Identification of nonlinear kinematic hardening parameters for sheet metal from biaxial loading tests

In this work an anisotropic material model at finite strains with nonlinear mixed (isotropic and kinematic) hardening is used for the identification of the hardening parameters of sheet steel. The algorithmic system is thereby reduced to a single equation return mapping. For the identification, a cruciform specimen is loaded biaxially in an alternating shear test to provoke the kinematic hardening behavior and prevent the sheet from buckling. The material parameters are found through an optimization strategy by comparing the deformation field from the experiment to that from a finite element (FE) simulation. The resulting cost function is minimized by means of a gradient-based method

Die Bildung von Fluorisocyanat (F—NCO) in Argonmatrix

Matrix samples of F-CO-N3, and X-CO-NF2 (X = H, NF2, CF3) were photolyzed by mercury arc light and the new infrared bands at 2172, 861, 695, 646, 529 cm-1 assigned to the F-NCO molecule. 15N isotopic substitution confirmed the assignment of the IR bands of the new compound

A party that backed deal with Europe could win support from both Leavers and Remainers

Richard P Bentall, Paul Willner and Todd K. Hartman present findings from a recent survey measuring Leave and Remain identities, which also tested for how acceptable participants found specific policies aimed at Britain’s future relationship with Europe. They write that the policy of remaining outside the EU but seeking closer alignment with it is not toxic for people who had identified as either Leavers or Remainers

New research shows freedom of movement is not toxic to Leavers, who are almost as positive about it as Remainers

There is a widespread assumption that freedom of movement with the EU is highly unpopular among people who identify as Leavers. Paul Willner, Todd Hartman, and Richard Bentall present data from a large (>2K) sample showing that this assumption is mistaken: freedom of movement is almost as acceptable to Leavers as it is to Remainers. This finding has implications for the positioning of political parties on freedom of movement and membership of the EU Single Market

Boost regulator design and development

Design criteria for pulse and frequency modulated boost regulato

Influence of density and temperature on the microscopic structure and the segmental relaxation of polybutadiene

We investigate the influence of temperature and density on the local structure and the dynamics of polybutadiene by controlling both hydrostatic pressure and temperature in polarized neutron diffraction experiments on deuterated polybutadiene and in inelastic incoherent scattering experiments on protonated polybutadiene. We observe that the static structure factor S(Q) does not change along macroscopic isochores. This behavior is contrary to the relaxations observed on the nanosecond and picosecond time scales and viewed by the dynamic incoherent scattering law S(Q,omega), which differ strongly along the same thermodynamic path. We conclude that the static behavior, i.e., S(Q), is dominated by macroscopic density changes, similar to the vibrational excitations in the meV range. However, the relaxation dynamics is more sensitive to thermal energy changes. This is confirmed by the finding that lines of identical relaxation behavior (in time, shape, and Q dependence), isochrones on the 10(-9) sec time scale, clearly cross the constant density lines in the (P,T) plane. Concerning S(Q), we can reasonably relate the variation of the main-peak position to the average neighbor chain distance and deduce crude microscopic thermal expansion and compressibility coefficients. In the low-Q regime, the observed pressure and temperature variation of S(Q) exceeds the compressibility contribution and suggests the existence of additional scattering, which might originate from structural correlations arising at higher temperature and low pressure

Coherent electronic and nuclear dynamics in a rhodamine heterodimer-DNA supramolecular complex

Elucidating the role of quantum coherences in energy migration within biological and artificial multichromophoric antenna systems is the subject of an intense debate. It is also a practical matter because of the decisive implications for understanding the biological processes and engineering artificial materials for solar energy harvesting. A supramolecular rhodamine heterodimer on a DNA scaffold was suitably engineered to mimic the basic donor-acceptor unit of light-harvesting antennas. Ultrafast 2D electronic spectroscopic measurements allowed identifying clear features attributable to a coherent superposition of dimer electronic and vibrational states contributing to the coherent electronic charge beating between the donor and the acceptor. The frequency of electronic charge beating is found to be 970 cm-1 (34 fs) and can be observed for 150 fs. Through the support of high level ab initio TD-DFT computations of the entire dimer, we established that the vibrational modes preferentially optically accessed do not drive subsequent coupling between the electronic states on the 600 fs of the experiment. It was thereby possible to characterize the time scales of the early time femtosecond dynamics of the electronic coherence built by the optical excitation in a large rigid supramolecular system at a room temperature in solution. © 2017 the Owner Societies.Multi valued and parallel molecular logi

On the effects of roughness on the nonlinear dynamics of a bolted joint: a multiscale analysis

Accurate prediction of the vibration response of friction joints is of great importance when estimating both the performance and the life of build-up structures. The contact conditions at the joint interface, including local normal load distribution and contact stiffness, play a critical role in the nonlinear dynamic response. These parameters strongly depend on the mating surfaces, where the surface roughness is well known to have a significant impact on the contact conditions in the static case. In contrast, its effects on the global and local nonlinear dynamic response of a build-up structure is not as well understood due to the complexity of the involved mechanisms. To obtain a better understanding of the dependence of the nonlinear dynamic response on surface roughness, a newly proposed multiscale approach has been developed. It links the surface roughness to the contact pressure and contact stiffness, and in combination with a multiharmonic balance solver, allows to compute the nonlinear dynamic response for different interface roughness. An application of the technique to a single bolted lap joint highlighted a strong impact of larger roughness values on the pressure distribution and local contact stiffness and in turn on the nonlinear dynamic response

Performance analysis of d-dimensional quantum cryptography under state-dependent diffraction

Standard protocols for quantum key distribution (QKD) require that the sender be able to transmit in two or more mutually unbiased bases. Here, we analyze the extent to which the performance of QKD is degraded by diffraction effects that become relevant for long propagation distances and limited sizes of apertures. In such a scenario, different states experience different amounts of diffraction, leading to state-dependent loss and phase acquisition, causing an increased error rate and security loophole at the receiver. To solve this problem, we propose a pre-compensation protocol based on pre-shaping the transverse structure of quantum states. We demonstrate, both theoretically and experimentally, that when performing QKD over a link with known, symbol-dependent loss and phase shift, the performance of QKD will be better if we intentionally increase the loss of certain symbols to make the loss and phase shift of all states same. Our results show that the pre-compensated protocol can significantly reduce the error rate induced by state-dependent diffraction and thereby improve the secure key rate of QKD systems without sacrificing the security.Comment: 10 pages, 6 figure