Local methylthiolate adsorption geometry on Au(111) from photoemission core-level shifts

The local adsorption structure of methylthiolate in the ordered Au(111)-(√3×√3)R30° phase has been investigated using core-level-shift measurements of the surface and bulk components of the Au 4f7/2 photoelectron binding energy. The amplitude ratio of the core-level-shift components associated with surface Au atoms that are, and are not, bonded to the thiolate is found to be compatible only with the previously proposed Au-adatom-monothiolate moiety in which the thiolate is bonded atop Au adatoms in hollow sites, and not on an unreconstructed surface, or in Au-adatom-dithiolate species

The Keck Aperture Masking Experiment: spectro-interferometry of 3 Mira Variables from 1.1 to 3.8 microns

We present results from a spectro-interferometric study of the Miras o Cet, R Leo and W Hya obtained with the Keck Aperture Masking Experiment from 1998 Sep to 2002 Jul. The spectrally dispersed visibility data permit fitting with circularly symmetric brightness profiles such as a simple uniform disk. The stellar angular diameter obtained over up to ~ 450 spectral channels spaning the region 1.1-3.8 microns is presented. Use of a simple uniform disk brightness model facilitates comparison between epochs and with existing data and theoretical models. Strong size variations with wavelength were recorded for all stars, probing zones of H2O, CO, OH, and dust formation. Comparison with contemporaneous spectra extracted from our data show a strong anti-correlation between the observed angular diameter and flux. These variations consolidate the notion of a complex stellar atmosphere consisting of molecular shells with time-dependent densities and temperatures. Our findings are compared with existing data and pulsation models. The models were found to reproduce the functional form of the wavelength vs. angular diameter curve well, although some departures are noted in the 2.8-3.5 micron range.Comment: 10 pages, 10 figures Accepted to Ap

Toward a unified theory of sparse dimensionality reduction in Euclidean space

Let $\Phi\in\mathbb{R}^{m\times n}$ be a sparse Johnson-Lindenstrauss transform [KN14] with $s$ non-zeroes per column. For a subset $T$ of the unit sphere, $\varepsilon\in(0,1/2)$ given, we study settings for $m,s$ required to ensure $$\mathop{\mathbb{E}}_\Phi \sup_{x\in T} \left|\|\Phi x\|_2^2 - 1 \right| < \varepsilon ,$$ i.e. so that $\Phi$ preserves the norm of every $x\in T$ simultaneously and multiplicatively up to $1+\varepsilon$. We introduce a new complexity parameter, which depends on the geometry of $T$, and show that it suffices to choose $s$ and $m$ such that this parameter is small. Our result is a sparse analog of Gordon's theorem, which was concerned with a dense $\Phi$ having i.i.d. Gaussian entries. We qualitatively unify several results related to the Johnson-Lindenstrauss lemma, subspace embeddings, and Fourier-based restricted isometries. Our work also implies new results in using the sparse Johnson-Lindenstrauss transform in numerical linear algebra, classical and model-based compressed sensing, manifold learning, and constrained least squares problems such as the Lasso

Spin resonance in the superconducting state of Li1−x_{1-x}Fex_{x}ODFe1−y_{1-y}Se observed by neutron spectroscopy

We have performed inelastic neutron scattering measurements on a powder sample of the superconductor lithium iron selenide hydroxide Li$_{1-x}$Fe$_{x}$ODFe$_{1-y}$Se ($x \simeq 0.16, y \simeq 0.02$, $T_{\rm c} = 41$\,K). The spectrum shows an enhanced intensity below $T_{\rm c}$ over an energy range $0.64\times2\Delta < E < 2\Delta$, where $\Delta$ is the superconducting gap, with maxima at the wave vectors $Q_1 \simeq 1.46$\,\AA$^{-1}$ and $Q_2 \simeq 1.97$\,\AA$^{-1}$. The behavior of this feature is consistent with the spin resonance mode found in other unconventional superconductors, and strongly resembles the spin resonance observed in the spectrum of the molecular-intercalated iron selenide, Li$_{0.6}$(ND$_{2}$)$_{0.2}$(ND$_{3}$)$_{0.8}$Fe$_{2}$Se$_{2}$. The signal can be described with a characteristic two-dimensional wave vector $(\pi, 0.67\pi)$ in the Brillouin zone of the iron square lattice, consistent with the nesting vector between electron Fermi sheets

Ampa Receptor Subunit Expression in the Endoplasmic Reticulum in Frontal Cortex of Elderly Patients with Schizophrenia

Several lines of evidence indicate altered trafficking of α-amino-3-hydroxyl-5-methyl-4-isoxazole-propionate (AMPA) receptors in schizophrenia. Previous reports have shown potential changes in the trafficking of AMPA receptors based on subunit expression of endosomes, subcellular organelles located near post-synaptic sites. We hypothesized that alterations in AMPA receptor trafficking through the endoplasmic reticulum (ER) may also be altered in schizophrenia. Accordingly, we developed a technique to isolate and measure content of the ER from postmortem brain tissue. We used Western blot and electron microscopy to show that we isolated an ER enriched fraction. We found no changes in the expression of the AMPA receptor subunits, GluR1–4, in the ER from the dorsolateral prefrontal cortex in schizophrenia. These data suggest that AMPA receptor trafficking through the ER is largely intact in schizophrenia

Using schema transformation pathways for data lineage tracing

With the increasing amount and diversity of information available on the Internet, there has been a huge growth in information systems that need to integrate data from distributed, heterogeneous data sources. Tracing the lineage of the integrated data is one of the problems being addressed in data warehousing research. This paper presents a data lineage tracing approach based on schema transformation pathways. Our approach is not limited to one specific data model or query language, and would be useful in any data transformation/integration framework based on sequences of primitive schema transformations

Identifying the Azobenzene/Aniline reaction intermediate on TiO2-(110) : a DFT Study

Density functional theory (DFT) calculations, both with and without dispersion corrections, have been performed to investigate the nature of the common surface reaction intermediate that has been shown to exist on TiO2(110) as a result of exposure to either azobenzene (C6H5N═NC6H5) or aniline (C6H5NH2). Our results confirm the results of a previous DFT study that dissociation of azobenzene into two adsorbed phenyl imide (C6H5N) fragments, as was originally proposed, is not energetically favorable. We also find that deprotonation of aniline to produce this surface species is even more strongly energetically disfavored. A range of alternative surface species has been considered, and while dissociation of azobenzene to form surface C6H4NH species is energetically favored, the same surface species cannot form from adsorbed aniline. On the contrary, adsorbed aniline is much the most stable surface species. Comparisons with experimental determinations of the local adsorption site, the Ti–N bond length, the molecular orientation, and the associated C 1s and N 1s photoelectron core level shifts are all consistent with the DFT results for adsorbed aniline and are inconsistent with other adsorbed species considered. Possible mechanisms for the hydrogenation of azobenzene required to produce this surface species are discussed

Optimal Principal Component Analysis in Distributed and Streaming Models

We study the Principal Component Analysis (PCA) problem in the distributed and streaming models of computation. Given a matrix $A \in R^{m \times n},$ a rank parameter $k < rank(A)$, and an accuracy parameter $0 < \epsilon < 1$, we want to output an $m \times k$ orthonormal matrix $U$ for which $$|| A - U U^T A ||_F^2 \le \left(1 + \epsilon \right) \cdot || A - A_k||_F^2,$$ where $A_k \in R^{m \times n}$ is the best rank-$k$ approximation to $A$. This paper provides improved algorithms for distributed PCA and streaming PCA.Comment: STOC2016 full versio

Expression of prodynorphin-derived peptides and mRNA in guinea-pig cortex

The distributions and extent of processing of four prodynorphin-derived peptides (dynorphin A (1-17), dynorphin A (1-8), dynorphin B, and [alpha]-neoendorphin) were determined in ten regions of the cortex as well as in the striatum of the guinea-pig. There were significant differences between concentrations of these peptides in most cortical regions, with [alpha]-neoendorphin being several times more abundant than the other peptides, and dynorphin A (1-17) being present in the least amount. There were significant between-region differences in concentration for each peptide, although most regions had concentrations similar to those seen in the striatum. Concentrations of each peptide tended to be higher in piriform, entorhinal, motor, and auditory cortex than in other cortical regions. The extent of processing of prodynorphin varied across cortical regions as well, primarily due to the extent of processing to [alpha]-neoendorphin. Prodynorphin mRNA levels were not significantly different between cortical regions or from the amount observed in the striatum. Although specific regional variation exists, it appears that in general prodynorphin is expressed and processed in a similar manner in the cortex as in the striatum.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/30648/1/0000290.pd

The non-uniform, dynamic atmosphere of Betelgeuse observed at mid-infrared wavelengths

We present an interferometric study of the continuum surface of the red supergiant star Betelgeuse at 11.15 microns wavelength, using data obtained with the Berkeley Infrared Spatial Interferometer each year between 2006 and 2010. These data allow an investigation of an optically thick layer within 1.4 stellar radii of the photosphere. The layer has an optical depth of ~1 at 11.15 microns, and varies in temperature between 1900 K and 2800 K and in outer radius between 1.16 and 1.36 stellar radii. Electron-hydrogen atom collisions contribute significantly to the opacity of the layer. The layer has a non-uniform intensity distribution that changes between observing epochs. These results indicate that large-scale surface convective activity strongly influences the dynamics of the inner atmosphere of Betelgeuse, and mass-loss processes.Comment: 13 pages, 5 figures, in press (ApJ