897 research outputs found
Production and stability of low amount fraction of formaldehyde in hydrogen gas standards
Formaldehyde is an intermediate of the steam methane reforming process for hydrogen production. According to International Standard ISO 14687-2 the amount fraction level of formaldehyde present in hydrogen supplied to fuel cell electric vehicles (FCEV) must not exceed 10 nmol molâ1. The development of formaldehyde standards in hydrogen is crucial to validate the analytical results and ensure measurement reliability for the FCEV industry. NPL demonstrated that these standards can be gravimetrically prepared and validated at 10 ÎŒmol molâ1 with a shelf-life of 8 weeks (stability uncertainty <10%; k = 1), but that formaldehyde degrades into methanol and dimethoxymethane, as measured by FTIR, GC-MS and SIFT-MS. The degradation kinetics is more rapid than predicted by thermodynamics, this may be due to the internal gas cylinder surface acting as a catalyst. The identification of by-products (methanol and dimethoxymethane) requires further investigation to establish any potential undesirable impacts to the FCEV
VERITAS Observations of the gamma-Ray Binary LS I +61 303
LS I +61 303 is one of only a few high-mass X-ray binaries currently detected
at high significance in very high energy gamma-rays. The system was observed
over several orbital cycles (between September 2006 and February 2007) with the
VERITAS array of imaging air-Cherenkov telescopes. A signal of gamma-rays with
energies above 300 GeV is found with a statistical significance of 8.4 standard
deviations. The detected flux is measured to be strongly variable; the maximum
flux is found during most orbital cycles at apastron. The energy spectrum for
the period of maximum emission can be characterized by a power law with a
photon index of Gamma=2.40+-0.16_stat+-0.2_sys and a flux above 300 GeV
corresponding to 15-20% of the flux from the Crab Nebula.Comment: accepted for publication in The Astrophysical Journa
Multiwavelength Observations of LS I +61 303 with VERITAS, Swift and RXTE
We present results from a long-term monitoring campaign on the TeV binary LSI
+61 303 with VERITAS at energies above 500 GeV, and in the 2-10 keV hard X-ray
bands with RXTE and Swift, sampling nine 26.5 day orbital cycles between
September 2006 and February 2008. The binary was observed by VERITAS to be
variable, with all integrated observations resulting in a detection at the 8.8
sigma (2006/2007) and 7.3 sigma (2007/2008) significance level for emission
above 500 GeV. The source was detected during active periods with flux values
ranging from 5 to 20% of the Crab Nebula, varying over the course of a single
orbital cycle. Additionally, the observations conducted in the 2007-2008
observing season show marginal evidence (at the 3.6 sigma significance level)
for TeV emission outside of the apastron passage of the compact object around
the Be star. Contemporaneous hard X-ray observations with RXTE and Swift show
large variability with flux values typically varying between 0.5 and 3.0*10^-11
ergs cm^-2 s^-1 over a single orbital cycle. The contemporaneous X-ray and TeV
data are examined and it is shown that the TeV sampling is not dense enough to
detect a correlation between the two bands.Comment: 30 pages, 5 figures, 2 table, Accepted for publication in The
Astrophysical Journa
VERITAS Observations of the BL Lac Object 1ES 1218+304
The VERITAS collaboration reports the detection of very-high-energy (VHE)
gamma-ray emission from the high-frequency-peaked BL Lac object 1ES 1218+304
located at a redshift of z=0.182. A gamma-ray signal was detected with high
statistical significance for the observations taken during several months in
the 2006-2007 observing season. The photon spectrum between ~160 GeV and ~1.8
TeV is well described by a power law with an index of Gamma = 3.08 +/-
0.34(stat) +/- 0.2(sys). The integral flux above 200 GeV corresponds to ~6% of
that of the Crab Nebula. The light curve does not show any evidence for VHE
flux variability. Using lower limits on the density of the extragalactic
background light (EBL) in the near-IR to mid-IR we are able to limit the range
of intrinsic energy spectra for 1ES 1218+304. We show that the intrinsic photon
spectrum is harder than a power law with an index of Gamma = 2.32 +/- 0.37.
When including constraints from the spectra of 1ES 1101-232 and 1ES 0229+200,
the spectrum of 1ES 1218+304 is likely to be harder than Gamma = 1.86 +/- 0.37.Comment: Submitted to Proceedings of "4th Heidelberg International Symposium
on High Energy Gamma-Ray Astronomy 2008
Status of the VERITAS Observatory
VERITAS, an Imaging Atmospheric Cherenkov Telescope (IACT) system for
gammma-ray astronomy in the GeV-TeV range, has recently completed its first
season of observations with a full array of four telescopes. A number of
astrophysical gamma-ray sources have been detected, both galactic and
extragalactic, including sources previously unknown at TeV energies. We
describe the status of the array and some highlight results, and assess the
technical performance, sensitivity and shower reconstruction capabilities.Comment: Submitted to Proceedings of "4th Heidelberg International Symposium
on High Energy Gamma-Ray Astronomy 2008
VERITAS Upper Limit on the VHE Emission from the Radio Galaxy NGC 1275
The recent detection by the Fermi gamma-ray space telescope of high-energy
gamma-rays from the radio galaxy NGC 1275 makes the observation of the very
high energy (VHE: E > 100 GeV) part of its broadband spectrum particularly
interesting, especially for the understanding of active galactic nuclei (AGN)
with misaligned multi-structured jets. The radio galaxy NGC 1275 was recently
observed by VERITAS at energies above 100 GeV for about 8 hours. No VHE
gamma-ray emission was detected by VERITAS from NGC 1275. A 99% confidence
level upper limit of 2.1% of the Crab Nebula flux level is obtained at the
decorrelation energy of approximately 340 GeV, corresponding to 19% of the
power-law extrapolation of the Fermi Large Area Telescope (LAT) result.Comment: Accepted for publication in ApJ Letter
Effect of early vasopressin vs norepinephrine on kidney failure in patients with septic shock. The VANISH Randomized Clinical Trial
IMPORTANCE: Norepinephrine is currently recommended as the first-line vasopressor in septic shock; however, early vasopressin use has been proposed as an alternative. OBJECTIVE: To compare the effect of early vasopressin vs norepinephrine on kidney failure in patients with septic shock. DESIGN, SETTING, AND PARTICIPANTS: A factorial (2Ă2), double-blind, randomized clinical trial conducted in 18 general adult intensive care units in the United Kingdom between February 2013 and May 2015, enrolling adult patients who had septic shock requiring vasopressors despite fluid resuscitation within a maximum of 6 hours after the onset of shock. INTERVENTIONS: Patients were randomly allocated to vasopressin (titrated up to 0.06 U/min) and hydrocortisone (nâ=â101), vasopressin and placebo (nâ=â104), norepinephrine and hydrocortisone (nâ=â101), or norepinephrine and placebo (nâ=â103). MAIN OUTCOMES AND MEASURES: The primary outcome was kidney failure-free days during the 28-day period after randomization, measured as (1) the proportion of patients who never developed kidney failure and (2) median number of days alive and free of kidney failure for patients who did not survive, who experienced kidney failure, or both. Rates of renal replacement therapy, mortality, and serious adverse events were secondary outcomes. RESULTS: A total of 409 patients (median age, 66 years; men, 58.2%) were included in the study, with a median time to study drug administration of 3.5 hours after diagnosis of shock. The number of survivors who never developed kidney failure was 94 of 165 patients (57.0%) in the vasopressin group and 93 of 157 patients (59.2%) in the norepinephrine group (difference, -2.3% [95% CI, -13.0% to 8.5%]). The median number of kidney failure-free days for patients who did not survive, who experienced kidney failure, or both was 9 days (interquartile range [IQR], 1 to -24) in the vasopressin group and 13 days (IQR, 1 to -25) in the norepinephrine group (difference, -4 days [95% CI, -11 to 5]). There was less use of renal replacement therapy in the vasopressin group than in the norepinephrine group (25.4% for vasopressin vs 35.3% for norepinephrine; difference, -9.9% [95% CI, -19.3% to -0.6%]). There was no significant difference in mortality rates between groups. In total, 22 of 205 patients (10.7%) had a serious adverse event in the vasopressin group vs 17 of 204 patients (8.3%) in the norepinephrine group (difference, 2.5% [95% CI, -3.3% to 8.2%]). CONCLUSIONS AND RELEVANCE: Among adults with septic shock, the early use of vasopressin compared with norepinephrine did not improve the number of kidney failure-free days. Although these findings do not support the use of vasopressin to replace norepinephrine as initial treatment in this situation, the confidence interval included a potential clinically important benefit for vasopressin, and larger trials may be warranted to assess this further. TRIAL REGISTRATION: clinicaltrials.gov Identifier: ISRCTN 20769191
Evidence for long-term Gamma-ray and X-ray variability from the unidentified TeV source HESS J0632+057
HESS J0632+057 is one of only two unidentified very-high-energy gamma-ray
sources which appear to be point-like within experimental resolution. It is
possibly associated with the massive Be star MWC 148 and has been suggested to
resemble known TeV binary systems like LS I +61 303 or LS 5039. HESS J0632+057
was observed by VERITAS for 31 hours in 2006, 2008 and 2009. During these
observations, no significant signal in gamma rays with energies above 1 TeV was
detected from the direction of HESS J0632+057. A flux upper limit corresponding
to 1.1% of the flux of the Crab Nebula has been derived from the VERITAS data.
The non-detection by VERITAS excludes with a probability of 99.993% that HESS
J0632+057 is a steady gamma-ray emitter. Contemporaneous X-ray observations
with Swift XRT reveal a factor of 1.8+-0.4 higher flux in the 1-10 keV range
than earlier X-ray observations of HESS J0632+057. The variability in the
gamma-ray and X-ray fluxes supports interpretation of the ob ject as a
gamma-ray emitting binary.Comment: 8 pages, 3 figures, Accepted for publication in The Astrophysical
Journa
A connection between star formation activity and cosmic rays in the starburst galaxy M 82
Although Galactic cosmic rays (protons and nuclei) are widely believed to be
dominantly accelerated by the winds and supernovae of massive stars, definitive
evidence of this origin remains elusive nearly a century after their discovery
[1]. The active regions of starburst galaxies have exceptionally high rates of
star formation, and their large size, more than 50 times the diameter of
similar Galactic regions, uniquely enables reliable calorimetric measurements
of their potentially high cosmic-ray density [2]. The cosmic rays produced in
the formation, life, and death of their massive stars are expected to
eventually produce diffuse gamma-ray emission via their interactions with
interstellar gas and radiation. M 82, the prototype small starburst galaxy, is
predicted to be the brightest starburst galaxy in gamma rays [3, 4]. Here we
report the detection of >700 GeV gamma rays from M 82. From these data we
determine a cosmic-ray density of 250 eV cm-3 in the starburst core of M 82, or
about 500 times the average Galactic density. This result strongly supports
that cosmic-ray acceleration is tied to star formation activity, and that
supernovae and massive-star winds are the dominant accelerators.Comment: 18 pages, 4 figures; published in Nature; Version is prior to
Nature's in-house style editing (differences are minimal
VERITAS Upper Limit on the VHE Emission from the Radio Galaxy NGC 1275
The recent detection by the Fermi gamma-ray space telescope of high-energy
gamma-rays from the radio galaxy NGC 1275 makes the observation of the very
high energy (VHE: E > 100 GeV) part of its broadband spectrum particularly
interesting, especially for the understanding of active galactic nuclei (AGN)
with misaligned multi-structured jets. The radio galaxy NGC 1275 was recently
observed by VERITAS at energies above 100 GeV for about 8 hours. No VHE
gamma-ray emission was detected by VERITAS from NGC 1275. A 99% confidence
level upper limit of 2.1% of the Crab Nebula flux level is obtained at the
decorrelation energy of approximately 340 GeV, corresponding to 19% of the
power-law extrapolation of the Fermi Large Area Telescope (LAT) result.Comment: Accepted for publication in ApJ Letter
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