Quantitative characterization of non-classic polarization of cations on clay aggregate stability.

Soil particle interactions are strongly influenced by the concentration, valence and ion species and the pH of the bulk solution, which will also affect aggregate stability and particle transport. In this study, we investigated clay aggregate stability in the presence of different alkali ions (Li+, Na+, K+, and Cs+) at concentrations from10-5 to 10-1 mol L-1. Strong specific ion effects on clay aggregate stability were observed, and showed the order Cs+>K+>Na+>Li+. We found that it was not the effects of ion size, hydration, and dispersion forces in the cation-surface interactions but strong non-classic polarization of adsorbed cations that resulted in these specific effects. In this study, the non-classic dipole moments of each cation species resulting from the non-classic polarization were estimated. By comparing non-classic dipole moments with classic values, the observed dipole moments of adsorbed cations were up to 104 times larger than the classic values for the same cation. The observed non-classic dipole moments sharply increased with decreasing electrolyte concentration. We conclude that strong non-classic polarization could significantly suppress the thickness of the diffuse layer, thereby weakening the electric field near the clay surface and resulting in improved clay aggregate stability. Even though we only demonstrated specific ion effects on aggregate stability with several alkali ions, our results indicate that these effects could be universally important in soil aggregate stability

Relationship between aggregates breaking strength and particle surface potential in Li⁺ system

<p>Relationship between aggregates breaking strength and particle surface potential in Li⁺ system</p

Relationship between aggregates breaking strength and particle surface potential in Li⁺ system

<p>Relationship between aggregates breaking strength and particle surface potential in Li⁺ system</p

Relationship between aggregates breaking strength and electrolyte concentrations (A, B and C represent released small particles of <i>d</i><10, 5 and 2 μm, respectively).

<p>Relationship between aggregates breaking strength and electrolyte concentrations (A, B and C represent released small particles of <i>d</i><10, 5 and 2 μm, respectively).</p

The β value of different system under different electrolyte concentration (mol L^-1).

<p>The β value of different system under different electrolyte concentration (mol L^-1).</p

The difference of aggregates breaking strength between each two system as a function of electrolyte concentrations and surface potential.

<p>The difference of aggregates breaking strength between each two system as a function of electrolyte concentrations and surface potential.</p

Distribution of the electric field strength from clay particle surface.

<p>Distribution of the electric field strength from clay particle surface.</p