1,713 research outputs found

    Multivariate analysis of volatile emission from wild tobacco Nicotiana attenuata using GCxGC-ToFMS

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    Generation of mechanical interference fringes by multi-photon counting

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    Exploring the quantum behaviour of macroscopic objects provides an intriguing avenue to study the foundations of physics and to develop a suite of quantum-enhanced technologies. One prominent path of study is provided by quantum optomechanics which utilizes the tools of quantum optics to control the motion of macroscopic mechanical resonators. Despite excellent recent progress, the preparation of mechanical quantum superposition states remains outstanding due to weak coupling and thermal decoherence. Here we present a novel optomechanical scheme that significantly relaxes these requirements allowing the preparation of quantum superposition states of motion of a mechanical resonator by exploiting the nonlinearity of multi-photon quantum measurements. Our method is capable of generating non-classical mechanical states without the need for strong single photon coupling, is resilient against optical loss, and offers more favourable scaling against initial mechanical thermal occupation than existing schemes. Moreover, our approach allows the generation of larger superposition states by projecting the optical field onto NOON states. We experimentally demonstrate this multi-photon-counting technique on a mechanical thermal state in the classical limit and observe interference fringes in the mechanical position distribution that show phase superresolution. This opens a feasible route to explore and exploit quantum phenomena at a macroscopic scale.Comment: 16 pages, 4 figures. v1: submitted for review on 28 Jan 2016. v2: significantly revised manuscript. v3: some further revisions and some extra results included. v3: new results added, extra author added, close to published version, supplementary material available with published versio

    Information measures based on Tsallis' entropy and geometric considerations for thermodynamic systems

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    An analysis of the thermodynamic behavior of quantum systems can be performed from a geometrical perspective investigating the structure of the state space. We have developed such an analysis for nonextensive thermostatistical frameworks, making use of the q-divergence derived from Tsallis' entropy. Generalized expressions for operator variance and covariance are considered, in terms of which the fundamental tensor is given.Comment: contribution to 3rd NEXT-SigmaPhi International Conference (August 2005, Kolymbari, Greece

    Engineering yeast alcohol dehydrogenase. Replacing Trp54 by Leu broadens substrate specificity

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    Analysis of a crystal structure of alcohol dehydrogenase (Adh) from horse liver suggests that Trp54 in the homologous yeast alcohol dehydrogenase prevents the yeast enzyme from efficiently catalysing the oxidation of long-chain primary alcohols with branching at the 4 position (e.g. 4-methyl-1-pentanol, cinnamyl alcohol). This residue has been altered to Leu by site-directed mutagenesis. The alteration yields an enzyme that serves as an effective catalyst for both longer straight-chain primary alcohols and branched chain alcohol

    Molecular interactions between the specialist herbivore Manduca sexta (Lepidoptera, Sphigidae) and its natural host Nicotiana attenuata. VIII. An unbiased GCxGC-ToFMS analysis of the plant´s elicited volatile emissions

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    Treating wounds in Nicotiana attenuata leaves with Manduca sexta oral secretions (W+OS) mimics most changes elicited by M. sexta herbivory, but an unbiased analysis of the effect of the different OS constituents on volatile emissions is lacking. We used two-dimensional gas chromatography/time-of-flight (GCxGC-ToF) mass spectrometry combined with multivariate statistics to parse volatiles into regulatory patterns. Volatiles released by wounding alone and by the alkalinity of OS were assessed by applying a buffer known to mimic the pH-mediated changes of OS elicitation (pectin methyl esterase activation and methanol release). The activities of fatty acid amino acid conjugates, well-known elicitors of antiherbivore defenses, and of 2-hydroxyoctadecatrienoic acid, a newly discovered signal in OS, were determined. Approximately 400 analytes were detected after deconvolution and alignment of GCxGC data; 35 volatiles were significantly regulated upon W+OS. Two-thirds of these were specifically regulated by OS, being either amplified (most terpenoids and certain hexenylesters) or strongly repressed (many short-chain alcohols and some aromatic and hexenylester derivatives). Fatty acid amino acid conjugates played a central role in this pattern of regulation, since they induced the emission of half of OS-elicited volatiles and inhibited the production of almost all OS-repressed volatiles; 2-hydroxyoctadecatrienoic acid influenced emission of trans-α-bergamotene, while other unknown OS constituents amplified hexenylester production. We conclude that the complex bouquet of herbivory-elicited volatiles results from the complex modulations of the wound response by diverse cues found in OS. This work also underscores the value of ultra-high-resolution GCxGC-ToF analysis combined with the nontargeted mining of the resulting data

    Manipulating biphotonic qutrits

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    Quantum information carriers with higher dimension than the canonical qubit offer significant advantages. However, manipulating such systems is extremely difficult. We show how measurement induced non-linearities can be employed to dramatically extend the range of possible transforms on biphotonic qutrits; the three level quantum systems formed by the polarisation of two photons in the same spatio-temporal mode. We fully characterise the biphoton-photon entanglement that underpins our technique, thereby realising the first instance of qubit-qutrit entanglement. We discuss an extension of our technique to generate qutrit-qutrit entanglement and to manipulate any bosonic encoding of quantum information.Comment: 4 pages, 4 figure

    Experimental demonstration of Shor's algorithm with quantum entanglement

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    Shor's powerful quantum algorithm for factoring represents a major challenge in quantum computation and its full realization will have a large impact on modern cryptography. Here we implement a compiled version of Shor's algorithm in a photonic system using single photons and employing the non-linearity induced by measurement. For the first time we demonstrate the core processes, coherent control, and resultant entangled states that are required in a full-scale implementation of Shor's algorithm. Demonstration of these processes is a necessary step on the path towards a full implementation of Shor's algorithm and scalable quantum computing. Our results highlight that the performance of a quantum algorithm is not the same as performance of the underlying quantum circuit, and stress the importance of developing techniques for characterising quantum algorithms.Comment: 4 pages, 5 figures + half-page additional online materia

    Demonstration of a simple entangling optical gate and its use in Bell-state analysis

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    We demonstrate a new architecture for an optical entangling gate that is significantly simpler than previous realisations, using partially-polarising beamsplitters so that only a single optical mode-matching condition is required. We demonstrate operation of a controlled-Z gate in both continuous-wave and pulsed regimes of operation, fully characterising it in each case using quantum process tomography. We also demonstrate a fully-resolving, nondeterministic optical Bell-state analyser based on this controlled-Z gate. This new architecture is ideally suited to guided optics implementations of optical gates.Comment: 4 pages, 3 figures. v2: additional author, improved data and figures (low res), some other minor changes. Accepted for publication in PR

    Phospholipid metabolism in the developing liver : I. The biosynthesis of choline glycerophosphatides by liver slices from fetal, newborn and adult rats

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    1. 1. The biosynthesis of choline glycerophosphatides was evaluated in fetal, neonatal and adult female rat liver. The two main pathways were assessed by studying the rates of incorporation of [Me-14C]choline and [Me-14C]methionine by liver slices.2. 2. Over 96% of the lipid radioactivity from [Me-14C] choline was located in choline glycerophosphatides. In adult liver slices 93% of the total lipid radioactivity from [Me-14C]methionine was located in choline glycerophosphatides. An appreciable amount of radioactivity from [Me-14C]methionine was incorporated into fatty acids by fetal liver slices.3. 3. Liver slices from fetal rats incorporated the same amount of [Me-14C]choline into lecithin as did adult liver slices except for a drop 2 days before birth. Liver slices from 3-day-old neonatal rats incorporated about twice as much [Me-14C]choline as the adult liver slices.4. 4. Liver slices from fetal and young rats incorporated about 8-10 times more [Me-14C]choline into phosphoryl choline than did liver slices from adults. Adult levels were reached at 10 days after birth.5. 5. The incorporation of radioactivity from [Me-14C]methionine into lecithin by fetal liver slices was much lower than that by adult liver slices and increased to twice adult levels by 10-12 days after birth. Adult levels were reached by 25 days after birth.6. 6. Studies with [1,2-14C2, Me-14H]choline indicated that the choline was incorporated intact and that little, if any, of the methyl groups of choline were used for the methylation of phosphatidyl ethanolamine.7. 7. The mechanism of choline incorporation into lecithin is discussed.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/32929/1/0000311.pd

    On The Phase Structure and Thermodynamic Geometry of R-Charged Black Holes

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    We study the phase structure and equilibrium state space geometry of R-charged black holes in D=5D = 5, 4 and 7 and the corresponding rotating D3D3, M2M2 and M5M5 branes. For various charge configurations of the compact black holes in the canonical ensemble we demonstrate new liquid-gas like phase coexistence behaviour culminating in second order critical points. The critical exponents turn out to be the same as that of four dimensional asymptotically AdS black holes in Einstein Maxwell theory. We further establish that the regions of stability for R-charged black holes are, in some cases, more constrained than is currently believed, due to properties of some of the response coefficients. The equilibrium state space scalar curvature is calculated for various charge configurations, both for the case of compact as well as flat horizons and its asymptotic behaviour with temperature is established.Comment: 1 + 33 pages, LaTeX, 25 figures. References adde
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