Distribution, age, and growth of young-of-the year greater amberjack (Seriola dumerili) associated with pelagic Sargassum

Patterns of distribution and growth were examined for young-of-the-year (YOY) greater amberjack (Seriola dumerili) associated with pelagic Sargassum in the NW Gulf of Mexico. Seriola dumerili were collected off Galveston, Texas, from May to July over a two-year period (2000 and 2001) in both inshore (<15 nautical miles [nmi]) and offshore zones (15−70 nmi). Relative abundance of YOY S. dumerili (32−210 mm standard length) from purse-seine collections peaked in May and June, and abundance was highest in the offshore zone. Ages of S. dumerili ranged from 39 to 150 days and hatching-date analysis indicated that the majority of spawning events occurred from February to April. Average daily growth rates of YOY S. dumerili for 2000 and 2001 were 1.65 mm/d and 2.00 mm/d, respectively. Intra-annual differences in growth were observed; the late-season (April) cohort experienced the fastest growth in both years. In addition, growth was significantly higher for S. dumerili collected from the offshore zone. Mortality was approximated by using catch-curve analysis, and the predicted instantaneous mortality rate (Z) of YOY S. dumerili was 0.0045 (0.45%/d)

Diet of the Blacktip Shark (Carcharhinus limbatus) in the Northwestern Gulf of Mexico

The stomach contents of 90 Blacktip Shark (Carcharhinus limbatus) specimens caught in the northwestern Gulf of Mexico (GOM) were examined. Stomach contents were identified to the lowest possible taxon, and quantified using percent weight, percent number, percent frequency of occurrence, and percent index of relative importance (IRI). Teleosts were the dominant prey group (98.95% IRI), although most were unidentified (61.70% IRI). Of identified teleost species, Atlantic Croaker (Micropogonias undulatus) (28.43% IRI), and Gulf Menhaden (Brevoortia patronus) (2.31% IRI) were the most important. Crustaceans (0.65% IRI), mollusks (0.46% IRI), and elasmobranchs (0.03% IRI) formed a minor component of the diet. Suspected shrimp fishery discards were found in 11% of stomachs, highlighting the potential importance of this food source for the Blacktip Shark. Diet composition did not differ between male and female sharks, but did between juveniles and adults. Juvenile shark diets had greater proportions of unidentified teleost, Clupeidae and Penaeidae, while adult diets had greater proportions of Sciaenidae, Ariidae and cephalopods. Our results were similar, although not identical to, other studies of Blacktip Shark diets in the northwestern GOM. Of note is finding of the mantis shrimp Squilla empusa, a species previously unreported in Blacktip Shark stomach contents. This new finding, the high importance of unidentified teleosts, and the lack of asymptote in the prey accumulation curve emphasize the need for further study of the Blacktip Shark diet in the northwestern GOM

Structural behaviour of copper chloride catalysts during the chlorination of CO to phosgene

The interaction of CO with an attapulgite-supported Cu(II)Cl2 catalyst has been examined in a micro-reactor arrangement. CO exposure to the dried, as-received catalyst at elevated temperatures leads to the formation of CO2 as the only identifiable product. However, phosgene production can be induced by a catalyst pre-treatment where the supported Cu(II)Cl2 sample is exposed to a diluted stream of chlorine. Subsequent CO exposure at ~ 370°C then leads to phosgene production. In order to investigate the origins of this atypical set of reaction characteristics, a series of x-ray absorption experiments were performed that were supplemented by DFT calculations. XANES measurements establish that at the elevated temperatures connected with phosgene formation, the catalyst is comprised of Cu+ and a small amount of Cu2+. Moreover, the data show that unique to the chlorine pre-treated sample, CO exposure at elevated temperature results in a short-lived oxidation of the copper. On the basis of calculated CO adsorption energies, DFT calculations indicate that a mixed Cu+/Cu2+ catalyst is required to support CO chemisorption

Cosmic Strings from Supersymmetric Flat Directions

Flat directions are a generic feature of the scalar potential in supersymmetric gauge field theories. They can arise, for example, from D-terms associated with an extra abelian gauge symmetry. Even when supersymmetry is broken softly, there often remain directions in the scalar field space along which the potential is almost flat. Upon breaking a gauge symmetry along one of these almost flat directions, cosmic strings may form. Relative to the standard cosmic string picture based on the abelian Higgs model, these flat-direction cosmic strings have the extreme Type-I properties of a thin gauge core surrounded by a much wider scalar field profile. We perform a comprehensive study of the microscopic, macroscopic, and observational characteristics of this class of strings. We find many differences from the standard string scenario, including stable higher winding mode strings, the dynamical formation of higher mode strings from lower ones, and a resultant multi-tension scaling string network in the early universe. These strings are only moderately constrained by current observations, and their gravitational wave signatures may be detectable at future gravity wave detectors. Furthermore, there is the interesting but speculative prospect that the decays of cosmic string loops in the early universe could be a source of ultra-high energy cosmic rays or non-thermal dark matter. We also compare the observational signatures of flat-direction cosmic strings with those of ordinary cosmic strings as well as (p,q) cosmic strings motivated by superstring theory.Comment: 58 pages, 16 figures, v2. accepted to PRD, added comments about baryogenesis and boosted decay products from cusp annihilatio