Phonons in potassium doped graphene: the effects of electron-phonon interactions, dimensionality and ad-atom ordering

Graphene phonons are measured as a function of electron doping via the addition of potassium adatoms. In the low doping regime, the in-plane carbon G-peak hardens and narrows with increasing doping, analogous to the trend seen in graphene doped via the field-effect. At high dopings, beyond those accessible by the field-effect, the G-peak strongly softens and broadens. This is interpreted as a dynamic, non-adiabatic renormalization of the phonon self-energy. At dopings between the light and heavily doped regimes, we find a robust inhomogeneous phase where the potassium coverage is segregated into regions of high and low density. The phonon energies, linewidths and tunability are remarkably similar for 1-4 layer graphene, but significantly different to doped bulk graphite.Comment: Accepted in Phys. Rev. B as a Rapid Communication. 5 pages, 3 figures, revised text with additional dat

The dust trail complex of comet 79P/du Toit-Hartley and meteor outbursts at Mars

The original publication is available in Astronomy & Astrophysics at www.aanda.org.International audienceAims. Meteoroid trails ejected during past perihelion passages of the Mars-orbit-intersecting comet 79P/du Toit-Hartley have the potential of generating meteor outbursts in the Martian atmosphere. Depending on timing and intensity, the effects of these outbursts may be detectable by instrumentation operating in the vicinity of Mars. We aim to generate predictions for meteor activity in the martian atmosphere related to that comet; to search for evidence, in planetary mission data, that such activity took place; and to make predictions for potentially detectable future activity. Methods. We have modelled the stream by integrating numerically the states of particle ensembles, each ensemble representing a trail of meteoroids ejected from the comet during 39 perihelion passages from 1803, and propagated them forward in time, concentrating on those particles that physically approach Mars in the recent past and near future. Results. We find several instances where meteor outbursts of low to moderate intensity may have taken place at Mars since 1997. A search through Mars Global Surveyor (MGS) radio science data during two periods in 2003 and 2005 when data coverage was available showed that a plasma layer did indeed form in the martian ionosphere for a period of a few hours in April 2003 as a direct consequence of the predicted outburst. The apparent failure to identify such an event in 2005 could be due to those meteoroids ablating lower in the atmosphere or that the cometary dust follows a different particle size distribution than what was assumed. Our study highlights the need for further theoretical modelling of the response of the martian ionosphere to a time-variable meteoroid flux, observations of the comet itself and, most importantly, regular monitoring of the martian ionosphere during future outbursts predicted by our model

Metabolic, Ventilatory, and Hygric Physiology of the Gracile Mouse Opossum (Gracilinanus agilis)

We present the first complete study of basic laboratory‐measured physiological variables (metabolism, thermoregulation, evaporative water loss, and ventilation) for a South American marsupial, the gracile mouse opossum (Gracilinanus agilis). Body temperature (Tb) was thermolabile below thermoneutrality (Tb = 33.5°C), but a substantial gradient between Tb and ambient temperature (Ta) was sustained even at Ta = 12°C (Tb = 30.6°C). Basal metabolic rate of 1.00 mL O2 g−1 h−1 at Ta = 30°C conformed to the general allometric relationship for marsupials, as did wet thermal conductance (5.7 mL O2 g−1 h−1 °C−1). Respiratory rate, tidal volume, and minute volume at thermoneutrality matched metabolic demand such that O2 extraction was 12.4%, and ventilation increased in proportion to metabolic rate at low Ta. Ventilatory accommodation of increased metabolic rate at low Ta was by an increase in respiratory rate rather than by tidal volume or O2 extraction. Evaporative water loss at the lower limit of thermoneutrality conformed to that of other marsupials. Relative water economy was negative at thermoneutrality but positive below Ta = 12°C. Interestingly, the Neotropical gracile mouse opossums have a more positive water economy at low Ta than an Australian arid‐zone marsupial, perhaps reflecting seasonal variation in water availability for the mouse opossum. Torpor occurred at low Ta, with spontaneous arousal when Tb > 20°C. Torpor resulted in absolute energy and water savings but lower relative water economy. We found no evidence that gracile mouse opossums differ physiologically from other marsupials, despite their Neotropical distribution, sympatry with placental mammals, and long period of separation from Australian marsupials

Review of robust measurement of phosphorus in river water: sampling, storage, fractionation and sensitivity

International audienceThis paper reviews current knowledge on sampling, storage and analysis of phosphorus (P) in river waters. Potential sensitivity of rivers with different physical, chemical and biological characteristics (trophic status, turbidity, flow regime, matrix chemistry) is examined in terms of errors associated with sampling, sample preparation, storage, contamination, interference and analytical errors. Key issues identified include: The need to tailor analytical reagents and concentrations to take into account the characteristics of the sample matrix. The effects of matrix interference on the colorimetric analysis. The influence of variable rates of phospho-molybdenum blue colour formation. The differing responses of river waters to physical and chemical conditions of storage. The higher sensitivities of samples with low P concentrations to storage and analytical errors. Given high variability of river water characteristics in space and time, no single standardised methodology for sampling, storage and analysis of P in rivers can be offered. ?Good Practice' guidelines are suggested, which recommend that protocols for sampling, storage and analysis of river water for P is based on thorough site-specific method testing and assessment of P stability on storage. For wider sampling programmes at the regional/national scale where intensive site-specific method and stability testing are not feasible, ?Precautionary Practice' guidelines are suggested. The study highlights key areas requiring further investigation for improving methodological rigour. Keywords: phosphorus, orthophosphate, soluble reactive, particulate, colorimetry, stability, sensitivity, analytical error, storage, sampling, filtration, preservative, fractionation, digestio

Residual stress of as-deposited and rolled Wire + Arc Additive Manufacturing Ti–6Al–4V components

Wire + arc additive manufacturing components contain significant residual stresses, which manifest in distortion. High-pressure rolling was applied to each layer of a linear Ti–6Al–4V wire + arc additive manufacturing component in between deposition passes. In rolled specimens, out-of-plane distortion was more than halved; a change in the deposits' geometry due to plastic deformation was observed and process repeatability was increased. The Contour method of residual stresses measurements showed that although the specimens still exhibited tensile stresses (up to 500 MPa), their magnitude was reduced by 60%, particularly at the interface between deposit and substrate. The results were validated with neutron diffraction measurements, which were in good agreement away from the baseplate

2D mapping of plane stress crack-tip fields following an overload

The evolution of crack-tip strain fields in a thin (plane stress) compact tension sample following an overload (OL) event has been studied using two different experimental techniques. Surface behaviour has been characterised by Digital Image Correlation (DIC), while the bulk behaviour has been characterised by means of synchrotron X-ray diffraction (XRD). The combination of both surface and bulk information allowed us to visualise the through-thickness evolution of the strain fields before the OL event, during the overload event, just after OL and at various stages after it. Unlike previous work, complete 2D maps of strains around the crack-tip were acquired at 60m spatial resolution by XRD. The DIC shows less crack opening after overload and the XRD a lower crack-tip peak stress after OL until the crack has grown past the compressive crack-tip residual stress introduced by the overload after which the behaviour returned to that for the baseline fatigue response. While the peak crack-tip stress is supressed by the compressive residual stress, the crack-tip stress field changes over each cycle are nevertheless the same for all Kmax cycles except at OL

Modularised process-based modelling of phosphorus loss at farm and catchment scale

In recent years, a co-ordinated programme of data collection has resulted in the collation of sub-hourly time-series of hydrological, sediment and phosphorus loss data, together with soil analysis, cropping and management information for two small (< 200 ha) headwater agricultural catchments in the UK Midlands (Rosemaund, Herefordshire and Cliftonthorpe, Leicestershire). These data sets have allowed the dynamics of phosphorus loss to be characterised and the importance of both storm runoff and drainflow to be identified, together with incidental losses following manure and fertiliser additions in contributing to total annual loss. A modularised process-based model has been developed to represent current understanding of the dynamics of phosphorus loss. Modules describing runoff and sediment generation and associated phosphorus adsorption/desorption dynamics are described and tested. In the model, the effect of a growing crop on sediment detachment processes is represented and the stability of topsoil is considered so that, overall, the model is responsive to farm management factors. Importantly, using data sets available from national-scale survey programmes to estimate model parameters, a transferable approach is presented, requiring only sub-hourly rainfall data and field-specific landcover information for application of the model to new sites. Results from application of the model to the hydrological year 1998–99 are presented. Assessment of performance, which suggests that the timing of simulated responses is acceptable, has focused attention on quantifying landscape and in-stream retention and remobilisation processes.</b></p> <p style='line-height: 20px;'><b>Keywords: </b>phosphorus, erosion, process-based modelling, agricultur