Durable superhydrophobic polyvinylidene fluoride membranes via facile spray-coating for effective membrane distillation

Membrane wetting and fouling substantially limits application and deployment of membrane distillation process. Designing high-performance superhydrophobic membranes offers an effective solution to solve the challenge. In this work, a highly durable superhydrophobic surface (water contact angle of 170.8 ± 1.3°) was constructed via a facile and rapid spray-coating of extremely hydrophobic SiO2 nanoparticles onto a porous polyvinylidene fluoride (PVDF) substrate for membrane distillation. The superhydrophobic membrane coated by fluorinated SiO2 nanoparticles exhibited a superior physicochemical stability in a wide range of extreme environments (i.e., NaOH, HCl, hot water, rust water, humic acid solution, ultrasonication, and high-speed water scouring). During 8-h continuous membrane distillation desalination experiment, the coated superhydrophobic membrane experienced a consistently stable water vapor flux (ca. 19.1 kg·m−2·h−1) and desalination efficiency (99.99 %). Additionally, such a stable superhydrophobicity endowed the spray-coated PVDF membrane to overcome membrane wetting and fouling during membrane distillation of highly saline solutions containing foulants (i.e., humic acid and rust). Results reported in this study provides a useful concept and strategy in facile construction of robust superhydrophobic membranes via spray-coating for effective membrane distillation.</p

Indirect influence in social networks as an induced percolation phenomenon

Significance Increasing empirical evidence in diverse social and ecological systems has shown that indirect interactions play a pivotal role in shaping systems’ dynamical behavior. Our empirical study on collaboration networks of scientists further reveals that an indirect effect can dominate over direct influence in behavioral spreading. However, almost all models in existence focus on direct interactions, and the general impact of indirect interactions has not been studied. We propose a new percolation process, termed induced percolation, to characterize indirect interactions and find that indirect interactions raise a plethora of new phenomena, including the wide range of possible phase transitions. Such an indirect mechanism leads to very different spreading outcomes from that of direct influences

Analysis of geothermal potential in Hangjiahu area based on remote sensing and geographic information system

Geothermal resources are one of the most valuable renewable energy sources because of their stability, reliability, cleanliness, safety and abundant reserves. Efficient and economical remote sensing and GIS (Geographic Information System) technology has high practical value in geothermal resources exploration. However, different study areas have different geothermal formation mechanisms. In the process of establishing the model, which factors are used for modeling and how to quantify the factors reasonably are still problems to be analyzed and studied. Taking Hangjiahu Plain of Zhejiang Province as an example, based on geothermal exploration and remote sensing interpretation data, the correlation between the existing geothermal hot spots and geothermal related factors was evaluated in this paper, such as lithology, fault zone distance, surface water system and its distance, seismic point distance, magmatic rock and volcanic rock distance, surface water, farmland, woodland temperature and so on. The relationship between geothermal potential and distribution characteristics of surface thermal environment, fault activity, surface water system and other factors was explored. AHP (Analytic Hierarchy Process) and BP (Back Propagation) neural network were used for establishing geothermal potential target evaluation models. The potential geothermal areas of Hangjiahu Plain were divided into five grades using geothermal exploration model, and most geothermal drilling sites were distributed in extremely high potential areas and high potential areas. The results show that it is feasible to analyze geothermal potential targets using remote sensing interpretation data and geographic information system analysis databased on analytic hierarchy process analytic hierarchy process and back propagation neural network, and the distribution characteristics of surface thermal environment, fault activity, surface water system and other related factors are also related to geothermal distribution. The prediction results of the model coincide with the existing geothermal drilling sites, which provides a new idea for geothermal exploration

Enhanced Carbon Dioxide Electrolysis at Redox Manipulated Interfaces

Utilization of carbon dioxide from industrial waste streams offers significant reductions in global carbon dioxide emissions. Solid oxide electrolysis is a highly efficient, high temperature approach that reduces polarization losses and best utilizes process heat; however, the technology is relatively unrefined for currently carbon dioxide electrolysis. In most electrochemical systems, the interface between active components are usually of great importance in determining the performance and lifetime of any energy materials application. Here we report a generic approach of interface engineering to achieve active interfaces at nanoscale by a synergistic control of materials functions and interface architectures. We show that the redox-manipulated interfaces facilitate the atomic oxygen transfer from adsorbed carbon dioxide molecules to the cathode lattice that determines carbon dioxide electrolysis at elevated temperatures. The composite cathodes with in situ grown interfaces demonstrate significantly enhanced carbon dioxide electrolysis and improved durability