Continuous wave detector has wide frequency range

Portable battery-operated detector indicates the presence of steady state signals exceeding a predetermined value over a wide frequency range by the closure of output relay contacts. It was designed to monitor electronic equipment used in the Saturn 2 program

Solvent promoted reversible cyclometalation in a tethered NHC iridium complex

Reaction of [Ir(COD)(py–ItBu)]+ (py–ItBu = 3-tert-butyl-1-picolylimidazol-2-ylidene) with acetonitrile results in reversible intramolecular C–H bond activation of the NHC ligand and formation of [Ir(η2:η1-C8H13)(py–ItBu′)(NCMe)]+. Coordinated COD acts as an internal hydride acceptor and acetonitrile coordination offsets the otherwise unfavourable thermodynamics of the process

Relationship between the Linear Ringing Frequencies in 3He-A and 3He-B near the Polycritical Point

New measurements of parallel ringing in a quasi-ideal geometry for 3He-B near the temperature and pressure of the polycritical point suggest fB2/fA2∼5/2, where fB and fA are the linear parallel-ringing frequencies at a given temperature near Tc. This result approaches the prediction of theory using the Anderson-Brinkman-Morel and Balian-Werthamer states to describe 3He-A and 3He-B, respectively, and hence the results of Osheroff at melting pressure, but disagrees with earlier observations at pressures near the polycritical point

Relaxation of the Wall-Pinned Magnetization Ringing Mode in Superfluid 3He-B

Observations of the wall-pinned mode in 3He-B allow new magnetic relaxation phenomena to be studied. Excepting the quantitative value of the zero-time ringing frequency, comparison of experiment with theory is satisfactory, including a linear dependence of the square of the ringing period on time and a square-root singularity near Tc in the relaxation parameter

Nonlinear Parallel Ringing of Magnetization in Superfluid 3He

Experiments based on an analogy to the ac Josephson effect have shown in both 3He-A and 3He-B that a pairing theory of the superfluidity of 3He is essentially correct. Additional observations of parallel ringing are not in agreement with the simple pendulum models used to describe nonlinear dynamic magnetic effects

Thermodynamically consistent equilibrium properties of normal-liquid Helium-3

The high-precision data for the specific heat C_{V}(T,V) of normal-liquid Helium-3 obtained by Greywall, taken together with the molar volume V(T_0,P) at one temperature T_0, are shown to contain the complete thermodynamic information about this phase in zero magnetic field. This enables us to calculate the T and P dependence of all equilibrium properties of normal-liquid Helium-3 in a thermodynamically consistent way for a wide range of parameters. The results for the entropy S(T,P), specific heat at constant pressure C_P(T,P), molar volume V(T,P), compressibility kappa(T,P), and thermal expansion coefficient alpha(T,P) are collected in the form of figures and tables. This provides the first complete set of thermodynamically consistent values of the equilibrium quantities of normal-liquid Helium-3. We find, for example, that alpha(T,P) has a surprisingly intricate pressure dependence at low temperatures, and that the curves alpha(T,P) vs T do not cross at one single temperature for all pressures, in contrast to the curves presented in the comprehensive survey of helium by Wilks. Corrected in cond-mat/9906222v3: The sign of the coefficient d_0 was misprinted in Table I of cond-mat/9906222v1 and v2. It now correctly reads d_0=-7.1613436. All results in the paper were obtained with the correct value of d_0. (We would like to thank for E. Collin, H. Godfrin, and Y. Bunkov for finding this misprint.)Comment: 19 pages, 19 figures, 9 tables; published version; note added in proof; v3: misprint correcte

Adaptive Optical Phase Estimation Using Time-Symmetric Quantum Smoothing

Quantum parameter estimation has many applications, from gravitational wave detection to quantum key distribution. We present the first experimental demonstration of the time-symmetric technique of quantum smoothing. We consider both adaptive and non-adaptive quantum smoothing, and show that both are better than their well-known time-asymmetric counterparts (quantum filtering). For the problem of estimating a stochastically varying phase shift on a coherent beam, our theory predicts that adaptive quantum smoothing (the best scheme) gives an estimate with a mean-square error up to $2\sqrt{2}$ times smaller than that from non-adaptive quantum filtering (the standard quantum limit). The experimentally measured improvement is $2.24 \pm 0.14$

Concentration Dependence of the Effective Mass of He-3 Atoms in He-3/He-4 Mixtures

Recent measurements by Yorozu et al. (S. Yorozu, H. Fukuyama, and H. Ishimoto, Phys. Rev. B 48, 9660 (1993)) as well as by Simons and Mueller (R. Simons and R. M. Mueller, Czhechoslowak Journal of Physics Suppl. 46, 201 (1976)) have determined the effective mass of He-3 atoms in a He-3/He-4 mixture with great accuracy. We here report theoretical calculations for the dependence of that effective mass on the He-3 concentration. Using correlated basis functions perturbation theory to infinite order to compute effective interactions in the appropriate channels, we obtain good agreement between theory and experiment.Comment: 4 pages, 1 figur

Efficient two-step access to azafluorenones and related compounds

International audienceCrystals of a lithiocuprate prepared from copper(I) chloride and lithium 2,2,6,6-tetramethylpiperidide (2 equiv) were isolated and analyzed by X-ray diffraction as (TMP)2Cu(Cl)Li2*THF. The observation of this species is consistent with its having a role in deprotocupration-aroylation. Phenyl pyridyl ketones, phenyl quinolyl ketones, and phenyl thienyl ketones were prepared in tetrahydrofuran using the lithiocuprate and aroyl chorides as electrophiles. Diaryl ketones bearing a chloro group at the 2 position (of a pyridyl or phenyl group) thus synthesized were next converted through palladium-catalyzed ring closure to polycycles of the 5H-indeno[1,2-b]pyridin-5-one, 11H-indeno[1,2-b]quinolin-11-one, 9H-indeno[2,1-c]pyridin-9-one, and 8H-indeno[2,1-b]thiophen-8-one families