Surfactant-aided exfoliation of molydenum disulphide for ultrafast pulse generation through edge-state saturable absorption

We use liquid phase exfoliation to produce dispersions of molybdenum disulphide (MoS2) nanoflakes in aqueous surfactant solutions. The chemical structures of the bile salt surfactants play a crucial role in the exfoliation and stabilization of MoS2. The resultant MoS2 dispersions are heavily enriched in single and few (<6) layer flakes with large edge to surface area ratio. We use the dispersions to fabricate free-standing polymer composite wide-band saturable absorbers to develop mode-locked and Q- switched fibre lasers, tunable from 1535-1565 and 1030-1070 nm, respectively. We attribute this sub-bandgap optical absorption and its nonlinear saturation behaviour to edge-mediated states introduced within the material band-gap of the exfoliated MoS2 nanoflakes.Comment: 6 pages, 5 figure

SeaWiFS technical report series. Volume 10: Modeling of the SeaWiFS solar and lunar observations

Post-launch stability monitoring of the Sea-viewing Wide Field-of-view Sensor (SeaWifs) will include periodic sweeps of both an onboard solar diffuser plate and the moon. The diffuser views will provide short-term checks and the lunar views will monitor long-term trends in the instrument's radiometric stability. Models of the expected sensor response to these observations were created on the SeaWiFS computer at the National Aeronautics and Space Administration's (NASA) Goddard Space Flight Center (GSFC) using the Interactive Data Language (IDL) utility with a graphical user interface (GUI). The solar model uses the area of intersecting circles to simulate the ramping of sensor response while viewing the diffuser. This model is compared with preflight laboratory scans of the solar diffuser. The lunar model reads a high-resolution lunar image as input. The observations of the moon are simulated with a bright target recovery algorithm that includes ramping and ringing functions. Tests using the lunar model indicate that the integrated radiance of the entire lunar surface provides a more stable quantity than the mean of radiances from centralized pixels. The lunar model is compared to ground-based scans by the SeaWiFS instrument of a full moon in December 1992. Quality assurance and trend analyses routines for calibration and for telemetry data are also discussed

Major Depressive Disorder Among Older African Americans, Caribbean Blacks, And Non‐Hispanic Whites: Secondary Analysis Of The National Survey Of American Life

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/98298/1/da22041.pd

A Spitzer IRAC Census of the Asymptotic Giant Branch Populations in Local Group Dwarfs. II. IC 1613

We present Spitzer Space Telescope IRAC photometry of the Local Group dwarf irregular galaxy IC 1613. We compare our 3.6, 4.5, 5.8, and 8.0 micron photometry with broadband optical photometry and find that the optical data do not detect 43% and misidentify an additional 11% of the total AGB population, likely because of extinction caused by circumstellar material. Further, we find that a narrowband optical carbon star study of IC 1613 detects 50% of the total AGB population and only considers 18% of this population in calculating the carbon to M-type AGB ratio. We derive an integrated mass-loss rate from the AGB stars of 0.2-1.0 x 10^(-3) solar masses per year and find that the distribution of bolometric luminosities and mass-loss rates are consistent with those for other nearby metal-poor galaxies. Both the optical completeness fractions and mass-loss rates in IC 1613 are very similar to those in the Local Group dwarf irregular, WLM, which is expected given their similar characteristics and evolutionary histories.Comment: Accepted by ApJ, 26 pages, 10 figures, version with high-resolution figures available at: http://webusers.astro.umn.edu/~djackson

The economic implications of HLA matching in cadaveric renal transplantation.

Abstract Background: The potential economic effects of the allocation of cadaveric kidneys on the basis of tissue-matching criteria are controversial. We analyzed the economic costs associated with the transplantation of cadaveric kidneys with various numbers of HLA mismatches and examined the potential economic benefits of a local, as compared with a national, system designed to minimize HLA mismatches between donor and recipient in first cadaveric renal transplantations. Methods: All data were supplied by the U.S. Renal Data System. Data on all payments made by Medicare from 1991 through 1997 for the care of recipients of a first cadaveric renal transplant were analyzed according to the number of HLA-A, B, and DR mismatches between donor and recipient and the duration of cold ischemia before transplantation. Results: Average Medicare payments for renal-transplant recipients in the three years after transplantation increased from $60,436 per patient for fully HLA-matched kidneys (those with no HLA-A, B, or DR mismatches) to$80,807 for kidneys with six HLA mismatches between donor and recipient, a difference of 34 percent (P\u3c0.001). By three years after transplantation, the average Medicare payments were $64,119 for transplantations of kidneys with less than 12 hours of cold-ischemia time and$74,997 for those with more than 36 hours (P\u3c0.001). In simulations, the assignment of cadaveric kidneys to recipients by a method that minimized HLA mismatching within a local geographic area (i.e., within one of the approximately 50 organ-procurement organizations, which cover widely varying geographic areas) produced the largest cost savings ($4,290 per patient over a period of three years) and the largest improvements in the graft-survival rate (2.3 percent) when the potential costs of longer cold-ischemia time were considered. Conclusions: Transplantation of better-matched cadaveric kidneys could have substantial economic advantages. In our simulations, HLA-based allocation of kidneys at the local level produced the largest estimated cost savings, when the duration of cold ischemia was taken into account. No additional savings were estimated to result from a national allocation program, because the additional costs of longer cold-ischemia time were greater than the advantages of optimizing HLA matching

Formation and Fate of Carboxylic Acids in the Lignin-First Biorefining of Lignocellulose via H-Transfer Catalyzed by Raney Ni

This work was conducted with the financial support provided by the ERC Consolidator Grant LIGNINFIRST (Project Number: 725762). The authors are thankful to Brazilian Synchrotron Light Laboratory (LNLS) for measurements in the DXAS beamline (Project Number: 20160732). R.R. and M.K. are grateful to Dr. Fabian Meemken (ETH Zürich) for granting us the access to the ATR-IR facilities.Peer reviewedPostprin

Spitzer IRAC Observations of Star Formation in N159 in the LMC

We present observations of the giant HII region complex N159 in the LMC using IRAC on the {\it Spitzer Space Telescope}. One of the two objects previously identified as protostars in N159 has an SED consistent with classification as a Class I young stellar object (YSO) and the other is probably a Class I YSO as well, making these two stars the youngest stars known outside the Milky Way. We identify two other sources that may also be Class I YSOs. One component, N159AN, is completely hidden at optical wavelengths, but is very prominent in the infrared. The integrated luminosity of the entire complex is L $\approx 9\times10^6$L$_{\odot}$, consistent with the observed radio emission assuming a normal Galactic initial mass function (IMF). There is no evidence for a red supergiant population indicative of an older burst of star formation. The N159 complex is 50 pc in diameter, larger in physical size than typical HII regions in the Milky Way with comparable luminosity. We argue that all of the individual components are related in their star formation history. The morphology of the region is consistent with a wind blown bubble $\approx 1-2Myr-old that has initiated star formation now taking place at the rim. Other than its large physical size, star formation in N159 appears to be indistinguishable from star formation in the Milky Way.Comment: 14 figure

Gigahertz measurement-device-independent quantum key distribution using directly modulated lasers

Measurement-device-independent quantum key distribution (MDI-QKD) is a technique for quantum-secured communication that eliminates all detector side-channels, although is currently limited by implementation complexity and low secure key rates. Here, we introduce a simple and compact MDI-QKD system design at gigahertz clock rates with enhanced resilience to laser fluctuations—thus enabling free-running semiconductor laser sources to be employed without spectral or phase feedback. This is achieved using direct laser modulation, carefully exploiting gain-switching and injection-locking laser dynamics to encode phase-modulated time-bin bits. Our design enables secure key rates that improve upon the state of the art by an order of magnitude, up to 8 bps at 54 dB channel loss and 2 kbps in the finite-size regime for 30 dB channel loss. This greatly simplified MDI-QKD system design and proof-of-principle demonstration shows that MDI-QKD is a practical, high-performance solution for future quantum communication networks