5,849 research outputs found
Case Report: Color as a Therapeutic Intervention
Peer reviewedFinal Accepted Versio
Developing site-specific guidelines for orchard soils based on bioaccessibility – Can it be done?
Horticultural land within the periurban fringe of NZ towns and cities increasingly is being developed for residential subdivision. Recent surveys have shown that concentrations of As, Cd, Cu, Pb, and ΣDDT (sum of DDT and its degradation products DDE and DDD) in such soils can exceed criteria protective of human health.¹ Soil ingestion is a key exposure pathway for non-volatile contaminants in soil. Currently in NZ, site-specific risk assessments and the derivation of soil guidelines protective of human health assume that all of the contaminant present in the soil is available for uptake and absorption by the human gastrointestinal tract. This assumption can overestimate health risks and has implications for the remediation of contaminated sites.² In comparison, the bioavailability of contaminants is considered when estimating exposure via dermal absorption and by ingestion of home-grown produce.³ Dermal absorption factors and plant uptake factors are included in the calculations for estimating exposures via these routes
Determination of the Antiferroquadrupolar Order Parameters in UPd3
By combining accurate heat capacity and X-ray resonant scattering results we
have resolved the long standing question regarding the nature of the
quadrupolar ordered phases in UPd_3. The order parameter of the highest
temperature quadrupolar phase has been uniquely determined to be antiphase
Q_{zx} in contrast to the previous conjecture of Q_{x^2-y^2} . The azimuthal
dependence of the X-ray scattering intensity from the quadrupolar superlattice
reflections indicates that the lower temperature phases are described by a
superposition of order parameters. The heat capacity features associated with
each of the phase transitions characterize their order, which imposes
restrictions on the matrix elements of the quadrupolar operators.Comment: 4 pages, 5 figure
Resonant X-Ray Scattering on the M-Edge Spectra from Triple-k Structure Phase in U_{0.75}Np_{0.25}O_{2} and UO_{2}
We derive an expression for the scattering amplitude of resonant x-ray
scattering under the assumption that the Hamiltonian describing the
intermediate state preserves spherical symmetry. On the basis of this
expression, we demonstrate that the energy profile of the RXS spectra expected
near U and Np M_4 edges from the triple-k antiferromagnetic ordering phase in
UO_{2} and U_{0.75}Np_{0.25}O_{2} agree well with those from the experiments.
We demonstrate that the spectra in the \sigma-\sigma' and \sigma-\pi' channels
exhibit quadrupole and dipole natures, respectively.Comment: 3 pages, 3 figures, to be published in J. Phys. Soc. Jpn. Supp
Phase transformation in Si from semiconducting diamond to metallic beta-Sn phase in QMC and DFT under hydrostatic and anisotropic stress
Silicon undergoes a phase transition from the semiconducting diamond phase to
the metallic beta-Sn phase under pressure. We use quantum Monte Carlo
calculations to predict the transformation pressure and compare the results to
density functional calculations employing the LDA, PBE, PW91, WC, AM05, PBEsol
and HSE06 exchange-correlation functionals. Diffusion Monte Carlo predicts a
transition pressure of 14.0 +- 1.0 GPa slightly above the experimentally
observed transition pressure range of 11.3 to 12.6 GPa. The HSE06 hybrid
functional predicts a transition pressure of 12.4 GPa in excellent agreement
with experiments. Exchange-correlation functionals using the local-density
approximation and generalized-gradient approximations result in transition
pressures ranging from 3.5 to 10.0 GPa, well below the experimental values. The
transition pressure is sensitive to stress anisotropy. Anisotropy in the stress
along any of the cubic axes of the diamond phase of silicon lowers the
equilibrium transition pressure and may explain the discrepancy between the
various experimental values as well as the small overestimate of the quantum
Monte Carlo transition pressure
Flaring from the supermassive black hole in Mrk 335 studied with Swift and NuSTAR
Monitoring of the narrow line Seyfert 1 galaxy Markarian 335 (Mrk 335) with the Swift satellite discovered an X-ray flare beginning 2014 August 29. At the peak, the 0.5–5 keV count rate had increased from that in the low-flux state by a factor of 10. A target of opportunity observation was triggered with NuSTAR, catching the decline of the flare on 2014 September 20. We present a joint analysis of Swift and NuSTAR observations to understand the cause of this flare. The X-ray spectrum shows an increase in directly observed continuum flux and the softening of the continuum spectrum to a photon index of 2.49 +0.08/−0.072.49−0.07+0.08 compared to the previous low-flux observations. The X-ray spectrum remains well described by the relativistically blurred reflection of the continuum from the accretion disc whose emissivity profile suggests that it is illuminated by a compact X-ray source, extending at most 5.2 rg over the disc. A very low reflection fraction of 0.41+0.15−0.150.41−0.15+0.15 is measured, unexpected for such a compact corona. The X-ray flare is, hence, interpreted as arising from the vertical collimation and ejection of the X-ray emitting corona at a mildly relativistic velocity, causing the continuum emission to be beamed away from the disc. As the flare subsides, the base of this jet-like structure collapses into a compact X-ray source that provides the majority of the radiation that illuminates the disc while continuum emission is still detected from energetic particles further out, maintaining the low reflection fraction
Estuary-associated syndrome in North Carolina: an occupational prevalence study.
Atlantic coast estuaries recently have experienced fish kills and fish with lesions attributed to Pfiesteria piscicida and related dinoflagellates. Human health effects have been reported from laboratory exposure and from a 1997 Maryland fish kill. North Carolina has recorded Pfiesteria-related fish kill events over the past decade, but human health effects from environmental exposure have not been systematically investigated or documented here. At the request of the state health agency, comprehensive examinations were conducted in a cross-sectional prevalence study of watermen working where Pfiesteria exposure may occur: waters where diseased or stressed fish were reported from June to September 1997, and where Pfiesteria had been identified in the past. Controls worked on unaffected waterways. The study was conducted 3 months after the last documented Pfiesteria-related fish kill. The goal was to document any persistent health effects from recent or remote contact with fish kills, fish with lesions, or affected waterways, using the 1997 U.S. Centers for Disease Control and Prevention case description for estuary-associated syndrome (EAS). Examinations included comprehensive medical, occupational, and environmental history, general medical, dermatologic, and neurologic examinations, vision testing, and neuropsychologic evaluations. Seventeen of 22 watermen working in affected waters and 11 of 21 in unaffected waters reported exposure to a fish kill or to fish with lesions. We found no pattern of abnormalities on medical, neurologic, neuropsychologic, or NES-2 evaluation. By history, one subject in each group met the EAS criteria, neither of whom had significant neuropsychological impairment when examined. Watermen from affected waterways had a significant reduction in visual contrast sensitivity (VCS) at the midspatial frequencies, but we did not identify a specific factor or exposure associated with this reduction. The cohorts did not differ in reported occupational exposure to solvents (qualitative) or to other neurotoxicants; however, exposure history was not sufficiently detailed to measure or control for solvent exposure. This small prevalence study in watermen, conducted 3 months after the last documented fish kill related to Pfiesteria, did not identify an increased risk of estuary-associated syndrome in those working on affected waterways. A significant difference between the estuary and ocean watermen was found on VCS, which could not be attributed to any specific factor or exposure. VCS may be affected by chemicals, drugs, alcohol, and several developmental and degenerative conditions; it has not been validated as being affected by known exposure to dinoflagellate secretions. VCS should be considered for inclusion in further studies, together with documentation or quantification of its potential confounders, to assess whether it has utility in relationship to dinoflagellate exposure
Soft X-ray resonant scattering study of single-crystal LaSrMnO
Soft X-ray resonant scattering studies at the Mn - and
the La - edges of single-crystal LaSrMnO are
reported. At low temperatures, below K, energy scans
with a fixed momentum transfer at the \emph{A}-type antiferromagnetic (0 0 1)
reflection around the Mn -edges with incident linear
and polarizations show strong resonant enhancements. The
splitting of the energy spectra around the Mn -edges may
indicate the presence of a mixed valence state, e.g., Mn/Mn. The
relative intensities of the resonance and the clear shoulder-feature as well as
the strong incident and polarization dependences strongly
indicate its complex electronic origin. Unexpected enhancement of the charge
Bragg (0 0 2) reflection at the La -edges with
polarization has been observed up to 300 K, with an anomaly appearing around
the orbital-ordering transition temperature, K,
suggesting a strong coupling (competition) between them.Comment: Accepted by European Physical Journal
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