Carbon-Based Compounds and Exobiology

The Committee for Planetary and Lunar Explorations (COMPLEX) posed questions related to exobiological exploration of Mars and the possibility of a population of carbonaceous materials in cometary nuclei to be addressed by future space missions. The scientific objectives for such missions are translated into a series of measurements and/or observations to be performed by Martian landers. These are: (1) A detailed mineralogical, chemical, and textural assessment of rock diversity at a landing site; (2) Chemical characterization of the materials at a local site; (3) Abundance of Hydrogen at any accessible sites; (4) Identification of specific minerals that would be diagnostic of aqueous processes; (5) Textual examination of lithologies thought to be formed by aqueous activity; (6) Search for minerals that might have been produced as a result of biological processes; (7) Mapping the distribution, in three dimensions, of the oxidant(s) identified on the Martian surface by the Viking mission; (8) Definition of the local chemical environment; (9) Determination of stable-isotopic ratios for the biogenic elements in surface mineral deposits; (10) Quantitative analysis of organic (non-carbonate) carbon; (11) Elemental and isotopic composition of bulk organic material; (12) Search for specific organic compounds that would yield information about synthetic mechanisms, in the case of prebiotic evolution, and about possible bio-markers, in the case of extinct or extant life; (13) and Coring, sampling, and detection of entrained gases and cosmic-ray induced reaction products at the polar ice cap. A discussion of measurements and/or observations required for cometary landers is included as well

Nickel on Mars: Constraints on meteoritic material at the surface

Impact craters and the discovery of meteorites on Mars indicate clearly that there is meteoritic material at the Martian surface. The Alpha Particle X-ray Spectrometers (APXS) on board the Mars Exploration Rovers measure the elemental chemistry of Martian samples, enabling an assessment of the magnitude of the meteoritic contribution. Nickel, an element that is greatly enhanced in meteoritic material relative to samples of the Martian crust, is directly detected by the APXS and is observed to be geochemically mobile at the Martian surface. Correlations between nickel and other measured elements are used to constrain the quantity of meteoritic material present in Martian soil and sedimentary rock samples. Results indicate that analyzed soils samples and certain sedimentary rocks contain an average of 1% to 3% contamination from meteoritic debris

Indication of drier periods on Mars from the chemistry and mineralogy of atmospheric dust

The ubiquitous atmospheric dust on Mars is well mixed by periodic global dust storms, and such dust carries information about the environment in which it once formed and hence about the history of water on Mars. The Mars Exploration Rovers have permanent magnets to collect atmospheric dust for investigation by instruments on the rovers. Here we report results from Mössbauer spectroscopy and X-ray fluorescence of dust particles captured from the martian atmosphere by the magnets. The dust on the magnets contains magnetite and olivine; this indicates a basaltic origin of the dust and shows that magnetite, not maghemite, is the mineral mainly responsible for the magnetic properties of the dust. Furthermore, the dust on the magnets contains some ferric oxides, probably including nanocrystalline phases, so some alteration or oxidation of the basaltic dust seems to have occurred. The presence of olivine indicates that liquid water did not play a dominant role in the processes that formed the atmospheric dust.Additional co-authors: Daniel S Rodionov, Paulo A de Souza, Jr, Steve W Squyres, Tom Wdowiak, Albert Yen Output Type: Lette