quad-tree (VQT) method were both applied to optimize the sampling scheme of soil salinity in a coastal reclamation field in north Jiangsu Province, China. Apparent soil electrical conductivity (ECa) measured with EM38 was used as an ancillary variable and the spatial distribution of ECa was used as priori information. The process and result of VQT algorithm analysis was illustrated and the obtained sampling strategy was validated using observed soil salinity. Then the spatial precision and sampling efficiency were evaluated. The result indicated that the spatial distribution of soil salinity produced with the VQT scheme was quite similar to that produced with total sampling sites, while sampling quantity of the former was reduced to approximately 1/2 of the latter. The spatial precision of VQT scheme was considerably higher than that of traditional grid method with respect to the same sampling number, and fewer samples were required for VQT scheme to obtain the same precision level. A 17.3% increase in sampling efficiency was achieved by VQT over grid method at the precision level of 90%. The VQT method was proved to be more efficient and economical because it can sample intensively or sparsely according to variation status in local areas. The associated application of EM38 and VQT method provides efficient tools and theoretical basis for saving sampling cost and improving sampling efficiency in coastal saline region and enriching soil ecology

Multiple target tracking under occlusions using modified Joint Probabilistic Data Association

International audienceThe size of target will induce a degradation of tracking performance, which has been neglected for simplicity in most previous studies. In multiple target tracking, occlusions will be caused by target size effect, one target can become a moving obstacle blocking the direct channel between the anchor and another target. In this paper, the data association problem in multiple target tracking is investigated. To reduce the computational complexity of traditional Joint Probabilistic Data Association (JPDA) algorithm, a modified JPDA algorithm is proposed to execute data association in multiple target tracking by utilizing the information of occlusion conditions, which is identified by a three-step algorithm. Simulation results show that the proposed algorithm is with good tracking performance and low computational complexity

Robust Localization Using Range Measurements With Unknown and Bounded Errors

Cooperative geolocation has attracted significant research interests in recent years. A large number of localization algorithms rely on the availability of statistical knowledge of measurement errors, which is often difficult to obtain in practice. Compared with the statistical knowledge of measurement errors, it can often be easier to obtain the measurement error bound. This paper investigates a localization problem assuming unknown measurement error distribution except for a bound on the error. We first formulate this localization problem as an optimization problem to minimize the worst case estimation error, which is shown to be a nonconvex optimization problem. Then, relaxation is applied to transform it into a convex one. Furthermore, we propose a distributed algorithm to solve the problem, which will converge in a few iterations. Simulation results show that the proposed algorithms are more robust to large measurement errors than existing algorithms in the literature. Geometrical analysis providing additional insights is also provided.This work was supported in part by 973 Program under Grant 2015CB352503, in part by National Program for Special Support of Top-Notch Young Professionals, in part by NSFC under Grant 61371159, in part by the Fundamental Research Funds for the Central Universities (2017XZZX009-01), in part by scholarship funded by China Scholarship Council, in part by National ICT Australia Ltd., and in part by the Australian Research Council under Grant DP-110100538, Grant DP-130103610 and Grant DP16010450

A series of lanthanide(iii) metal-organic frameworks derived from a pyridyl-dicarboxylate ligand: single-molecule magnet behaviour and luminescence properties

The reactions of LnIII ions with a versatile pyridyl-decorated dicarboxylic acid ligand lead to a series of novel three-dimensional (3D) Ln-MOFs, [Ln3(pta)4(Hpta)(H2O)]·xH2O (Ln = Dy (1), Eu (2), Gd (3), Tb (4), H2pta = 2-(4-pyridyl)-terephthalic acid, x = 6 for 1, 2.5 for 2, 1.5 for 3 and 2 for 4). The Ln3+ ions act as the nine-coordinated Muffin spheres, linking to each other to generate trinuclear {Ln3(OOC)6N2} SBUs, which are further extended to be interesting 3D topology architectures. To the best of our knowledge, the Dy-MOF exhibits a zero-field single-molecule magnet (SMM) behaviour with the largest effective energy barrier among the previously reported 3D MOF-based Dy-SMMs. The combined analyses of a dilution sample (1@Y) and ab initio calculation demonstrate that the thermally assisted slow relaxation is mainly attributed to the single-ion magnetism. Furthermore, fluorescence measurements reveal that H2pta can sensitize EuIII and TbIII characteristic luminescence