Experimental study on tensile and shear strength of anthracite under supercritical CO2

In the process of CO2 geological sequestration, the mechanical properties of coal will be changed after supercritical CO2 interacts with coal. Based on this, in this paper, Brazilian splitting test and variable angle shear test were carried out on anthracite under different test conditions, and the changes of tensile strength, shear peak strength, residual strength, internal friction angle and cohesion of coal under different test conditions were studied and compared from two aspects of dry/saturated moisture content and supercritical CO2 soaking time(3, 5, 7 days). The results show that the tensile strength, shear strength and residual strength of coal decrease with the increase of supercritical CO2 soaking time, but the decreasing amplitude decreases gradually; the degradation effect of mechanical parameters of coal under the action of water + supercritical CO2 is greater than that of drying test group; the internal friction angle and cohesion tend to decrease with the increase of supercritical CO2 action time, but the effect of supercritical CO2 on cohesion is more obvious, but the effect of internal friction angle is less

De Novo Assembly, Characterization and Comparative Transcriptome Analysis of the Mature Gonads in <i>Spinibarbus hollandi</i>

Spinibarbus hollandi is an important commercial aquaculture species in southeastern China, but with long maturity period and low egg laying amount. However, there has been little study of its gonad development and reproductive regulation, which limits aquaculture production. Here, for the first time, gonadal transcriptomes of male and female S. hollandi were analyzed. A total of 167,152 unigenes were assembled, with only 48,275 annotated successfully. After comparison, a total of 21,903 differentially expressed genes were identified between male and female gonads, of which 16,395 were upregulated and 5508 were downregulated in the testis. In addition, a large number of differentially expressed genes participating in reproduction, gonad formation and differentiation, and gametogenesis were screened out and the differential expression profiles of partial genes were further validated using quantitative real-time PCR. These results will provide basic information for further research on gonad differentiation and development in S. hollandi

A multifunctional hydrogel fabricated via ultra-fast polymerization by graphene oxide-adsorbed liquid metal nanodroplets

Graphene structures have never been found to play a role in accelerating fabrication of functional hydrogels. In this work, it is initially discovered that multifunctional hydrogels are fabricated via ultra-fast polymerization (∼minutes) by graphene oxide-adsorbed liquid metal nanodroplets (LMNPs@GO) vs. by conventional approaches (∼hours/days). LMNPs@GO are used to rapidly initiate and further cross-link polyacrylic acid (PAA) chains into a three-dimensional (3D) network without any extra molecular initiators, cross-linkers, heat source, and/or protective gas. The polymerization process with LMNPs@GO is extremely faster than that without GO involved (20 s vs. 4 h of prepolymer formation, and then 10 min vs. 3 days of crosslinking) for free radical polymerization of PAA hydrogels. The resulting hydrogel with 2 wt% reduced graphene oxide (rGO) exhibits 600% increase in tensile strength and 950% enhancement in conductivity, as well as excellent self-healing capabilities, in comparison with that of the pure PAA. The sensitivity studies show its great potential for the application of flexible sensors. Furthermore, the hydrogel possesses good dissolving properties, which is greatly beneficial for recyclability of the LM. This creative study not only broadens a novel application of graphene for making advanced multifunctional polymer materials, but also provides a brand-new route to realization of ultra-fast manufacturing technology that is significantly promising for industrial production in wearable devices

Bioinspired Assembly of Carbon Nanotube into Graphene Aerogel with “Cabbagelike” Hierarchical Porous Structure for Highly Efficient Organic Pollutants Cleanup

Nowadays, physical absorption has become a feasible method offering an efficient and green route to remove organic pollutants from the industrial wastewater. Inspired by polydopamine (PDA) chemistry, one-dimensional PDA-functionalized multiwalled carbon nanotubes (MWCNT-PDA) were creatively introduced into graphene aerogel framework to synthesize a robust graphene/MWCNT-PDA composite aerogel (GCPCA). The whole forming process needed no additional reducing agents, significantly reducing the contamination emissions to the environment. The GCPCA exhibited outstanding repeatable compressibility, ultralight weight, as well as hydrophobic nature, which were crucial for highly efficient organic pollution absorption. The MWCNTs in moderate amounts can provide the composite aerogels with desirable structure stability and extra specific surface area. Meanwhile, the eventual absorption performance of GCPCAs can be improved by optimizing the microporous structure. In particular, a novel “cabbagelike” hierarchical porous structure was obtained as the prefreezing temperature was decreased to −80 °C. The miniaturization of pore size around the periphery of GCPCA enhanced the capillary flow in aerogel channels, and the super-absorption capacity for organic solvents was up to 501 times (chloroform) its own mass. Besides, the GCPCAs exhibited excellent reusable performance in absorption–squeezing, absorption–combustion, and absorption–distillation cycles according to the characteristic of different organic solvents. Because of the viable synthesis method, the resulting GCPCAs with unique performance possess broad and important application prospects, such as oil pollution cleanup and treatment of chemical industrial wastewater

Table_1_Testosterone and soluble ST2 as mortality predictive biomarkers in male patients with sepsis-induced cardiomyopathy.docx

Sepsis-induced cardiomyopathy (SIC) is characterized by high mortality and poor outcomes. This study aimed to explore the relationship between testosterone and soluble ST2 (sST2) and all-cause mortality in patients with SIC. Clinical data from SIC patients at Renmin Hospital of Wuhan University from January 2021 and March 2023 were reviewed. Serum testosterone and sST2 were measured at admission. Kaplan–Meier analysis and receiver operative characteristic curve (ROC) were used to estimate the predictive values of testosterone and sST2 on 28 days and 90 days mortality of SIC. A total of 327 male subjects with SIC were enrolled in this study. During the 28 days and 90 days follow-up, 87 (26.6%) and 103 deaths (31.5%) occurred, respectively. Kaplan–Meier analysis showed significantly higher 28 days and 90 days survival in patients with higher testosterone and decreased sST2 levels (p < 0.001). Testosterone, sST2, and N-terminal pro-B-type natriuretic peptide (NT-proBNP) were significantly associated with 28 days and 90 days mortality (p < 0.05). Partial correlation analysis showed strong positive correlation between testosterone and left ventricular ejection fraction (LVEF) (p < 0.001), and negative correlation between testosterone and sST2 (p < 0.001), high-sensitivity troponin I (hs-TnI) levels (p < 0.001) and smoke history (p < 0.01). The concentrations of sST2 were positively related with E/e′ ratio (p < 0.001), and negatively correlated with TAPSE (p < 0.001). The combination of testosterone and sST2 enhanced the prediction of both 28 days [area under the ROC curve (AUC), 0.805] and 90 days mortality (AUC, 0.833). Early serum testosterone and sST2 levels could predict mortality of SIC independently and jointly. Further research is needed to determine the utility of biochemical markers in identifying high-risk patients with SIC.</p