4,879 research outputs found
Antiferromagnetic spin-coupling between MnII and amminium radical cation ligands: models for coordination polymer magnets
One and two electron oxidation of the manganese(II) complex [L2Mn(hfac)2] {L = 4'',4'''-di-tert-butyl-2',2'',2'''trimethoxy-{4-(4'-diphenylaminophenyl)pyridine} were studied by ultra violet/ visible/ near infra red spectroscopy, cyclic voltammetry and magnetometry. A one-electron oxidation converts the triarylamine ligand to its radical cation and gives a complex in which the antiferromagnetic coupling between the spin on the ligand and that on the metal J/kb is -1.5 K. In a dilute frozen matrix and at low temperature this behaves as an S = 2 system. A two electron oxidation gives [L2Mn(hfac)2]2.+ which at low enough temperatures behaves as an S = 3/2 system but the spin-coupling between the metal and the ligand is weaker (J/kb = -0.3 K). The weakness of these spin-couplings mean that MnII/amminium radical cation complexes are not promising systems on which to base coordination polymer magnets. The equivalent copper(II) complex [L2Cu(hfac)2] was also investigated but this decomposes when an attempt is made to oxidise the ligand to its amminium radical cation
Immunological studies on the light-harvesting polypeptides of photosystems I and II
AbstractMonoclonal and polyclonal antibodies have been raised against the three apoproteins of the peripheral light-harvesting complex of photosystem I (LHC I) from Pisum sativum L. These antibodies have been used to study the immunological relatedness of the light-harvesting polypeptides of photosystems I and II. The results suggest that there is no immunological/structural relationship between the two light-harvesting systems. The apoproteins of the LHC I fall into two distinct groups corresponding to the two chlorophyllab complexes comprising the PS I antenna
A Cascade Neural Network Architecture investigating Surface Plasmon Polaritons propagation for thin metals in OpenMP
Surface plasmon polaritons (SPPs) confined along metal-dielectric interface
have attracted a relevant interest in the area of ultracompact photonic
circuits, photovoltaic devices and other applications due to their strong field
confinement and enhancement. This paper investigates a novel cascade neural
network (NN) architecture to find the dependance of metal thickness on the SPP
propagation. Additionally, a novel training procedure for the proposed cascade
NN has been developed using an OpenMP-based framework, thus greatly reducing
training time. The performed experiments confirm the effectiveness of the
proposed NN architecture for the problem at hand
A hybrid neuro--wavelet predictor for QoS control and stability
For distributed systems to properly react to peaks of requests, their
adaptation activities would benefit from the estimation of the amount of
requests. This paper proposes a solution to produce a short-term forecast based
on data characterising user behaviour of online services. We use \emph{wavelet
analysis}, providing compression and denoising on the observed time series of
the amount of past user requests; and a \emph{recurrent neural network} trained
with observed data and designed so as to provide well-timed estimations of
future requests. The said ensemble has the ability to predict the amount of
future user requests with a root mean squared error below 0.06\%. Thanks to
prediction, advance resource provision can be performed for the duration of a
request peak and for just the right amount of resources, hence avoiding
over-provisioning and associated costs. Moreover, reliable provision lets users
enjoy a level of availability of services unaffected by load variations
Heat flux effects on magnetic field dynamics in solid density plasmas traversed by relativistic electron beams
Relativistic electron beam propagation through solid density plasma is a rich area for magnetic field dynamics. It is well known that Ohmic heating of the background plasma caused by the beam significantly affects magnetic field generation, primarily through changes in the resistivity. In particular, temperature changes in the background plasma leads to the generation of a magnetic field that acts to deflect relativistic electrons from the beam axis. This 'beam hollowing' field could have disastrous implications for the fast ignitor scheme. In this paper, the effects of background heat flow on magnetic field generation are considered, first with a simple analytic investigation, and then with 1D Vlasov Fokker–Planck and classical transport simulations using a rigid beam for the fast electrons. It is shown that the thermal conduction of the background plasma acts to diffuse the temperature, reducing both the temperature gradients and the beam hollowing field. This gives rise to the re-emergence of a collimating magnetic field. The influence of the background heat flux is also investigated in the context of solids with imposed resistivity gradients, and is shown to significantly enhance the magnetic field present. More exotic transport effects, such as an enhanced Nernst velocity (due to non-local heat flux) and double peaked temperature profiles (due to distortion of the heating and heat-flow profiles by the magnetic field), are also reported
Impact of climate change and population growth on a risk assessment for endocrine disruption in fish due to steroid estrogens in England and Wales
In England and Wales, steroid estrogens: estrone, estradiol and ethinylestradiol have previously been identified as the main chemicals causing endocrine disruption in male fish. A national risk assessment is already available for intersex in fish arising from estrogens under current flow conditions. This study presents, to our knowledge, the first set of national catchment-based risk assessments for steroid estrogen under future scenarios. The river flows and temperatures were perturbed using three climate change scenarios (ranging from relatively dry to wet). The effects of demographic changes on estrogen consumption and human population served by sewage treatment works were also included. Compared to the current situation, the results indicated increased future risk:the percentage of high risk category sites, where endocrine disruption is more likely to occur, increased. These increases were mainly caused by changes in human population. This study provides regulators with valuable information to prepare for this potential increased risk
Geodetic precession and frame dragging observed far from massive objects and close to a gyroscope
Total precession (geodetic precession and frame dragging) depends on the
velocity of each source of gravitation, which means that it depends on the
choice of the coordinate system. We consider the latter as an anomaly
specifically in the Gravity Probe B experiment, we investigated it and solved
this anomaly. Thus, we proved that if our present expression for the geodetic
precession is correct, then the frame dragging should be 25% less than its
predicted value.Comment: 11 page
Practice pointer: Using the new UK-WHO growth charts
The new UK growth charts for children aged 0-4 years (designed using data from the new WHO standards) describe the optimal pattern of growth for all children, rather than the prevailing pattern in the UK (as with previous charts).
The new charts are suitable for all ethnic groups and set breast feeding as the norm.
UK children match the new charts well for length and height, but after age 6 months fewer children will be below the 2nd centile for weight or show weight faltering, and more will be above the 98th centile.
The new charts look different: they have a separate preterm section, no lines between 0 and 2 weeks, and the 50th percentile is no longer emphasised.
The charts give clear instructions on gestational correction, and there is a new chart for infants born before 32 weeks’ gestation.
The instructions advise on when and how to measure and when a measurement or growth pattern is outside the normal range.
The charts include a “look-up” tool for determining the body mass index centile from height and weight centiles without calculation and aid for predicting adult height.
The charts and supporting educational materials can be downloaded from www.growthcharts.rcpch.ac.u
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