Numerical simulation of ram extrusion in short-fiber-reinforced fresh cementitious composites

This is the author's accepted manuscript. The final published article is available from the link below. First published in JoMMS in 4(10), 2009, published by Mathematical Sciences Publishers.A series of ram extrusion tests was carried out on a short-fiber-reinforced, semisolid, fresh cementitious composite. An elastoviscoplastic constitutive model is proposed for the extrudable fresh cementitious composite. It features the associative flow rule, a nonlinear strain rate-hardening law, and the von Mises yield criterion. The model is then implemented in ANSYS/LS-DYNA explicit finite element code. Various ram extrusion processes of the fresh cementitious composite were simulated. It has been found that the extrusion load versus imposed displacement predictions agree well with the experimental results. The fresh paste flow, through the die entry and the die-land, is then interpreted in light of the evolution of the deformation and distribution of state variables, mainly based on numerical results and the ram extrusion mechanism. The effects of extrusion ratio and extrusion velocity on extrusion load are also investigated, based on the mechanical properties of the fresh cementitious composite. The study indicates that the numerical procedure established, together with the constitutive model proposed, is applicable for describing ram extrusion of short-fiber-reinforced fresh cementitious composites, which might provide a numerical rheometric tool from which ram extrusion of elastoviscoplastic paste-like materials can be examined and quantified.Hong Kong Research Grant Council and China Ministry of Science and Technology

Combining remote sensing and ground census data to develop new maps of the distribution of rice agriculture in China

Large-scale assessments of the potential for food production and its impact on biogeochemical cycling require the best possible information on the distribution of cropland. This information can come from ground-based agricultural census data sets and/or spaceborne remote sensing products, both with strengths and weaknesses. Official cropland statistics for China contain much information on the distribution of crop types, but are known to significantly underestimate total cropland areas and are generally at coarse spatial resolution. Remote sensing products can provide moderate to fine spatial resolution estimates of cropland location and extent, but supply little information on crop type or management. We combined county-scale agricultural census statistics on total cropland area and sown area of 17 major crops in 1990 with a fine-resolution land-cover map derived from 1995–1996 optical remote sensing (Landsat) data to generate 0.5° resolution maps of the distribution of rice agriculture in mainland China. Agricultural census data were used to determine the fraction of crop area in each 0.5° grid cell that was in single rice and each of 10 different multicrop paddy rice rotations (e.g., winter wheat/rice), while the remote sensing land-cover product was used to determine the spatial distribution and extent of total cropland in China. We estimate that there were 0.30 million km2 of paddy rice cropland; 75% of this paddy land was multicropped, and 56% had two rice plantings per year. Total sown area for paddy rice was 0.47 million km2. Paddy rice agriculture occurred on 23% of all cultivated land in China

Nitric Oxide Synthase in Male Urological and Andrologic Functions

Nitric oxide (NO), a crucial signaling molecule, is synthesized by the nitric oxide synthase (NOS) enzyme. The significant effects of NOS are under exploration, and the roles of potential therapy targets for diseases of NOS are widely accepted. In this chapter, we summarized the important roles of NOS mainly on pathogenesis of prostate diseases, male infertility, erectile dysfunction and, addition, the potential therapeutic efficacies of NOS for those diseases

Reduced methane emissions from large-scale changes in water management of China’s rice paddies during 1980-2000

Decreased methane emissions from paddy rice may have contributed to the decline in the rate of increase of global atmospheric methane (CH4) concentration over the last 20 years. In China, midseason paddy drainage, which reduces growing season CH4 fluxes, was first implemented in the early 1980s, and has gradually replaced continuous flooding in much of the paddy area. We constructed a regional prediction for China\u27s rice paddy methane emissions using the DNDC biogeochemical model. Results of continuous flooding and midseason drainage simulations for all paddy fields in China were combined with regional scenarios for the timing of the transition from continuous flooding to predominantly mid-season drainage to generate estimates of total methane flux for 1980–2000. CH4 emissions from China\u27s paddy fields were reduced over that period by ∼5 Tg CH4 yr−1

Modeling impacts of farming management alternatives on CO2, CH4, and N2O emissions: A case study for water management of rice agriculture of China

Since the early 1980s, water management of rice paddies in China has changed substantially, with midseason drainage gradually replacing continuous flooding. This has provided an opportunity to estimate how a management alternative impacts greenhouse gas emissions at a large regional scale. We integrated a process-based model, DNDC, with a GIS database of paddy area, soil properties, and management factors. We simulated soil carbon sequestration (or net CO2 emission) and CH4 and N2O emissions from China\u27s rice paddies (30 million ha), based on 1990 climate and management conditions, with two water management scenarios: continuous flooding and midseason drainage. The results indicated that this change in water management has reduced aggregate CH4 emissions about 40%, or 5 Tg CH4 yr−1, roughly 5–10% of total global methane emissions from rice paddies. The mitigating effect of midseason drainage on CH4 flux was highly uneven across the country; the highest flux reductions (\u3e200 kg CH4-C ha−1 yr−1) were in Hainan, Sichuan, Hubei, and Guangdong provinces, with warmer weather and multiple-cropping rice systems. The smallest flux reductions (\u3c25 kg CH4-C ha−1 yr−1) occurred in Tianjin, Hebei, Ningxia, Liaoning, and Gansu Provinces, with relatively cool weather and single cropping systems. Shifting water management from continuous flooding to midseason drainage increased N2O emissions from Chinese rice paddies by 0.15 Tg N yr−1 (∼50% increase). This offset a large fraction of the greenhouse gas radiative forcing benefit gained by the decrease in CH4 emissions. Midseason drainage-induced N2O fluxes were high (\u3e8.0 kg N/ha) in Jilin, Liaoning, Heilongjiang, and Xinjiang provinces, where the paddy soils contained relatively high organic matter. Shifting water management from continuous flooding to midseason drainage reduced total net CO2emissions by 0.65 Tg CO2-C yr−1, which made a relatively small contribution to the net climate impact due to the low radiative potential of CO2. The change in water management had very different effects on net greenhouse gas mitigation when implemented across climatic zones, soil types, or cropping systems. Maximum CH4 reductions and minimum N2O increases were obtained when the mid-season draining was applied to rice paddies with warm weather, high soil clay content, and low soil organic matter content, for example, Sichuan, Hubei, Hunan, Guangdong, Guangxi, Anhui, and Jiangsu provinces, which have 60% of China\u27s rice paddies and produce 65% of China\u27s rice harvest

A novel mechanism for glycoconjugate vaccine activation of the adaptive immune system

Although glycoconjugate vaccines have provided enormous health benefits globally, they have been less successful in significant high-risk populations. Exploring novel approaches to the enhancement of glycoconjugate effectiveness, we investigated molecular and cellular mechanisms governing the immune response to a prototypical glycoconjugate vaccine. In antigen-presenting cells, a carbohydrate epitope is generated upon endolysosomal processing of group B streptococcal type III polysaccharide coupled to a carrier protein. In conjunction with a carrier protein-derived peptide, this carbohydrate epitope binds to major histocompatibility class II (MHCII) and stimulates carbohydrate-specific CD4+ T-cell clones to produce interleukins 2 and 4—cytokines essential for providing T-cell help to antibody-producing B cells. An archetypical glycoconjugate vaccine constructed to maximize the presentation of carbohydrate epitopes recognized by T cells is 50–100 times more potent and significantly more protective in an animal model of infection than is a currently used vaccine construct

Manufacturing cement-based materials and building products via extrusion: From laboratory to factory

Manufacturing is critical to the economies of the UK and many other countries in the rest of the world. However, manufacturing of cement-based materials and building products predominantly remains based on old batch processing such as casting and pressing technologies and this may limit the applications and performance of the materials and products formed. In this paper, research is reported on transforming manufacturing of precast cement-based materials and building products from in batches to continuous processes via extrusion. Techniques used for producing plastic products are transferred into manufacturing cement-based building products like flat and corrugated sheet tiles, down pipes, door/window frames, door panels, solid wall/facade panels, honeycomb wall/facade panels etc. at laboratory and factory scales. In combination with sustainable cementitious materials with low carbon and low energy as matrix, this enables sustainable building products with key characteristics required by the 21st century can be manufactured via extrusion. The cement-based building products extrusion technique has been successfully transferred to industry. For instance, fibre reinforced cement-based partition wall panels, with a honeycomb cross section as large as 600 mm wide and 90 mm high, have been produced by a continuous extrusion process in a precast concrete products factory in Hangzhou, China.European Commission Seventh Framework Programme, (grant agreement no. 262954) and from the Hong Kong Research Grants Council through grants 6091/00E, 6226/01E, 6273/03E and 6167/06

One-step Preparation and Characterization of Water-dispersible Astaxanthin Emulsion by Tween-20 under Ultrasonic Condition

In order to achieve sustainable extraction and enhance the properties of astaxanthin from Haematococcus pluvialis, a green and efficient approach was developed by utilizing Tween-20 under ultrasonic conditions. This approach allowed for the efficient release of astaxanthin while simultaneously preparing water-dispersible astaxanthin emulsions. The factors influencing the process, the formation mechanism of the water-dispersible astaxanthin emulsion, and the composition and performance characterization of the obtained product were investigated. Exploration of the process revealed that Tween-20 dosage, ultrasonic power, and solid-to-liquid ratio significantly influenced the release and dispersion efficiency of astaxanthin, with 98.41% astaxanthin being released and dispersed when Tween-20 dosage, ultrasonic power, and solid-to-liquid ratio were 200 μL, 600 W, and 1:20 g/mL, respectively. The mechanism exploration results demonstrated that ultrasound had a dual effect of disrupting the cells of H. pluvialis to a limited extent and assisting Tween-20 to disperse astaxanthin, which was superior to high-pressure homogenization. The characterization results showed that the water-dispersible astaxanthin emulsion obtained under these conditions had an average particle size of 115.55 nm, a Zeta potential of −23.35 mV, and an encapsulated astaxanthin content of up to 43.82% in the dry product. Astaxanthin was found to be encapsulated in an amorphous non-crystalline state, with selective encapsulation of saturated fatty acids. The amount of saturated fatty acids was up to 17.93% (wt.%). Overall, this one-step, ultrasonic approach to preparing water-dispersible astaxanthin emulsions from H. pluvialis using Tween-20 is easy to operate, highly efficient, green and feasible, with some of the product properties being superior to those of pure astaxanthin encapsulated products