The role of d-electron metal ions complexation on the nonlinear-optical parameters of new trans-dichloropalladium(II) complex

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Annoyance Related to Wind Turbine Noise

A questionnaire inquiry on response to wind turbine noise was carried out on 361 subjects living in the vicinity of 8 wind farms. Current mental health status of respondents was assessed using Goldberg General Health Questionnaire GHQ-12. For areas where respondents lived, A-weighted sound pressure levels (SPLs) were calculated as the sum of the contributions from the wind power plants in the specific area. Generally, 33.0% of respondents were annoyed outdoors by wind turbine noise at the calculated A-weighted SPL of 31–50 dB, while indoors the noise was annoying to 21.3% of them. The propor- tion of subjects evaluating the noise produced by operative wind turbines as annoying decreased with increasing the distance from the nearest wind turbine (27.6% at the distance of 400–800 m vs 14.3% at the distance above 800 m, p < 0.016). On the other hand, the higher was the noise level, the greater was the percentage of annoyed respondents (14.0% at SPL up to 40 dB vs 28.1% at SPL of 40–45 dB, p < 0.016). Besides noise and distance categories, subjective factors, such as general attitude to wind turbines, sensitivity to landscape littering and current mental health status, were found to have significant impact on the perceived annoyance. About 50% of variance in annoyance rating might be explained by the aforesaid subjective factors

New architecture of organo electronic chalcones derivatives: Synthesis, crystal structures and optical properties

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Transition metals induce control of enhanced NLO properties of functionalized organometallic complexes under laser modulations

International audienceThe molecular engineering of organometallic complexes has recently attracted renewed interest on account of their potential technological applications for optoelectronics in general and optical data storage. The transition metal which induces control of enhanced nonlinear optical properties of functionalized organometallic complexes versus not only the intensity but also the polarization of the incident laser beam is original and important for all optical switching. This makes organometallic complexes valuable and suitable candidates for nonlinear optical applications. In the present work, we report the synthesis and full characterization of four organometallic complexes consisting of N, N-dibutylamine and azobenzene fragments but differ by auxiliary alkynyl ligands or metal cations. Thus, a ferrocenyl derivative 1 and three ruthenium complexes 2-4 have been prepared. The nonlinear optical properties of the four new azo-based ruthenium and iron organometallic complexes in the solid state, using polymethylmethacrylate as matrix, have been thoroughly studied. This concept is extended to computing the HOMO and LUMO energy levels of the considered complexes, dipole moment, first and second order hyperpolarizabilities using the 6-31 + G(d,p) + LANL2DZ mixed basis set. The second and third nonlinear optical properties of the resulting polymer composites were obtained by measuring SHG and THG response by means of the Maker fringe technique using a laser generating at 1,064 nm with a 30 ps pulse duration. The values of the second and third order NLO susceptibilities of the four organometallic complexes were found to be higher than the common references used. Theoretical calculation shows that the large first and second order hyperpolarizablities are caused by strong intramolecular charge transfer between the transition metal parts and the ligands though a conjugated transmitter. These results indicate that the present organometallic complexes are valuable candidates for optoelectronic and photonic applications