19,578 research outputs found

    4-Methyl-2,6-bis(phosphonomethyl)phenol dihydrate

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    The 4-methyl-2,6-bis(phosphomethyl)phenol molecule, which crystallizes with two water molecules per asymmetric unit, has approximate twofold symmetry and is involved in extensive three-dimensional hydrogen bonding in which every available OH group participates. The principal dimensions include P--O 1.4981 (13) and 1.5015 (14) ,~, four P--OH distances in the range 1.5395(14) to 1.5688(13) A, P--C 1.7857(17) and 1.7893 (17) ~k, and O...O intramolecular and intermolecular hydro.gen-bond distances in the range 2.458 (2) to 2.866 (2) A

    Sleepwalking into the ‘post-racial’: social policy and research-led teaching

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    Research-led teaching is the sine qua non of the 21st century university. To understand its possibilities for teaching and learning about race in Social Policy requires, as a first step, interrogating the epistemological and theoretical core of the discipline, as well as its organisational dynamics. Using parts of Emirbayer and Desmond’s (2012) framework of disciplinary reflexivity, this article traces the discipline’s habits of thought but also its lacunae in the production of racial knowledge. This entails focusing on its different forms of institutionalised and epistemological whiteness, and what has shaped the omission or marginalisation of a full understanding of the racialisation of welfare subjects and regimes in the discipline. Throughout, the article offers alternative analyses and thinking that fully embrace the historical and contemporary role of race, racism, and nation in lived realities, institutional processes, and global racial orders. It concludes with pointers towards a re-envisioning of Social Policy, within a framework in which postcolonial and intersectional theory and praxis are championed. Only then might a decolonised curriculum be possible in which race is not peripheral to core teaching and learning

    Insolation driven variations of Mercury’s lithospheric strength

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    Mercury's coupled 3:2 spin-orbit resonance in conjunction with its relatively high eccentricity of ~0.2 and near-zero obliquity results in both a latitudinal and longitudinal variation in annual average solar insolation and thus equatorial hot and cold regions. This results in an asymmetric temperature distribution in the lithosphere and a long wavelength lateral variation in lithosphere structure and strength that mirrors the insolation pattern. We employ a thermal evolution model for Mercury generating strength envelopes of the lithosphere to demonstrate and quantify the possible effects the insolation pattern has on Mercury's lithosphere. We find the heterogeneity in lithosphere strength is substantial and increases with time. We also find that a crust thicker than that of the Moon or Mars and dry rheologies for the crust and mantle are favorable when compared with estimates of brittle-ductile transition depths derived from lobate scarps. Regions of stronger and weaker compressive strength imply that the accommodation of radial contraction of Mercury as its interior cooled, manifest as lobate scarps, may not be isotropic, imparting a preferential orientation and distribution to the lobate scarps

    Search for Rapid Changes in the Visible-Light Corona during the 21 June 2001 Total Solar Eclipse

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    Some 8000 images obtained with the SECIS fast-frame CCD camera instrument located at Lusaka, Zambia, during the total eclipse of 21 June 2001 have been analyzed to search for short-period oscillations in intensity that could be a signature of solar coronal heating mechanisms by MHD wave dissipation. Images were taken in white- light and Fe XIV green-line (5303 A) channels over 205 seconds (frame rate 39 s-1), approximately the length of eclipse totality at this location, with a pixel size of four arcseconds square. The data are of considerably better quality than were obtained during the 11 August 1999 total eclipse, observed by us (Rudawy et al.: Astron. Astrophys. 416, 1179, 2004), in that the images are much better exposed and enhancements in the drive system of the heliostat used gave a much improved image stability. Classical Fourier and wavelet techniques have been used to analyze the emission at 29518 locations, of which 10714 had emission at reasonably high levels, searching for periodic fluctuations with periods in the range 0.1-17 seconds (frequencies 0.06-10 Hz). While a number of possible periodicities were apparent in the wavelet analysis, none of the spatially and time-limited periodicities in the local brightness curves was found to be physically important. This implies that the pervasive Alfven wave-like phenomena (Tomczyk et al.: Science 317, 1192, 2007) using polarimetric observations with the CoMP instrument do not give rise to significant oscillatory intensity fluctuations.Comment: Accepted by Solar Physics; 16 figure

    What’s Good in Theory May Be Flawed in Practice: Potential Legal Consequences of Poor Implementation of a Theoretical Sample

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    This article discusses the problems with the use of statistical sampling in litigation. Sample-based research is increasingly used in a diverse array of cases including products liability, antitrust, intellectual property, and criminal law. Sample-based research provides objective evidence upon which decisions, damages, and liability may rest. Despite its importance, however, statistical evidence is often misused and misunderstood by attorneys unfamiliar with the underlying form of analysis. This article explores common errors when using litigative samples, comments upon best practices for the use in law of sample-based research, and demonstrates the importance of sound statistical sampling and data collection in a recent case

    Investment Dispute Prevention and Management Agencies: Toward a more informed policy discussion

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    Community acquired acute kidney injury: findings from a large population cohort

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    Background: The extent of patient contact with medical services prior to development of community acquired-acute kidney injury (CA-AKI)is unknown. Aim: We examined the relationship between incident CA-AKI alerts, previous contact with hospital or primary care and clinical outcomes. Design: A prospective national cohort study of all electronic AKIalerts representing adult CA-AKI. Methods: Data were collected for all cases of adult (≥18 years of age) CA-AKI in Wales between 1 November 2013 and 31 January 2017. Results: There were a total of 50 560 incident CA-AKI alerts. In 46.8% there was a measurement of renal function in the 30 days prior to the AKI alert. In this group, in 63.8% this was in a hospital setting, of which 37.6% were as an inpatient and 37.5% in Accident and Emergency. Progression of AKI to a higher AKI stage (13.1 vs. 9.8%, P  50% from the creatinine value generating the alert), the proportion of patients admitted to Intensive Care (5.5 vs. 4.9%, P = 0.001) and 90-day mortality (27.2 vs. 18.5%, P < 0.001) was significantly higher for patients with a recent test. 90-day mortality was highest for patients with a recent test taken in an inpatient setting prior to CA-AKI (30.9%). Conclusion: Almost half of all patients presenting with CA-AKI are already known to medical services, the majority of which have had recent measurement of renal function in a hospital setting, suggesting that AKI for at least some of these may potentially be predictable and/or avoidable
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