1,713 research outputs found
Multivariate analysis of volatile emission from wild tobacco Nicotiana attenuata using GCxGC-ToFMS
Generation of mechanical interference fringes by multi-photon counting
Exploring the quantum behaviour of macroscopic objects provides an intriguing
avenue to study the foundations of physics and to develop a suite of
quantum-enhanced technologies. One prominent path of study is provided by
quantum optomechanics which utilizes the tools of quantum optics to control the
motion of macroscopic mechanical resonators. Despite excellent recent progress,
the preparation of mechanical quantum superposition states remains outstanding
due to weak coupling and thermal decoherence. Here we present a novel
optomechanical scheme that significantly relaxes these requirements allowing
the preparation of quantum superposition states of motion of a mechanical
resonator by exploiting the nonlinearity of multi-photon quantum measurements.
Our method is capable of generating non-classical mechanical states without the
need for strong single photon coupling, is resilient against optical loss, and
offers more favourable scaling against initial mechanical thermal occupation
than existing schemes. Moreover, our approach allows the generation of larger
superposition states by projecting the optical field onto NOON states. We
experimentally demonstrate this multi-photon-counting technique on a mechanical
thermal state in the classical limit and observe interference fringes in the
mechanical position distribution that show phase superresolution. This opens a
feasible route to explore and exploit quantum phenomena at a macroscopic scale.Comment: 16 pages, 4 figures. v1: submitted for review on 28 Jan 2016. v2:
significantly revised manuscript. v3: some further revisions and some extra
results included. v3: new results added, extra author added, close to
published version, supplementary material available with published versio
Information measures based on Tsallis' entropy and geometric considerations for thermodynamic systems
An analysis of the thermodynamic behavior of quantum systems can be performed
from a geometrical perspective investigating the structure of the state space.
We have developed such an analysis for nonextensive thermostatistical
frameworks, making use of the q-divergence derived from Tsallis' entropy.
Generalized expressions for operator variance and covariance are considered, in
terms of which the fundamental tensor is given.Comment: contribution to 3rd NEXT-SigmaPhi International Conference (August
2005, Kolymbari, Greece
Engineering yeast alcohol dehydrogenase. Replacing Trp54 by Leu broadens substrate specificity
Analysis of a crystal structure of alcohol dehydrogenase (Adh) from horse liver suggests that Trp54 in the homologous yeast alcohol dehydrogenase prevents the yeast enzyme from efficiently catalysing the oxidation of long-chain primary alcohols with branching at the 4 position (e.g. 4-methyl-1-pentanol, cinnamyl alcohol). This residue has been altered to Leu by site-directed mutagenesis. The alteration yields an enzyme that serves as an effective catalyst for both longer straight-chain primary alcohols and branched chain alcohol
Molecular interactions between the specialist herbivore Manduca sexta (Lepidoptera, Sphigidae) and its natural host Nicotiana attenuata. VIII. An unbiased GCxGC-ToFMS analysis of the plant´s elicited volatile emissions
Treating wounds in Nicotiana attenuata leaves with Manduca sexta oral secretions (W+OS) mimics most changes elicited by M. sexta herbivory, but an unbiased analysis of the effect of the different OS constituents on volatile emissions is lacking. We used two-dimensional gas chromatography/time-of-flight (GCxGC-ToF) mass spectrometry combined with multivariate statistics to parse volatiles into regulatory patterns. Volatiles released by wounding alone and by the alkalinity of OS were assessed by applying a buffer known to mimic the pH-mediated changes of OS elicitation (pectin methyl esterase activation and methanol release). The activities of fatty acid amino acid conjugates, well-known elicitors of antiherbivore defenses, and of 2-hydroxyoctadecatrienoic acid, a newly discovered signal in OS, were determined. Approximately 400 analytes were detected after deconvolution and alignment of GCxGC data; 35 volatiles were significantly regulated upon W+OS. Two-thirds of these were specifically regulated by OS, being either amplified (most terpenoids and certain hexenylesters) or strongly repressed (many short-chain alcohols and some aromatic and hexenylester derivatives). Fatty acid amino acid conjugates played a central role in this pattern of regulation, since they induced the emission of half of OS-elicited volatiles and inhibited the production of almost all OS-repressed volatiles; 2-hydroxyoctadecatrienoic acid influenced emission of trans-α-bergamotene, while other unknown OS constituents amplified hexenylester production. We conclude that the complex bouquet of herbivory-elicited volatiles results from the complex modulations of the wound response by diverse cues found in OS. This work also underscores the value of ultra-high-resolution GCxGC-ToF analysis combined with the nontargeted mining of the resulting data
Manipulating biphotonic qutrits
Quantum information carriers with higher dimension than the canonical qubit
offer significant advantages. However, manipulating such systems is extremely
difficult. We show how measurement induced non-linearities can be employed to
dramatically extend the range of possible transforms on biphotonic qutrits; the
three level quantum systems formed by the polarisation of two photons in the
same spatio-temporal mode. We fully characterise the biphoton-photon
entanglement that underpins our technique, thereby realising the first instance
of qubit-qutrit entanglement. We discuss an extension of our technique to
generate qutrit-qutrit entanglement and to manipulate any bosonic encoding of
quantum information.Comment: 4 pages, 4 figure
Experimental demonstration of Shor's algorithm with quantum entanglement
Shor's powerful quantum algorithm for factoring represents a major challenge
in quantum computation and its full realization will have a large impact on
modern cryptography. Here we implement a compiled version of Shor's algorithm
in a photonic system using single photons and employing the non-linearity
induced by measurement. For the first time we demonstrate the core processes,
coherent control, and resultant entangled states that are required in a
full-scale implementation of Shor's algorithm. Demonstration of these processes
is a necessary step on the path towards a full implementation of Shor's
algorithm and scalable quantum computing. Our results highlight that the
performance of a quantum algorithm is not the same as performance of the
underlying quantum circuit, and stress the importance of developing techniques
for characterising quantum algorithms.Comment: 4 pages, 5 figures + half-page additional online materia
Demonstration of a simple entangling optical gate and its use in Bell-state analysis
We demonstrate a new architecture for an optical entangling gate that is
significantly simpler than previous realisations, using partially-polarising
beamsplitters so that only a single optical mode-matching condition is
required. We demonstrate operation of a controlled-Z gate in both
continuous-wave and pulsed regimes of operation, fully characterising it in
each case using quantum process tomography. We also demonstrate a
fully-resolving, nondeterministic optical Bell-state analyser based on this
controlled-Z gate. This new architecture is ideally suited to guided optics
implementations of optical gates.Comment: 4 pages, 3 figures. v2: additional author, improved data and figures
(low res), some other minor changes. Accepted for publication in PR
Phospholipid metabolism in the developing liver : I. The biosynthesis of choline glycerophosphatides by liver slices from fetal, newborn and adult rats
1. 1. The biosynthesis of choline glycerophosphatides was evaluated in fetal, neonatal and adult female rat liver. The two main pathways were assessed by studying the rates of incorporation of [Me-14C]choline and [Me-14C]methionine by liver slices.2. 2. Over 96% of the lipid radioactivity from [Me-14C] choline was located in choline glycerophosphatides. In adult liver slices 93% of the total lipid radioactivity from [Me-14C]methionine was located in choline glycerophosphatides. An appreciable amount of radioactivity from [Me-14C]methionine was incorporated into fatty acids by fetal liver slices.3. 3. Liver slices from fetal rats incorporated the same amount of [Me-14C]choline into lecithin as did adult liver slices except for a drop 2 days before birth. Liver slices from 3-day-old neonatal rats incorporated about twice as much [Me-14C]choline as the adult liver slices.4. 4. Liver slices from fetal and young rats incorporated about 8-10 times more [Me-14C]choline into phosphoryl choline than did liver slices from adults. Adult levels were reached at 10 days after birth.5. 5. The incorporation of radioactivity from [Me-14C]methionine into lecithin by fetal liver slices was much lower than that by adult liver slices and increased to twice adult levels by 10-12 days after birth. Adult levels were reached by 25 days after birth.6. 6. Studies with [1,2-14C2, Me-14H]choline indicated that the choline was incorporated intact and that little, if any, of the methyl groups of choline were used for the methylation of phosphatidyl ethanolamine.7. 7. The mechanism of choline incorporation into lecithin is discussed.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/32929/1/0000311.pd
On The Phase Structure and Thermodynamic Geometry of R-Charged Black Holes
We study the phase structure and equilibrium state space geometry of
R-charged black holes in , 4 and 7 and the corresponding rotating ,
and branes. For various charge configurations of the compact black
holes in the canonical ensemble we demonstrate new liquid-gas like phase
coexistence behaviour culminating in second order critical points. The critical
exponents turn out to be the same as that of four dimensional asymptotically
AdS black holes in Einstein Maxwell theory. We further establish that the
regions of stability for R-charged black holes are, in some cases, more
constrained than is currently believed, due to properties of some of the
response coefficients. The equilibrium state space scalar curvature is
calculated for various charge configurations, both for the case of compact as
well as flat horizons and its asymptotic behaviour with temperature is
established.Comment: 1 + 33 pages, LaTeX, 25 figures. References adde
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