Extraction of contact resistance in carbon nanofiber via interconnects with varying lengths

A method to extract the contact resistance and bulk resistivity of vertically grown carbon nanofibers (CNFs) or similar one-dimensional nanostructures is described. Using a silicon-compatible process to fabricate a terrace test structure needed for the CNF length variation, the contact resistance is extracted by measuring in situ the resistances of individual CNFs with different lengths and within a small range of diameters using a nanoprober inside a scanning electron microscope. Accurate determination of contact resistances for various combinations of catalysts and underlayer metals can lead to eventual optimization of materials’ growth and device fabrication processes for CNF via interconnects

Length dependence of current-induced breakdown in carbon nanofiber interconnects

Current-induced breakdown is investigated for carbon nanofibers (CNF) for potential interconnect applications. The measured maximum current density in the suspended CNF is inversely proportional to the nanofiber length and is independent of diameter. This relationship can be described with a heat transport model that takes into account Joule heating and heat diffusion along the CNF, assuming that breakdown occurs when and where the temperature reaches a threshold or critical value

Electrical and Structural Analysis of CNT-Metal Contacts in Via Interconnects

Vertically aligned carbon nanotubes grown by plasmaenhanced chemical vapor deposition offer a potentially suitable material for via interconnects in next-generation integrated circuits. Key performance-limiting factors include high contact resistance and low carbon nanotube packing density, which fall short of meeting the requirements delineated in the ITRS roadmap for interconnects. For individual carbon nanotube s, contact resistance is a major performance hurdle since it is the dominant component of carbon nanotube interconnect resistance, even in the case of vertically aligned carbon nanotube arrays. In this study, we correlate the carbon nanotube-metal interface nanostructure to their electrical properties in order to elucidate growth parameters that can lead to high density and low contact resistance and resistivity

Change in carbon nanofiber resistance from ambient to vacuum

The electrical properties of carbon nanofibers (CNFs) can be affected by adsorbed gas species. In this study, we compare the resistance values of CNF devices in a horizontal configuration in air and under vacuum. CNFs in air are observed to possess lower current capacities compared to those in vacuum. Further, Joule heating due to current stressing can result in desorption of gas molecules responsible for carrier trapping, leading to lower resistances and higher breakdown currents in vacuum, where most adsorbed gaseous species are evacuated before any significant re-adsorption can occur. A model is proposed to describe these observations, and is used to estimate the number of adsorbed molecules on a CNF device

Improved contact for thermal and electrical transport in carbon nanofiber interconnects

We study the performance and reliability of carbon nanofiber (CNF) interconnects under high-current stress by examining CNF breakdown for four test configurations, suspended/supported with/without tungsten deposition. The use of W is to improve the CNF-electrode contact. The supported cases show a larger current density just before breakdown than the suspended ones, suggesting an effective heat dissipation to the substrate. The W-deposited contacts reduce the initial total resistance from megaohm range without W to kilo-ohms. High-current stress does not change the total resistance of the test structures with W unlike those without W deposition

Tunneling between carbon nanofiber and gold electrodes

In a carbon nanofiber (CNF)-metal system such as a bridge between two gold electrodes, passing high current (current stressing) reduces the total resistance of the system (CNF resistance RCNF plus contact resistance Rc) by orders of magnitude. The role of current stressing is modeled as a reduction in the interfacial tunneling gap with transport characteristics attributed to tunneling between Au and CNF. The model predicts a reduction in Rc and gradual disappearance of the nonlinearity in the current-voltage (I-V) characteristics as Rc decreases. These results are consistent with measured I-V behavior

Contact resistance in carbon nanostructure via interconnects

We present an in-depth electrical characterization of contact resistance in carbon nanostructure via interconnects. Test structures designed and fabricated for via applications contain vertically aligned arrays of carbon nanofibers (CNFs) grown on a thin titanium film on silicon substrate and embedded in silicon dioxide. Current-voltage measurements are performed on single CNFs using atomic force microscope current-sensing technique. By analyzing the dependence of measured resistance on CNF diameter, we extract the CNF resistivity and the metal-CNF contact resistance

Thermoreflectance small scale temperature measurement under ambient conditions

Paper presented at the 9th International Conference on Heat Transfer, Fluid Mechanics and Thermodynamics, Malta, 16-18 July, 2012.dc201

Thermoreflectance of carbon nanofibers: joule heating experiment and calibration

Paper presented to the 10th International Conference on Heat Transfer, Fluid Mechanics and Thermodynamics, Florida, 14-16 July 2014.Thermoreflectance (TR) is a novel, non-contact technique that uses the change in surface reflectivity over optical wavelengths of light to deduce temperature. This reflectivity is also wavelength dependent and material dependent. By calibrating a sample to determine the TR coefficient k, the relative change in intensity per degree change in temperature, the difference between heated and cool images is used to measure the relative temperature change. A two-dimensional, steady state TR method is used to examine the thermoreflectance behavior of carbon nanofibers (CNFs). Signal mixing between the CNF and the substrate at the sub-micron level is minimized by use of gold at its TR cross-point. A TR signal is created by the CNF as it is subject to Joule heating by passing a constant current through it. The calibration coefficient is measured though uniform heating of the sample. Initially, imaging during the heating process suffered from image shifting caused by air currents. Once the visible shifting is removed, the TR coefficient kcomp derived from the heating experiment was 7.93 x 10-5/K. To validate these results, the TR signal from a CNF undergoing Joule heating and the predicted temperature from a heat-transfer model were used to produce a second calibration, yielding a TR coefficient kJoule of 2.45 x 10-5/K. The discrepancy between the two TR coefficients suggests that further experiments are needed to determine more accurately the CNF TR coefficient.cf201

Thrombopoietin: A Novel Bone Healing Agent

poster abstractCritical-size defects in bones do not heal spontaneously and usually require the use of grafts. Unfortunately, grafts have several limitations. To improve bone formation, many clinicians now use bone morphogenetic proteins (BMP), particularly in spinal fusion, fracture healing, and in critical-size defect regeneration. However, multiple side effects of BMP treatment have been uncovered including increased incidence of cancer. Thus, there is great interest in alternatives that allow for safe and effective bone regeneration. Here we show the ability of thrombopoietin (TPO), the main megakaryocyte growth factor, to heal critical-size femoral defects rodents. 5mm or 4mm segmental defects were created in the femur of Long Evans rats or C57BL/6 mice, respectively. The defects were filled with a novel bioabsorbable scaffold which was loaded with recombinant human TPO, BMP-2, or saline, and held stable by a retrograde 1.6 mm intramedullary Kirschner wire (rats) or 23G needle (mice). Xrays were taken every 3 weeks in rats and weekly in mice. Animal were sacrificed at 15 weeks, at which time micro-computed tomography (μCT) and histological analyses were performed. The results observed in mice and rats were similar. The saline control group did not show bridging callus at any time. Both the BMP-2 and TPO groups healed the defect, although bridging callus was evident at earlier times in the BMP-2 groups. However, the TPO groups showed a much more remodeled and physiologic contour on both Xray and μCT. μCT and histological analysis confirms that compared to BMP-2, TPO-treated specimens have a thicker cortex but smaller diameter and smoother contour. TPO appears to restore the original bone contour by stimulating osteoblastogenesis, allowing for periosteal bridging and stabilization to occur, while simultaneously stimulating osteoclast formation. Thus, TPO may serve as a novel bone healing agent