Intercomparison of standard resolution and high resolution TOVS soundings with radiosonde, lidar, and surface temperature/humidity data

One objective of the FIRE Cirrus IFO is to characterize relationships between cloud properties inferred from satellite observations at various scales to those obtained directly or inferred from very high resolution measurements. Satellite derived NOAA-9 high and standard resolution Tiros Operational Vertical Sounder (TOVS) soundings are compared with directly measured lidar, surface temperature, humidity, and vertical radiosonde profiles associated with the Ft. McCoy site. The results of this intercomparison should be useful in planning future cloud experiments

Investigations of excitation energy transfer and intramolecular interactions in a nitrogen corded distrylbenzene dendrimer system.

The photophysics of an amino-styrylbenzene dendrimer (A-DSB) system is probed by time-resolved and steady state luminescence spectroscopy. For two different generations of this dendrimer, steady state absorption, emission, and photoluminescence excitation spectra are reported and show that the efficiency of energy transfer from the dendrons to the core is very close to 100%. Ultrafast time-resolved fluorescence measurements at a range of excitation and detection wavelengths suggest rapid (and hence efficient) energy transfer from the dendron to the core. Ultrafast fluorescence anisotropy decay for different dendrimer generations is described in order to probe the energy migration processes. A femtosecond time-scale fluorescence depolarization was observed with the zero and second generation dendrimers. Energy transfer process from the dendrons to the core can be described by a Förster mechanism (hopping dynamics) while the interbranch interaction in A-DSB core was found to be very strong indicating the crossover to exciton dynamics

The Asymptotic Giant Branches of GCs: Selective Entry Only

The handful of available observations of AGB stars in Galactic Globular Clusters suggest that the GC AGB populations are dominated by cyanogen-weak stars. This contrasts strongly with the distributions in the RGB (and other) populations, which generally show a 50:50 bimodality in CN band strength. If it is true that the AGB populations show very different distributions then it presents a serious problem for low mass stellar evolution theory, since such a surface abundance change going from the RGB to AGB is not predicted by stellar models. However this is only a tentative conclusion, since it is based on very small AGB sample sizes. To test whether this problem really exists we have carried out an observational campaign specifically targeting AGB stars in GCs. We have obtained medium resolution spectra for about 250 AGB stars across 9 Galactic GCs using the multi-object spectrograph on the AAT (2df/AAOmega). We present some of the preliminary findings of the study for the second parameter trio of GCs: NGC 288, NGC 362 and NGC 1851. The results indeed show that there is a deficiency of stars with strong CN bands on the AGB. To confirm that this phenomenon is robust and not just confined to CN band strengths and their vagaries, we have made observations using FLAMES/VLT to measure elemental abundances for NGC 6752.We present some initial results from this study also. Our sodium abundance results show conclusively that only a subset of stars in GCs experience the AGB phase of evolution. This is the first direct, concrete confirmation of the phenomenon.Comment: 4 pages, to appear in conference proceedings of "Reading the book of globular clusters with the lens of stellar evolution", Rome, 26-28 November 201

Sodium content as a predictor of the advanced evolution of globular cluster stars

The asymptotic giant branch (AGB) phase is the final stage of nuclear burning for low-mass stars. Although Milky Way globular clusters are now known to harbour (at least) two generations of stars they still provide relatively homogeneous samples of stars that are used to constrain stellar evolution theory. It is predicted by stellar models that the majority of cluster stars with masses around the current turn-off mass (that is, the mass of the stars that are currently leaving the main sequence phase) will evolve through the AGB phase. Here we report that all of the second-generation stars in the globular cluster NGC 6752 -- 70 per cent of the cluster population -- fail to reach the AGB phase. Through spectroscopic abundance measurements, we found that every AGB star in our sample has a low sodium abundance, indicating that they are exclusively first-generation stars. This implies that many clusters cannot reliably be used for star counts to test stellar evolution timescales if the AGB population is included. We have no clear explanation for this observation.Comment: Published in Nature (online 29 May 2013, hard copy 13 June), 12 pages, 3 figures + supplementary information sectio

Beyond the Brim of the Hat: Kinematics of Globular Clusters out to Large Radius in the Sombrero Galaxy

We have obtained radial velocity measurements for 51 new globular clusters around the Sombrero galaxy. These measurements were obtained using spectroscopic observations from the AAOmega spectrograph on the Anglo-Australian Telescope and the Hydra spectrograph at WIYN. Combined with our own past measurements and velocity measurements obtained from the literature we have constructed a large database of radial velocities that contains a total of 360 confirmed globular clusters. Previous studies' analyses of the kinematics and mass profile of the Sombrero globular cluster system have been constrained to the inner ~9' (~24 kpc or ~5 effective radii), but our new measurements have increased the radial coverage of the data, allowing us to determine the kinematic properties of M104 out to ~15' (~41 kpc or ~9 effective radii). We use our set of radial velocities to study the GC system kinematics and to determine the mass profile and V-band mass-to-light profile of the galaxy. We find that the V-band mass-to-light ratio increases from 4.5 at the center to a value of 20.9 at 41 kpc (~9 effective radii or 15'), which implies that the dark matter halo extends to the edge of our available data set. We compare our mass profile at 20 kpc (~4 effective radii or ~7.4') to the mass computed from x-ray data and find good agreement. We also use our data to look for rotation in the globular cluster system as a whole, as well as in the red and blue subpopulations. We find no evidence for significant rotation in any of these samples.Comment: Accepted for publication in the Astronomical Journal; 23 pages, 14 figures, and 2 table

A decade of Australian methotrexate dosing errors

"OBJECTIVE: Accidental daily dosing of methotrexate can result in life-threatening toxicity. We investigated methotrexate dosing errors reported to the National Coronial Information System (NCIS), the Therapeutic Goods Administration Database of Adverse Event Notifications (TGA DAEN) and Australian Poisons Information Centres (PICs). DESIGN AND SETTING: A retrospective review of coronial cases in the NCIS (2000-2014), and of reports to the TGA DAEN (2004-2014) and Australian PICs (2004-2015). Cases were included if dosing errors were accidental, with evidence of daily dosing on at least 3 consecutive days. MAIN OUTCOME MEASURES: Events per year, dose, consecutive days of methotrexate administration, reasons for the error, clinical features. RESULTS: Twenty-two deaths linked with methotrexate were identified in the NCIS, including seven cases in which erroneous daily dosing was documented. Methotrexate medication error was listed in ten cases in the DAEN, including two deaths. Australian PIC databases contained 92 cases, with a worrying increase seen during 2014-2015. Reasons for the errors included patient misunderstanding and incorrect packaging of dosette packs by pharmacists. The recorded clinical effects of daily dosage were consistent with those previously reported for methotrexate toxicity. CONCLUSION: Dosing errors with methotrexate can be lethal and continue to occur despite a number of safety initiatives in the past decade. Further strategies to reduce these preventable harms need to be implemented and evaluated. Recent suggestions include further changes in packet size, mandatory weekly dosing labelling on packaging, improving education, and including alerts in prescribing and dispensing software."NHMRC Program Grant: 105517