4,672 research outputs found
Optical absorption in small BN and C nanotubes
We present a theoretical study of the optical absorption spectrum of small
boron-nitride and carbon nanotubes using time-dependent density-functional
theory and the random phase approximation. Both for C and BN tubes, the
absorption of light polarized perpendicular to the tube-axis is strongly
suppressed due to local field effects. Since BN-tubes are wide band-gap
insulators, they only absorb in the ultra-violet energy regime, independently
of chirality and diameter. In comparison with the spectra of the single C and
BN-sheets, the tubes display additional fine-structure which stems from the
(quasi-) one-dimensionality of the tubes and sensitively depends on the
chirality and tube diameter. This fine structure can provide additional
information for the assignment of tube indices in high resolution optical
absorption spectroscopy.Comment: 5 pages, 3 figure
Purpose and Effect in Sherman Act Conspiracies
The Gypsum decision supplies the proper occasion for a renewed effort to sort out and line up the Court\u27s pronouncements since Trans-Missouri concerning the respective functions in cases arising under section 1 of proof of anticompetitive purpose and effect. Once this is done, a reasonably coherent body of doctrine emerges and the unresolved issues come more clearly into focus. The first two sections of this article deal with purpose and effect as determinants, respectively, of restraint of trade and of contract, combination . . . and conspiracy. The third section takes up the problems that arise when the doctrine that bad purpose need not be shown in section 1 cases—a doctrine developed primarily in suits in equity—is applied to criminal cases and civil actions for treble damages
Treatment of a wastewater from furfural production in anaerobic filters at mesophilic temperatures
Inter- and intra-layer excitons in MoS/WS and MoSe/WSe heterobilayers
Accurately described excitonic properties of transition metal dichalcogenide
heterobilayers (HBLs) are crucial to comprehend the optical response and the
charge carrier dynamics of them. Excitons in multilayer systems posses inter or
intralayer character whose spectral positions depend on their binding energy
and the band alignment of the constituent single-layers. In this study, we
report the electronic structure and the absorption spectra of MoS/WS
and MoSe/WSe HBLs from first-principles calculations. We explore the
spectral positions, binding energies and the origins of inter and intralayer
excitons and compare our results with experimental observations. The absorption
spectra of the systems are obtained by solving the Bethe-Salpeter equation on
top of a GW calculation which corrects the independent particle
eigenvalues obtained from density functional theory calculations. Our
calculations reveal that the lowest energy exciton in both HBLs possesses
interlayer character which is decisive regarding their possible device
applications. Due to the spatially separated nature of the charge carriers, the
binding energy of inter-layer excitons might be expected to be considerably
smaller than that of intra-layer ones. However, according to our calculations
the binding energy of lowest energy interlayer excitons is only 20\%
lower due to the weaker screening of the Coulomb interaction between layers of
the HBLs. Therefore, it can be deduced that the spectral positions of the
interlayer excitons with respect to intralayer ones are mostly determined by
the band offset of the constituent single-layers. By comparing oscillator
strengths and thermal occupation factors, we show that in luminescence at low
temperature, the interlayer exciton peak becomes dominant, while in absorption
it is almost invisible.Comment: 17 pages, 4 figure
Intra- and inter-examiner Reliability of Direct Facial Soft Tissue Measurements Using Digital Calipers
Background: The objective of this study is to determine if facial soft tissue measurements using digital calipers can be reliably taken by the same examiner and by a large group of examiners. Materials and Methods: Ten examiners performed a set of 18 in-clinic measurements on 10 female and 10 male dental students using a digital caliper twice over a 3-week period. The intra-class correlation coefficient and the Shrout-Fleiss method were used for the statistical analysis. Results: Anthropometric intra-examiner reliability was high for all measurements (none fell below R = 0.934). However, inter-examiner reliability exhibited a wide range of values, some reliable (nasal width at widest nostrils [R = 0.922] and subnasale to upper lip [R = 0.926]), and others unreliable [base of nose (R = 0.590), mouth height (R = 0.585), and soft tissue B point to gnathion (R = 0.623)]. Conclusions: Soft tissue measurements of clearly identifiable points measured by the same examiner produced highly consistent, accurate and reliable measurements. Soft tissue points with poor definition resulted in average-to-poor reliabilities measurements
Spatially Resolved Raman Spectroscopy of Single- and Few-Layer Graphene
We present Raman spectroscopy measurements on single- and few-layer graphene
flakes. Using a scanning confocal approach we collect spectral data with
spatial resolution, which allows us to directly compare Raman images with
scanning force micrographs. Single-layer graphene can be distinguished from
double- and few-layer by the width of the D' line: the single peak for
single-layer graphene splits into different peaks for the double-layer. These
findings are explained using the double-resonant Raman model based on ab-initio
calculations of the electronic structure and of the phonon dispersion. We
investigate the D line intensity and find no defects within the flake. A finite
D line response originating from the edges can be attributed either to defects
or to the breakdown of translational symmetry
Raman imaging of doping domains in graphene on SiO2
We present spatially resolved Raman images of the G and 2D lines of
single-layer graphene flakes. The spatial fluctuations of G and 2D lines are
correlated and are thus shown to be affiliated with local doping domains. We
investigate the position of the 2D line -- the most significant Raman peak to
identify single-layer graphene -- as a function of charging up to |n|~4 10^12
cm^-2. Contrary to the G line which exhibits a strong and symmetric stiffening
with respect to electron and hole-doping, the 2D line shows a weak and slightly
asymmetric stiffening for low doping. Additionally, the line width of the 2D
line is, in contrast to the G line, doping-independent making this quantity a
reliable measure for identifying single-layer graphene
Maritime Strategy and Naval Innovation (Continuation)
NPS NRP Executive SummaryMaritime Strategy and Naval Innovation (Continuation)N3/N5 - Information, Plans & StrategyThis research is supported by funding from the Naval Postgraduate School, Naval Research Program (PE 0605853N/2098). https://nps.edu/nrpChief of Naval Operations (CNO)Approved for public release. Distribution is unlimited.
Maritime Strategy and Naval Innovation (Continuation)
NPS NRP Project PosterMaritime Strategy and Naval Innovation (Continuation)N3/N5 - Information, Plans & StrategyThis research is supported by funding from the Naval Postgraduate School, Naval Research Program (PE 0605853N/2098). https://nps.edu/nrpChief of Naval Operations (CNO)Approved for public release. Distribution is unlimited.
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