Poly[aqua­(μ3-2-hy­droxy-5-nitro­benzoato-κ3 O 1:O 1′:O 2)rubidium]

In the structure of title compound, [Rb(C7H4NO5)(H2O)]n, the centrosymmetric cyclic dimeric repeating unit comprises two irregular RbO4 complex centres bridged by the carboxyl­ate groups of the 5-nitro­salicylate ligands. The coordination about each Rb atom is completed by a monodentate water mol­ecule and a phenolic O-atom donor which gives a bridging extension [Rb—O range = 3.116 (7)–3.135 (5) Å]. The polymeric structure is stabilized by inter­molecular water O—H⋯Ocarboxyl­ate hydrogen bonds and weak inter-ring π–π inter­actions [minimum ring centroid separation = 3.620 (4) Å]. An intramolecular O—H⋯O hydrogen bond between phenol and carboxylate groups is also present

Maximum Likelihood Estimation in Gaussian Chain Graph Models under the Alternative Markov Property

The AMP Markov property is a recently proposed alternative Markov property for chain graphs. In the case of continuous variables with a joint multivariate Gaussian distribution, it is the AMP rather than the earlier introduced LWF Markov property that is coherent with data-generation by natural block-recursive regressions. In this paper, we show that maximum likelihood estimates in Gaussian AMP chain graph models can be obtained by combining generalized least squares and iterative proportional fitting to an iterative algorithm. In an appendix, we give useful convergence results for iterative partial maximization algorithms that apply in particular to the described algorithm.Comment: 15 pages, article will appear in Scandinavian Journal of Statistic

Sexual Behaviors and Human Papillomavirus Vaccination in a Heterosexually active adult Population at increased Risk For HIV infection

Human papillomavirus (HPV) is the most common sexually acquired infection in the US. Vaccination is effective against infection with high-risk HPV strains, yet HPV vaccine coverage is lower in the US than the national target. This study aimed to determine the relationship between sexual behaviors and HPV vaccination in a heterosexually active population at increased risk for HIV infection. Data from 380 participants aged 18-45 years obtained from the National HIV Behavioral Surveillance system increased risk heterosexuals cycle 5 (2019) in Houston, Texas, was analyzed. RDS-Analyst was used to generate population-based descriptive statistics. Modified Poisson regression models clustered on recruitment chain were conducted in SAS 9.4 to assess the relationship between sexual behaviors and HPV vaccination. Only 11.5% of participants had received at least one dose of the HPV vaccine. Regarding behaviors within the past 12 months, 44.8% reported having condomless casual sex, 51.3% reported having concurrent sexual partnerships while in their most recent relationship, 14.5% reported exchanging sex, and participants had an average of 4-5 sex partners. Further, those who exchanged sex had a significantly lower prevalence of HPV vaccine uptake when compared to those who did not exchange sex (adjusted prevalence ratio 0.23; confidence interval 0.10-0.52), while all other measures of sexual behavior were not significantly associated with HPV vaccination. More research is needed to understand the relationship between exchange sex and low prevalence of vaccination, specifically in women who bear the highest burden of poor HPV-related morbidity and mortality

Awareness of Human Papillomavirus and Reported Human Papillomavirus Vaccine Uptake in a High-Risk Population

INTRODUCTION: Disparities in human papillomavirus (HPV) awareness and HPV vaccine uptake are likely exacerbated among racial/ethnic minority populations living in low-income areas. This study aims to determine the prevalence and correlates of HPV awareness and HPV vaccine uptake in an urban, low-income, racial/ethnic minority population. METHODS: Secondary data analyses were performed in 2021 using 380 participants aged 18-45 years from the 2019 National HIV Behavioral Surveillance for high-risk heterosexuals, which monitors HIV risk behaviors among individuals living in high-poverty, high HIV prevalence neighborhoods. Prevalence estimates and modified Poisson regression models were used to assess the relationship between HPV awareness and HPV vaccine uptake, and sociodemographic characteristics. RESULTS: Only 53% of participants had heard of HPV and 11.5% had received at least one dose of the HPV vaccine. Those who were female, non-Hispanic White or other, had public health insurance, lived above the federal poverty level, had experienced homelessness and incarceration, and had usual source of healthcare showed higher awareness of HPV while those who were younger, female, non-Hispanic White or other, recently incarcerated, had a usual source of healthcare, and had a healthcare encounter in the past year showed higher prevalence of HPV vaccine uptake. CONCLUSIONS: Prevalence of HPV vaccination in this high-risk population was low and there was a lack of preventive care utilization. Further research is needed on how to effectively target these populations to not only increase vaccine uptake, but to mitigate barriers that contribute to low awareness and suboptimal vaccination uptake in high-risk heterosexual populations

Diiodidobis[4-(4-nitro­benz­yl)pyridine-κN 1]zinc

The asymmetric unit of the title compound, [ZnI2(C12H10N2O2)2], obtained from the reaction of 4-(4-nitro­benz­yl)pyridine with zinc(II) iodide, contains two independent discrete distorted tetra­hedral complex units [Zn—I = 2.5472 (8)–2.5666 (7) Å and Zn—N = 2.044 (4)–2.052 (4) Å], which are essentially identical conformationally. The crystal used for measurement was a racemic twin

catena-Poly[[diaqua­lithium]-μ-[rac-cis-(2-carb­oxy­cyclo­hexane-1-carboxyl­ato-κ2 O 1:O 2]]

In the structure of the title compound, [Li(C8H11O4)(H2O)2]n, the distorted tetra­hadral LiO4 coordination sphere comprises two water mol­ecules and two carboxyl O-atom donors from separate bridging cis-2-carb­oxy­cyclo­hexane-1-carboxyl­ate monoanions [Li—O = 1.887 (4)–1.946 (3) Å], giving chain substructures which extend along [010]. Water–water and water–carboxyl O—H⋯O hydrogen bonds stabilize these chain structures and provide inter­chain links, resulting in a two-dimensional layered structure extending parallel to (100)