Interfaces within graphene nanoribbons

We study the conductance through two types of graphene nanostructures: nanoribbon junctions in which the width changes from wide to narrow, and curved nanoribbons. In the wide-narrow structures, substantial reflection occurs from the wide-narrow interface, in contrast to the behavior of the much studied electron gas waveguides. In the curved nanoribbons, the conductance is very sensitive to details such as whether regions of a semiconducting armchair nanoribbon are included in the curved structure -- such regions strongly suppress the conductance. Surprisingly, this suppression is not due to the band gap of the semiconducting nanoribbon, but is linked to the valley degree of freedom. Though we study these effects in the simplest contexts, they can be expected to occur for more complicated structures, and we show results for rings as well. We conclude that experience from electron gas waveguides does not carry over to graphene nanostructures. The interior interfaces causing extra scattering result from the extra effective degrees of freedom of the graphene structure, namely the valley and sublattice pseudospins

Interfaces Within Graphene Nanoribbons

We study the conductance through two types of graphene nanostructures: nanoribbon junctions in which the width changes from wide to narrow, and curved nanoribbons. In the wide-narrow structures, substantial reflection occurs from the wide-narrow interface, in contrast to the behavior of the much studied electron gas waveguides. In the curved nanoribbons, the conductance is very sensitive to details such as whether regions of a semiconducting armchair nanoribbon are included in the curved structure -- such regions strongly suppress the conductance. Surprisingly, this suppression is not due to the band gap of the semiconducting nanoribbon, but is linked to the valley degree of freedom. Though we study these effects in the simplest contexts, they can be expected to occur for more complicated structures, and we show results for rings as well. We conclude that experience from electron gas waveguides does not carry over to graphene nanostructures. The interior interfaces causing extra scattering result from the extra effective degrees of freedom of the graphene structure, namely the valley and sublattice pseudospins.Comment: 19 pages, published version, several references added, small changes to conclusion

Edge effects in graphene nanostructures: I. From multiple reflection expansion to density of states

We study the influence of different edge types on the electronic density of states of graphene nanostructures. To this end we develop an exact expansion for the single particle Green's function of ballistic graphene structures in terms of multiple reflections from the system boundary, that allows for a natural treatment of edge effects. We first apply this formalism to calculate the average density of states of graphene billiards. While the leading term in the corresponding Weyl expansion is proportional to the billiard area, we find that the contribution that usually scales with the total length of the system boundary differs significantly from what one finds in semiconductor-based, Schr\"odinger type billiards: The latter term vanishes for armchair and infinite mass edges and is proportional to the zigzag edge length, highlighting the prominent role of zigzag edges in graphene. We then compute analytical expressions for the density of states oscillations and energy levels within a trajectory based semiclassical approach. We derive a Dirac version of Gutzwiller's trace formula for classically chaotic graphene billiards and further obtain semiclassical trace formulae for the density of states oscillations in regular graphene cavities. We find that edge dependent interference of pseudospins in graphene crucially affects the quantum spectrum.Comment: to be published in Phys. Rev.

Impurity and edge roughness scattering in armchair graphene nanoribbons: Boltzmann approach

The conductivity of armchair graphene nanoribbons in the presence of short-range impurities and edge roughness is studied theoretically using the Boltzmann transport equation for quasi-one-dimensional systems. As the number of occupied subbands increases, the conductivity due to short-range impurities converges towards the two-dimensional case. Calculations of the magnetoconductivity confirm the edge-roughness-induced dips at cyclotron radii close to the ribbon width suggested by the recent quantum simulations

Drifting inwards in protoplanetary discs I Sticking of chondritic dust at increasing temperatures

Sticking properties rule the early phases of pebble growth in protoplanetary discs in which grains regularly travel from cold, water-rich regions to the warm inner part. This drift affects composition, grain size, morphology, and water content as grains experience ever higher temperatures. In this study we tempered chondritic dust under vacuum up to 1400 K. Afterwards, we measured the splitting tensile strength of millimetre-sized dust aggregates. The deduced effective surface energy starts out as $\gamma_e = 0.07\,\rm J/m^2$. This value is dominated by abundant iron-oxides as measured by M\"ossbauer spectroscopy. Up to 1250 K, $\gamma_e$ continuously decreases by up to a factor five. Olivines dominate at higher temperature. Beyond 1300 K dust grains significantly grow in size. The $\gamma_e$ no longer decreases but the large grain size restricts the capability of growing aggregates. Beyond 1400 K aggregation is no longer possible. Overall, under the conditions probed, the stability of dust pebbles would decrease towards the star. In view of a minimum aggregate size required to trigger drag instabilities it becomes increasingly harder to seed planetesimal formation closer to a star

Physical Conditoins in Orion's Veil II: A Multi-Component Study of the Line of Sight Toward the Trapezium

Orion's Veil is an absorbing screen that lies along the line of sight to the Orion H II region. It consists of two or more layers of gas that must lie within a few parsecs of the Trapezium cluster. Our previous work considered the Veil as a whole and found that the magnetic field dominates the energetics of the gas in at least one component. Here we use high-resolution STIS UV spectra that resolve the two velocity components in absorption and determine the conditions in each. We derive a volume hydrogen density, 21 cm spin temperature, turbulent velocity, and kinetic temperature, for each. We combine these estimates with magnetic field measurements to find that magnetic energy significantly dominates turbulent and thermal energies in one component, while the other component is close to equipartition between turbulent and magnetic energies. We observe molecular hydrogen absorption for highly excited v, J levels that are photoexcited by the stellar continuum, and detect blueshifted S III and P III. These ions must arise from ionized gas between the mostly neutral portions of the Veil and the Trapezium and shields the Veil from ionizing radiation. We find that this layer of ionized gas is also responsible for He I absorption in the Veil, which resolves a 40-year-old debate on the origin of He I absorption towards the Trapezium. Finally, we determine that the ionized and mostly atomic layers of the Veil will collide in less than 85,000 years.Comment: 43 pages, 15 figures, to be published in Ap

Dual‐Targeted Nanoreactors and Prodrugs: Hydrogen Peroxide Triggers Oxidative Damage and Prodrug Activation for Synergistic Elimination of Cancer Cells

Synergistic strategies by combining nanoreactors and prodrugs hold tremendous potential in anticancer treatment. However, precise death of target cancer cells remains a significant challenge due to the absence of an elaborate cancer targeting strategy. Here, a dual-targeting approach that combines the action of H2O2-producing folate receptor-targeted nanoreactors with a cyclooxygenase-2 (COX-2) targeted prodrug is reported. A folate-modified silica nanoreactor encapsulating glucose oxidase (GOX) is prepared to generate H2O2, which induces oxidative stress and allows the activation of the prodrug by targeted intracellular delivery. A novel prodrug bearing both COX-2 targeting Celecoxib and SN-38 anticancer agent with an H2O2-cleavable thioketal linker to activate the drug is presented. By dual-targeting, the generated H2O2 from GOX triggers the cleavage of a thioketal linker in the prodrug to produce the active form of the SN-38 anticancer drug in cancer cells inducing synergistic cell death. This dual-targeting strategy with a synergistic potency can aid in developing selective and effective anticancer therapeutics

Graphene Rings in Magnetic Fields: Aharonov-Bohm Effect and Valley Splitting

We study the conductance of mesoscopic graphene rings in the presence of a perpendicular magnetic field by means of numerical calculations based on a tight-binding model. First, we consider the magnetoconductance of such rings and observe the Aharonov-Bohm effect. We investigate different regimes of the magnetic flux up to the quantum Hall regime, where the Aharonov-Bohm oscillations are suppressed. Results for both clean (ballistic) and disordered (diffusive) rings are presented. Second, we study rings with smooth mass boundary that are weakly coupled to leads. We show that the valley degeneracy of the eigenstates in closed graphene rings can be lifted by a small magnetic flux, and that this lifting can be observed in the transport properties of the system.Comment: 12 pages, 9 figure

Semi-Hard Scattering Unraveled from Collective Dynamics by Two-Pion Azimuthal Correlations in 158 A GeV/c Pb + Au Collisions

Elliptic flow and two-particle azimuthal correlations of charged hadrons and high-$p_T$ pions ($p_T>$ 1 GeV/$c$) have been measured close to mid-rapidity in 158A GeV/$c$ Pb+Au collisions by the CERES experiment. Elliptic flow ($v_2$) rises linearly with $p_T$ to a value of about 10% at 2 GeV/$c$. Beyond $p_T\approx$ 1.5 GeV/$c$, the slope decreases considerably, possibly indicating a saturation of $v_2$ at high $p_T$. Two-pion azimuthal anisotropies for $p_T>$ 1.2 GeV/$c$ exceed the elliptic flow values by about 60% in mid-central collisions. These non-flow contributions are attributed to near-side and back-to-back jet-like correlations, the latter exhibiting centrality dependent broadening.Comment: Submitted to Phys. Rev. Letters, 4 pages, 5 figure