Wetting Kinetics of Films Containing Non-Adsorbing Polymers

Kinetics of wetting by a polymer solution have been studied theoretically for a film pinned to a slot. The fluid mechanical equations have been solved using a numerical scheme. The role of polymers appears in the disjoining pressure in the model. The spreading kinetics are observed to follow a power law: a power of (1/4) is observed at short times due to the Laplace pressure, and (1/2) at large times under the Hamaker part of the disjoining pressure at very large times and with no equilibration. It is argued and demonstrated that techniques which have low resolutions such as microscopy will measure quite different kinetics: at short times a power of (1/4) as for wetting liquids and then a sudden equilibration as reported in these experiments. It is also argued on the basis of steric exclusion, and quantified in the disjoining pressure, that the behavior returns to that of wetting liquids when the polymer molecular weight becomes very high, as also observed in the experiments. Examples of how these features can find practical applications, and hence, the importance of use of polymers as additives are given

2-tert-Butyl-4-chloro-5-[4-(2-fluoro­eth­oxy)benz­yloxy]pyridazin-3(2H)-one

In the title compound, C17H20ClFN2O3, the dihedral angle between the pyridazine and benzene rings is 41.37 (10)°. In the crystal, there are no significant intermolecular interactions present. The terminal –CH2F group is disordered over two sets of sites with an occupancy ratio of 0.737 (2):0.263 (2)

Helicity Dependent Directional Surface Plasmon Polariton Excitation Using A Metasurface with Interfacial Phase Discontinuity

Surface plasmon polaritons (SPPs) have been widely exploited in various scientific communities, ranging from physics, chemistry to biology, due to the strong confinement of light to the metal surface. For many applications it is important that the free space photon can be coupled to SPPs in a controllable manner. In this Letter, we apply the concept of interfacial phase discontinuity for circularly polarizations on a metasurface to the design of a novel type of polarization dependent SPP unidirectional excitation at normal incidence. Selective unidirectional excitation of SPPs along opposite directions is experimentally demonstrated at optical frequencies by simply switching the helicity of the incident light. This approach, in conjunction with dynamic polarization modulation techniques, opens gateway towards integrated plasmonic circuits with electrically reconfigurable functionalities.Comment: 17 pages, 5 figures. Published on <Light:Science & Applications

Invertibility of Nonlinear Differential-Algebraic-Equation Subsystems with Application to Power Systems

For nonlinear differential-algebraic-equation subsystems, whose index is one and interconnection input is locally measurable, the problem of invertibility is discussed and the results are applied to the power systems component decentralized control. The inverse systems’ definitions for such a class of differential-algebraic-equation subsystems are put forward. A recursive algorithm is proposed to judge whether the controlled systems are invertible. Then physically feasible α-order integral right inverse systems are constructed, with which the composite systems are linearizaed and decoupled. Finally, decentralized excitation and valve coordinative control for one synchronous generator within multimachine power systems are studied and the simulation results based on MATLAB demonstrate the effectiveness of the control scheme proposed in this paper

HSP70: a promising target for laryngeal carcinoma radiaotherapy by inhibiting cleavage and degradation of nucleolin

Previous studies have shown that heat shock proteins (HSPs) were upregulated in various types of tumors and were associated with histological grade, recurrence and metastasis of malignant tumors. In this study, we investigated whether heat shock protein 70 kDa (HSP70) was associated with histological grade of laryngeal squamous cell carcinomas (LSCC). We also determine the role of HSP70 in LSCC radiation resistance using a laryngeal carcinoma xenograft model by antisense HSP70 RNA technique. Immunohistochemistry data showed that HSP70 was detected in 96% of LSCC tissues (48 out of 50). The expression level of HSP70 was significantly lower in early stage of LSCC than that in late stage (P = 0.015). Radiation treatment result showed that the volumes and weights of implantation tumors in the group injected with antisense HSP70 oligos were significantly reduced comparing to the group injected with random oligos(p < 0.05). In addition, cleavage and degradation of tumor nucleolin in antisense HSP70 oligos injection group was significantly higher than that in random oligos injection group. Our result suggested that HSP70 may play a role in LSCC radiotherapy resistance by inhibiting cleavage and degradation of nucleolin

Mechanistic examination of causes for narrow distribution in an endangered shrub: a comparison of its responses to drought stress with a widespread congeneric species

Although deep rooting is usually considered a drought-tolerant trait, we found that Syringapinnatifolia, a deep rooting and hydrotropic shrub, has a limited distribution in arid areas. To elucidate the mechanisms for its narrow distribution, we conducted two experiments to examine the physiological and morphological responses to water availability and heterogeneity in S. pinnatifolia and a widespread congeneric species, S. oblata. We measured gas exchange, water use efficiency, and plasticity index in plants of these two species grown at different levels of soil water regimes and in containers with patched water distribution. Our results showed that high photosynthetic capacity in the narrowly distributed S. pinnatifolia was an important factor enabling its survival in the harsh sub-alpine environment. High photosynthetic capacity in S. pinnatifolia, however, was obtained at the expense of high transpiratory water loss, resulting in lower integrative water use efficiency. Biomass allocation to roots in S. pinnatifolia increased by 73 % when soil water increased from 75 to 95 % field capacity, suggesting that S. pinnatifolia could be less competitive for above-ground resources under favorable water regimes. The horizontal root hydrotropism and vertical root hydrotropism of S. pinnatifolia in soil with patched water patterns were likely related to compensation for leaf water loss at low soil water level, indicating a limited capacity for homeostasis within the plant for water conservation and lower level of inherent drought-tolerance. In summary, greater degree of morphological plasticity but lower degree of physiological adjustment may be the main causes for the hydrotropism and narrow distribution of S. pinnatifolia in the sub-alpine habitats

Effect of acidification treatment on the extraction performance of coking coal

In order to study the influence mechanism of minerals removal from coal on solvent extraction behavior, different concentrations of tetrahydrofuran (THF) solvents were used to extract coking coal before and after acidification with hydrochloric acid (HCl) and hydrofluoric acid (HF). With the help of conventional coal quality analysis and GC-MS test methods, the differences of THF extraction rate and extract composition before and after demineralization of coal samples were analyzed, and the influence mechanism of solvent concentration, extraction time, temperature and minerals was discussed. The results show that: ①After acidification, the ash yield of coal sample reaches 97.3%, the content decreases significantly, the fixed carbon content increases by 21%, the volatile content increases relatively, but the moisture content remains basically unchanged; The contents of C and H decrease, while the contents of O, N and S increase, among which the contents of C and O change significantly. ②The extraction rate of coal samples after acidification increase significantly, but with the increase of THF concentration, the increase of extraction rate show a decreasing trend. The same extraction effect is achieved under the same conditions, and the extraction time of acidified coal is 1.25~5 times faster than that of raw coal; Acidification treatment enlarges the effect of temperature on extraction rate, which makes the extraction advantage at 35 ℃ more obvious. ③The relative content of heteroatom compounds in raw coal extracts is the highest, while aliphatic hydrocarbons are the main components in acidified coal extracts, among which the content of straight chain hydrocarbons increases with the increase of THF concentration, accounting for 91.92% of the total content. The number of carbon atoms is mainly concentrated in C15~C22, but the number of extracted species is significantly less than that of raw coal. Generally speaking, acidification treatment can effectively improve the extraction capacity of THF, greatly shorten the extraction time, and improve the extraction capacity of high carbon alkanes in coal. In addition, although water does not dominate the extraction process, it will also affect the extraction ability of THF to a certain extent, making the extraction ability of low concentration THF solvent better than that of pure THF solvent