42 research outputs found
Heavy quark potential and the phase transitions in the continuum theory at finite temperature
Heavy quark potential in the continuum theory at finite temperature is
calculated in different phases by using the Polyakov loop as the order
parameter. We find the linearly rising potential in the confinement phase, the
Debye screened potential in the deconfinement phase and the perturbative
dependence at very high temperatures. Within the approximation used in
this paper we report an evidence of the first order phase transition
accompanied by the symmetry restoration at very high temperatures in
the static three dimensional theory.Comment: 10 pages, RevTeX, 2 PostScript figures appende
Multifaceted behavior of a doubly reduced arylborane in B–H-bond activation and hydroboration catalysis
Alkali-metal salts of 9,10-dimethyl-9,10-dihydro-9,10-diboraanthrancene (M2[DBA-Me2]; M+ = Li+, Na+, K+) activate the H–B bond of pinacolborane (HBpin) in THF already at room temperature. For M+ = Na+, K+, the addition products M2[4] are formed, which contain one new H–B and one new B–Bpin bond; for M+ = Li+, the H– ion is instantaneously transferred from the DBA-Me2 unit to another equivalent of HBpin to afford Li[5]. Although Li[5] might commonly be considered a [Bpin]– adduct of neutral DBA-Me2, it donates a [Bpin]+ cation to Li[SiPh3], generating the silyl borane Ph3Si–Bpin; Li2[DBA-Me2] with an aromatic central B2C4 ring acts as the leaving group. Furthermore, Li2[DBA-Me2] catalyzes the hydroboration of various unsaturated substrates with HBpin in THF. Quantum-chemical calculations complemented by in situ NMR spectroscopy revealed two different mechanistic scenarios that are governed by the steric demand of the substrate used: In the case of the bulky Ph(H)C=NtBu, the reaction requires elevated temperatures of 100 °C, starts with H–Bpin activation which subsequently generates Li[BH4], so that the mechanism eventually turns into “hidden borohydride catalysis”. Ph(H)C=NPh, Ph2C=O, Ph2C=CH2, and iPrN=C=NiPr undergo hydroboration already at room temperature. Here, the active hydroboration catalyst is the [4+2] cycloadduct between the respective substrate and Li2[DBA-Me2]: In the key step, attack of HBpin on the bridging unit opens the bicyclo[2.2.2]octadiene scaffold and gives the activated HBpin adduct of the Lewis-basic moiety that was previously coordinated to the DBA-B atom
Financial Systems and Industrial Policy in Germany and Great Britain: The Limits of Convergence
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Research and Design of a Routing Protocol in Large-Scale Wireless Sensor Networks
无线传感器网络,作为全球未来十大技术之一,集成了传感器技术、嵌入式计算技术、分布式信息处理和自组织网技术,可实时感知、采集、处理、传输网络分布区域内的各种信息数据,在军事国防、生物医疗、环境监测、抢险救灾、防恐反恐、危险区域远程控制等领域具有十分广阔的应用前景。 本文研究分析了无线传感器网络的已有路由协议,并针对大规模的无线传感器网络设计了一种树状路由协议,它根据节点地址信息来形成路由,从而简化了复杂繁冗的路由表查找和维护,节省了不必要的开销,提高了路由效率,实现了快速有效的数据传输。 为支持此路由协议本文提出了一种自适应动态地址分配算——ADAR(AdaptiveDynamicAddre...As one of the ten high technologies in the future, wireless sensor network, which is the integration of micro-sensors, embedded computing, modern network and Ad Hoc technologies, can apperceive, collect, process and transmit various information data within the region. It can be used in military defense, biomedical, environmental monitoring, disaster relief, counter-terrorism, remote control of haz...学位:工学硕士院系专业:信息科学与技术学院通信工程系_通信与信息系统学号:2332007115216
Ueber Freiheit, Gleichheit und Bruederlichkeit: Kritik des Wohlfahrtsstaates, Theorie der Sozialordnung und Utopie der sozialen Marktwirtschaft
SIGLEAvailable from Bibliothek des Instituts fuer Weltwirtschaft, ZBW, Duesternbrook Weg 120, D-24105 Kiel A 159837 / FIZ - Fachinformationszzentrum Karlsruhe / TIB - Technische InformationsbibliothekDEGerman
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Available from Bibliothek des Instituts fuer Weltwirtschaft, ZBW, Duesternbrook Weg 120, D-24105 Kiel A 169438 / FIZ - Fachinformationszzentrum Karlsruhe / TIB - Technische InformationsbibliothekSIGLEDEGerman