62 research outputs found
Nanoscale Suppression of Magnetization at Atomically Assembled Manganite Interfaces
Using polarized X-rays, we compare the electronic and magnetic properties of
a La(2/3)Sr(1/3)MnO(3)(LSMO)/SrTiO(3)(STO) and a modified
LSMO/LaMnO(3)(LMO)/STO interface. Using the technique of X-ray resonant
magnetic scattering (XRMS), we can probe the interfaces of complicated layered
structures and quantitatively model depth-dependent magnetic profiles as a
function of distance from the interface. Comparisons of the average electronic
and magnetic properties at the interface are made independently using X-ray
absorption spectroscopy (XAS) and X-ray magnetic circular dichroism (XMCD). The
XAS and the XMCD demonstrate that the electronic and magnetic structure of the
LMO layer at the modified interface is qualitatively equivalent to the
underlying LSMO film. From the temperature dependence of the XMCD, it is found
that the near surface magnetization for both interfaces falls off faster than
the bulk. For all temperatures in the range of 50K - 300K, the magnetic
profiles for both systems always show a ferromagnetic component at the
interface with a significantly suppressed magnetization that evolves to the
bulk value over a length scale of ~1.6 - 2.4 nm. The LSMO/LMO/STO interface
shows a larger ferromagnetic (FM) moment than the LSMO/STO interface, however
the difference is only substantial at low temperature.Comment: 4 pages, 4 figure
Reduced Dimensionality Effects in Ferromagnetic Behavior in La1-xSrxMnO3
We study the magnetic properties of La1-xSrxMnO3 samples for concentrations x, 0 ≤ x ≤ 0.5. An analysis is done to accurately determine the transition temperature or critical temperature. Magnetic phase diagrams showing the various concentrations at different temperatures will be determined for our thin films. Using the phase diagrams for both bulk and thin film materials can show how reducing the dimensionality from the third dimension to approaching the second-dimension affects the phase diagram
Magnetic Properties of MBE Grown La1/3Y1/3Sr1/3MnO3 Thin Films and Superlattices
We have investigated the magnetic properties of thin films related to the standard CMR system La2/3Sr1/3MnO3 where Y substituted for 50% of the La atoms. These La1/3Y1/3Sr1/3MnO3 films were grown as a random alloy where La, Y, and Sr atoms randomly occupied the A-site or as a superlattice where each unit-cell-thick layer stacked along the crystallographic (001) direction contained only one of the atoms La, Y, and Sr occupying the A-site. One of the key magnetic features of La2/3Sr1/3MnO3 is a prominent ferromagnetic transition near 350 K. We find the substitution of La with Y suppresses this ferromagnetic transition in both the random alloy and the superlattice samples. In the superlattice sample we find a magnetic transition that is coincident with a metal-to-insulator transition we observe in electronic transport. In the random alloy sample, we see a similar magnetic transition but at lower temperatures where we find the sample is too insulating to measure electronic transport. We will compare our measurements on these La1/3Y1/3Sr1/3MnO3 samples with CMR thin films of La2/3Sr1/3MnO3
Suppressed Magnetization at the Surfaces and Interfaces of Ferromagnetic Metallic Manganites
What happens to ferromagnetism at the surfaces and interfaces of manganites?
With the competition between charge, spin, and orbital degrees of freedom, it
is not surprising that the surface behavior may be profoundly different than
that of the bulk. Using a powerful combination of two surface probes, tunneling
and polarized x-ray interactions, this paper reviews our work on the nature of
the electronic and magnetic states at manganite surfaces and interfaces. The
general observation is that ferromagnetism is not the lowest energy state at
the surface or interface, which results in a suppression or even loss of
ferromagnetic order at the surface. Two cases will be discussed ranging from
the surface of the quasi-2D bilayer manganite
(LaSrMnO) to the 3D Perovskite
(LaSrMnO)/SrTiO interface. For the bilayer manganite,
that is, ferromagnetic and conducting in the bulk, these probes present clear
evidence for an intrinsic insulating non-ferromagnetic surface layer atop
adjacent subsurface layers that display the full bulk magnetization. This
abrupt intrinsic magnetic interface is attributed to the weak inter-bilayer
coupling native to these quasi-two-dimensional materials. This is in marked
contrast to the non-layered manganite system
(LaSrMnO/SrTiO), whose magnetization near the interface
is less than half the bulk value at low temperatures and decreases with
increasing temperature at a faster rate than the bulk.Comment: 15 pages, 13 figure
Magnetic Properties of MBE Grown La0.6Sr0.4MnO3 Thin Films
Honorable Mention Winner
This project investigates the magnetic properties of a La1-xSrxMnO3 (x = 0.40) sample of high quality. This sample was grown one atomic layer at a time by Prof. Warusawithana using UNF’s Molecular Beam Epitaxy (MBE) machine. These magnetic properties are investigated over a range of temperatures from 5 to 400 K in fields up to 7 T. We make use of the techniques to analyze the sample to determine to a high degree of precision the critical temperature of the sample, we determined it to be 252 K. We further identified the saturated magnetization, remnant magnetization, and coercive field at 5 K to be 0.00733 emu/g, 0.00563 emu/g and 0.0090 T respectivel
Epitaxially strained [001]-(PbTiO)(PbZrO) superlattice and PbTiO from first principles
The effect of layer-by-layer heterostructuring and epitaxial strain on
lattice instabilities and related ferroelectric properties is investigated from
first principles for the [001]-(PbTiO)(PbZrO) superlattice and
pure PbTiO on a cubic substrate. The results for the superlattice show an
enhancement of the stability of the monoclinic r-phase with respect to pure
PbTiO. Analysis of the lattice instabilities of the relaxed centrosymmetric
reference structure computed within density functional perturbation theory
suggests that this results from the presence of two unstable zone-center modes,
one confined in the PbTiO layer and one in the PbZrO layer, which
produce in-plane and normal components of the polarization, respectively. The
zero-temperature dielectric response is computed and shown to be enhanced not
only near the phase boundaries, but throughout the r-phase. Analysis of the
analogous calculation for pure PbTiO is consistent with this
interpretation, and suggests useful approaches to engineering the dielectric
properties of artificially structured perovskite oxides.Comment: 8 pages, 5 figure
LaAlO3 stoichiometry found key to electron liquid formation at LaAlO3/SrTiO3 interfaces
Emergent phenomena, including superconductivity and magnetism, found in the
two-dimensional electron liquid (2-DEL) at the interface between the insulators
LaAlO3 and SrTiO3 distinguish this rich system from conventional
two-dimensional electron gases at compound semiconductor interfaces. The origin
of this 2-DEL, however, is highly debated with focus on the role of defects in
the SrTiO3 while the LaAlO3 has been assumed perfect. Our experiments and first
principles calculations show that the cation stoichiometry of the nominal
LaAlO3 layer is key to 2-DEL formation: only Al-rich LaAlO3 results in a 2-DEL.
While extrinsic defects including oxygen deficiency are known to render
LaAlO3/SrTiO3 samples conducting, our results show that in the absence of such
extrinsic defects, an interface 2-DEL can form. Its origin is consistent with
an intrinsic electronic reconstruction occurring to counteract a polarization
catastrophe. This work provides a roadmap for identifying other interfaces
where emergent behaviors await discovery
Electrical and magnetic properties of epitaxial (SrMnO3)n/(LaMnO3)2n superlattices
We report the magnetic and transport properties of SrMnO3n / LaMnO32nm superlattices grown
by molecular-beam epitaxy on 100 SrTiO3 with periodicities n=1, 2, 3, 4, 5, 6, 8, and 16.
Although the superlattice constituents, LaMnO3 and SrMnO3, are both antiferromagnetic insulators,
for small n n2 the superlattices behave like the ferromagnetic conductor La0.67Sr0.33MnO3. As
n increases, the magnetic properties become dominated by the LaMnO3 layers, but the electronic
transport properties continue to be controlled by the interfaces
Doping dependent electronic and magnetic ordering in mixed-valent La1-x Srx MnO3thin films
We have investigated the collective electronic and magnetic orderings of a series of La1-x Sr x MnO3 thin films grown epitaxially strained to (001) oriented strontium titanate substrates as a function of doping, x, for 0 = x = 0.4. We find that the ground states of these crystalline thin films are, in general, consistent with that observed in bulk crystals and thin film samples synthesized under a multitude of techniques. Our systematic study, however, reveal subtle features in the temperature dependent electronic transport and magnetization measurements, which presumably arise due to Jahn-Teller type distortions in the lattice for particular doping levels. For the parent compound LaMnO3 (x = 0), we report evidence of a strain-induced ferromagnetic ordering in contrast to the antiferromagnetic ground state found in bulk crystals
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