Space VLBI Observations of 3C 279 at 1.6 and 5 GHz

We present the first VLBI Space Observatory Programme (VSOP) observations of the gamma-ray blazar 3C 279 at 1.6 and 5 GHz. The combination of the VSOP and VLBA-only images at these two frequencies maps the jet structure on scales from 1 to 100 mas. On small angular scales the structure is dominated by the quasar core and the bright secondary component `C4' located 3 milliarcseconds from the core (at this epoch). On larger angular scales the structure is dominated by a jet extending to the southwest, which at the largest scale seen in these images connects with the smallest scale structure seen in VLA images. We have exploited two of the main strengths of VSOP: the ability to obtain matched-resolution images to ground-based images at higher frequencies and the ability to measure high brightness temperatures. A spectral index map was made by combining the VSOP 1.6 GHz image with a matched-resolution VLBA-only image at 5 GHz from our VSOP observation on the following day. The spectral index map shows the core to have a highly inverted spectrum, with some areas having a spectral index approaching the limiting value for synchrotron self-absorbed radiation of 2.5. Gaussian model fits to the VSOP visibilities revealed high brightness temperatures (>10^{12} K) that are difficult to measure with ground-only arrays. An extensive error analysis was performed on the brightness temperature measurements. Most components did not have measurable brightness temperature upper limits, but lower limits were measured as high as 5x10^{12} K. This lower limit is significantly above both the nominal inverse Compton and equipartition brightness temperature limits. The derived Doppler factor, Lorentz factor, and angle to the line-of-sight in the case of the equipartition limit are at the upper end of the range of expected values for EGRET blazars.Comment: 11 pages, 6 figures, emulateapj.sty, To be published in The Astrophysical Journal, v537, Jul 1, 200

Direct determination of absolute stereochemistry of α-methylselenocysteine using the Mosher method

Mosher amides of α-methylselenocysteine were synthesized to determine the absolute stereochemistry of the sterically hindered α-carbon utilizing 1H, 13C, 19F, and 77Se NMR spectroscopies. After analysis of these spectra using the established Mosher method, the stereochemistry of the α-carbon was determined to be (R), which was subsequently confirmed using x-ray crystallography

Variability in the X-ray Flux of Quasar 3C345: Inverse-Compton Emission from the Parsec-Scale Jet?

We present the results of the first systematic study of variability in the X-ray emission from the 'superluminal' quasar 3C 345. Its power-law 1-keV X-ray emission varies by a factor of two on a timescale of years, but with no change in spectral index, closely following the high-frequency radio flux. Using VLBI images, we show that one of the superluminal 'knots' in the jet (at a distance of ≈ 15 pc from the nucleus), rather than the nucleus, produces most of the observed X-rays, via the synchrotron self-Compton process. We show that this knot accelerates as it moves away from the nucleus, along along a path at ≈ 10° from the line of sight

Reputation Systems for Supply Chains: The Challenge of Achieving Privacy Preservation

Consumers frequently interact with reputation systems to rate products, services, and deliveries. While past research extensively studied different conceptual approaches to realize such systems securely and privacy-preservingly, these concepts are not yet in use in business-to-business environments. In this paper, (1) we thus outline which specific challenges privacy-cautious stakeholders in volatile supply chain networks introduce, (2) give an overview of the diverse landscape of privacy-preserving reputation systems and their properties, and (3) based on well-established concepts from supply chain information systems and cryptography, we further propose an initial concept that accounts for the aforementioned challenges by utilizing fully homomorphic encryption. For future work, we identify the need of evaluating whether novel systems address the supply chain-specific privacy and confidentiality needs

Estudio del proceso de cambio conceptual y la construcción del modelo científico precursor de ser vivo en niños de pre-escolar

La presente investigación estudia el cambio conceptual y la construcción de modelos científicos precursores en un contexto socioconstructivista con niños pequeños, utilizando una metodología cualitativa. Se analizan los cambios epistemológicos y ontológicos en las concepciones de los niños acerca de los seres vivos y cómo una estrategia didáctica basada en la construcción de un modelo científico precursor basado en propiedades biológicas los promueven. Los cambios en la comprensión de los niños fueron significativos en las dimensiones ontológicas y epistemológicas, presentando diferentes patones. Los segundos proporcionaron una mejor coherencia explicativa en su sistema conceptual contribuyendo, de esta forma, a los cambios ontológicos y promoviendo, a su vez, la construcción del modelo científico precursor de ser vivo

Quasar Astrophysics with the Space Interferometry Mission

recision optical astrometry of quasars and active galaxies can provide important insight into the spatial distribution and variability of emission in compact nuclei. SIM - the Space Interferometry Mission - will be the first optical interferometer capable of precision astrometry on quasars. Although it is not expected to resolve the emission, it will be very sensitive to astrometric shifts, for objects as faint as R magnitude 20. In its wide-angle mode, SIM will yield 4 microarcsecond absolute positions, and proper motions to about 2 microarcsecond/yr. A variety of AGN phenomena are expected to be visible to SIM on these scales, including time and spectral dependence in position offsets between accretion disk and jet emission. SIM should be able to answer the following questions. Does the most compact optical emission from an AGN come from an accretion disk or from a relativistic jet? Do the relative positions of the radio core and optical photocentre of quasars used for the reference frame tie change on the timescales of their photometric variability? Do the cores of galaxies harbour binary supermassive black holes remaining from galaxy mergers? In this paper we briefly describe the operation of SIM and the quasar measurements it will make. We estimate the size of the astrometric signatures which may be expected, and we discuss prospects for using astrometry as a fundamental tool for understanding quasar nuclei