Earthquake recurrence as a record breaking process

Extending the central concept of recurrence times for a point process to recurrent events in space-time allows us to characterize seismicity as a record breaking process using only spatiotemporal relations among events. Linking record breaking events with edges between nodes in a graph generates a complex dynamical network isolated from any length, time or magnitude scales set by the observer. For Southern California, the network of recurrences reveals new statistical features of seismicity with robust scaling laws. The rupture length and its scaling with magnitude emerges as a generic measure for distance between recurrent events. Further, the relative separations for subsequent records in space (or time) form a hierarchy with unexpected scaling properties

VOx/Fe2O3 Shell-Core Catalysts for the selective oxidation of methanol to formaldehyde

Efficient oxidation catalysts are important in many current industrial processes, including the selective oxidation of methanol to formaldehyde. Vanadium-containing catalysts have been shown to be effective selective oxidation catalysts for certain reactions, and research continues to examine their applicability to other reactions of interest. Several VOx/Fe2O3 shell–core catalysts with varying VOx coverage have been produced to investigate the stability of VOx monolayers and their selectivity for methanol oxidation. Catalyst formation proceeds via a clear progression of distinct surface species produced during catalyst calcination. At 300 °C the selective VOx overlayer has formed; by 500 °C a sandwich layer of FeVO4 arises between the VOx shell and the Fe2O3 core, inhibiting iron cation participation in the catalysis and enhancing catalyst selectivity. The resulting catalysts, comprising a shell–subshell–core system of VOx/FeVO4/Fe2O3, possess good catalytic activity and selectivity to formaldehyde

SN~1991T: Reflections of Past Glory

We have obtained photometry and spectra of SN~1991T which extend more than 1000 days past maximum light, by far the longest a SN~Ia has been followed. Although SN~1991T exhibited nearly normal photometric behavior in the first 400 days following maximum, by 600 days its decline had slowed, and by 950~days the supernova brightness was consistent with a constant apparent magnitude of $m_B=21.30$. Spectra near maximum showed minor variations on the SN~Ia theme which grew less conspicuous during the exponential decline. At 270 days the nebular spectrum was composed of Fe and Co lines common to SNe~Ia. However, by 750 days past maximum light, these lines had shifted in wavelength, and were superimposed on a strong blue continuum. The luminosity of SN~1991T at 950 days is more than $9.0\times10^{38}(D/13~{\rm Mpc})^2$~ergs~s$^{-1}$ with a rate of decline of less than $0.04$ mags/100~days. We show that this emission is likely to be light that was emitted by SN~1991T near maximum light which has reflected from foreground dust, much like the light echos observed around SN~1987A.Comment: 15 pages (includes figures and tables) uuencoded compressed postscript, CfA Preprint - To Appear in ApJ

Protein flexibility is key to cisplatin crosslinking in calmodulin

Chemical crosslinking in combination with Fourier transform ion cyclotron resonance mass spectrometry (FTICR MS) has significant potential for studying protein structures and proteinprotein interactions. Previously, cisplatin has been shown to be a crosslinker and crosslinks multiple methionine (Met) residues in apo-calmodulin (apo-CaM). However, the inter-residue distances obtained from nuclear magnetic resonance structures are inconsistent with the measured distance constraints by crosslinking. Met residues lie too far apart to be crosslinked by cisplatin. Here, by combining FTICR MS with a novel computational flexibility analysis, the flexible nature of the CaM structure is found to be key to cisplatin crosslinking in CaM. It is found that the side chains of Met residues can be brought together by flexible motions in both apo-CaM and calcium-bound CaM (Ca4-CaM). The possibility of cisplatin crosslinking Ca4-CaM is then confirmed by MS data. Therefore, flexibility analysis as a fast and low-cost computational method can be a useful tool for predicting crosslinking pairs in protein crosslinking analysis and facilitating MS data analysis. Finally, flexibility analysis also indicates that the crosslinking of platinum to pairs of Met residues will effectively close the nonpolar groove and thus will likely interfere with the binding of CaM to its protein targets, as was proved by comparing assays for cisplatin-modified/unmodified CaM binding to melittin. Collectively, these results suggest that cisplatin crosslinking of apo-CaM or Ca4-CaM can inhibit the ability of CaM to recognize its target proteins, which may have important implications for understanding the mechanism of tumor resistance to platinum anticancer drugs

Producing the electric car

The purpose of this chapter is to highlight the key differences in the production processes of battery electric vehicles (BEV) and internal combustion engine vehicles (ICEV). This exploration not only includes the fundamental physical architectural differences between the types of vehicles but also their entirely different supporting supply chains and underpinning business logics. Many nuanced and less-discussed considerations such as geopolitics, supporting infrastructure, and background policy implications are also covered. This chapter stems from the collection and analysis of secondary peer-reviewed data that is supplemented by verified press publications. The automotive industry moves at an incredibly fast pace, and thus understanding the sociotechnical transition to BEVs requires the additional, timely context of press publications. The overall result of this chapter is a holistic overview of the BEV’s value chain, and more importantly some much needed context for readers to better appreciate the significant implications that are involved. Society is not merely substituting one ‘full fat’ product for a ‘low calorie’ version, but rather we are adopting a new technology that solves some of our problems but comes with challenges of its own. In the coming transition to BEVs, it will be impossible to switch technologies without reformulating various policies and reconsidering how we consume transportation as a commodity or a service. By presenting how society intends to evolve its predominant road propulsion system, this chapter seeks to explain the twists and turns ahead, and offer a glimpse of a more sustainable path forward

Structural behaviour of copper chloride catalysts during the chlorination of CO to phosgene

The interaction of CO with an attapulgite-supported Cu(II)Cl2 catalyst has been examined in a micro-reactor arrangement. CO exposure to the dried, as-received catalyst at elevated temperatures leads to the formation of CO2 as the only identifiable product. However, phosgene production can be induced by a catalyst pre-treatment where the supported Cu(II)Cl2 sample is exposed to a diluted stream of chlorine. Subsequent CO exposure at ~ 370°C then leads to phosgene production. In order to investigate the origins of this atypical set of reaction characteristics, a series of x-ray absorption experiments were performed that were supplemented by DFT calculations. XANES measurements establish that at the elevated temperatures connected with phosgene formation, the catalyst is comprised of Cu+ and a small amount of Cu2+. Moreover, the data show that unique to the chlorine pre-treated sample, CO exposure at elevated temperature results in a short-lived oxidation of the copper. On the basis of calculated CO adsorption energies, DFT calculations indicate that a mixed Cu+/Cu2+ catalyst is required to support CO chemisorption

Networks of Recurrent Events, a Theory of Records, and an Application to Finding Causal Signatures in Seismicity

We propose a method to search for signs of causal structure in spatiotemporal data making minimal a priori assumptions about the underlying dynamics. To this end, we generalize the elementary concept of recurrence for a point process in time to recurrent events in space and time. An event is defined to be a recurrence of any previous event if it is closer to it in space than all the intervening events. As such, each sequence of recurrences for a given event is a record breaking process. This definition provides a strictly data driven technique to search for structure. Defining events to be nodes, and linking each event to its recurrences, generates a network of recurrent events. Significant deviations in properties of that network compared to networks arising from random processes allows one to infer attributes of the causal dynamics that generate observable correlations in the patterns. We derive analytically a number of properties for the network of recurrent events composed by a random process. We extend the theory of records to treat not only the variable where records happen, but also time as continuous. In this way, we construct a fully symmetric theory of records leading to a number of new results. Those analytic results are compared to the properties of a network synthesized from earthquakes in Southern California. Significant disparities from the ensemble of acausal networks that can be plausibly attributed to the causal structure of seismicity are: (1) Invariance of network statistics with the time span of the events considered, (2) Appearance of a fundamental length scale for recurrences, independent of the time span of the catalog, which is consistent with observations of the ``rupture length'', (3) Hierarchy in the distances and times of subsequent recurrences.Comment: 19 pages, 13 figure

Selectivity determinants for dual function catalysts: applied to methanol selective oxidation on iron molybdate

Evolution of the IRAS spectrum with temperature after adsorbing methanol at room temperature. The bands at 2930 and 2820 cm− 1 are due to the methoxy species C–H stretches, while that at 2870 is due to the formate. Here, we report a simple, quantitative model to describe the behaviour of bi-cationic oxide catalysts, in terms of selectivity variation as a function of increased loading of one cation into a sample of the other. We consider its application to a particular catalytic system, namely the selective oxidation of methanol, which proceeds with three main C1 products, namely CO2, CO, and H2CO. The product selectivity varies in this order as Mo is added in increasing amounts to an iron oxide catalyst, and the product selectivity is determined by the distribution of dual sites and single sites of each species

Identification of single-site gold catalysis in acetylene hydrochlorination

There remains considerable debate over the active form of gold under operating conditions of a recently validated gold catalyst for acetylene hydrochlorination. We have performed an in situ x-ray absorption fine structure study of gold/carbon (Au/C) catalysts under acetylene hydrochlorination reaction conditions and show that highly active catalysts comprise single-site cationic Au entities whose activity correlates with the ratio of Au(I):Au(III) present. We demonstrate that these Au/C catalysts are supported analogs of single-site homogeneous Au catalysts and propose a mechanism, supported by computational modeling, based on a redox couple of Au(I)-Au(III) species. View Full Tex