12,652 research outputs found
A Multiwavelength View at the Heart of the Superwind in NGC 253
Here we present new optical data from the Hubble Space Telescope of the NGC
253 central region, which reveal numerous discrete sources in a ring--like
structure. This is combined with data at infrared, millimeter, radio and X-ray
wavelengths to examine the nature of these discrete sources and the nucleus
itself. We find that the majority of optical/IR/mm sources are young star
clusters which trace out a ~50 pc ring, that defines the inner edge of a cold
gas torus. This reservoir of cold gas has probably been created by gas inflow
from a larger scale bar and deposited at the inner Lindblad resonance. The
family of compact radio sources lie interior to the starburst ring, and in
general do not have optical or IR counterparts. They are mostly SNRs. The radio
nucleus, which is probably an AGN, lies near the centre of the ring. The X-ray
emission from the nuclear source is extended in the ROSAT HRI detector
indicating that not all of the X-ray emission can be associated with the AGN.
The lack of X-ray variability and the flat radio spectrum of the nucleus,
argues against an ultraluminous SN as the dominant energetic source at the
galaxy core. The diffuse emission associated with the outflowing superwind is
present in the central region on a size scale consistent with the idea of
collimation by the gas torus.Comment: 26 pages, Latex, 6 figures, 4 tables, submitted to MNRA
Laser-induced nucleation promotes crystal growth of anhydrous sodium bromide
We report on a study of crystal hydrate formation in supersaturated aqueous sodium bromide using different methods to induce nucleation: mechanical shock-induced nucleation (MSIN), nucleation by ultrasound (sonocrystallization), non-photochemical laser-induced nucleation (NPLIN) and laser-trapping nucleation. The most stable crystal form at room temperature is known to be sodium bromide dihydrate (DH) and this form was favoured (>95%) through spontaneous nucleation or mechanical shock. Sonocrystallization favoured DH crystals (74%). Remarkably both laser-induced nucleation methods showed a strong preference (>90%) for anhydrous (AH) crystals. The nucleation mechanisms are discussed with reference to the solution–solid phase diagram. For laser-trapping nucleation, the results are consistent with previous studies showing that nucleation is preceded by formation of a localised volume of increased solute concentration. The common mechanistic feature linking sonocrystallization, MSIN and NPLIN is cavitation. The preference for AH sodium bromide suggests that nanosecond laser pulses produce cavitation events with more thermal energy compared to the other methods. The results demonstrate the value of laser-induced nucleation in controlling crystal hydrate growth and provide new understanding of the nucleation mechanisms
Antisolvent addition at extreme conditions
This article describes the use of antisolvent addition at high-pressure to aid precipitation and recovery of high-pressure phases to ambient pressure. Paracetamol (PCM) was used as a model system to demonstrate the principle due to the extensive literature of paracetamol at high-pressure and ambient pressure. We have observed that we are able to recover the orthorhombic form of paracetamol to ambient pressure using this technique, although solvent-mediated transformations are a hurdle. During this investigation we observed a new methanol solvate of paracetamol that is simlar in structure to the known form. The methanol solvate is stable to 0.2 GPa before transformation to the orthorhombic form that is known to be the stable form at high pressure
On the Use of Historical Bathymetric Data to Determine Changes in Bathymetry: An Analysis of Errors and Application to Great Bay Estuary, NH
The depth measurements that are incorporated into bathymetric charts have associated errors with magnitudes depending on the survey circumstances and applied techniques. For this reason, combining and comparing depth measurements collected over many years with different techniques and standards is a difficult task which must be done with great caution. In this study we have developed an approach for comparing historical bathymetric surveys. Our methodology uses Monte Carlo modelling to account for the random error components inherited in the data due to positioning and depth measurement uncertainties
The role of cavitation and gas bubbles in the non-photochemical laser-induced nucleation of sodium acetate
An experimental study of the effects of the sodium salt of poly(methacrylic acid) (Na-PMAA) on non-photochemical laser-induced nucleation (NPLIN) of sodium acetate crystals is presented. Seeding of supersaturated aqueous solutions with anhydrous (AH) seeds always produced trihydrate (TH) crystals, with or without polymer additive. Using NPLIN, with no Na-PMAA and at low Na-PMAA concentrations (0.25% w/w) AH sodium acetate was produced, firstly as plate-like form IV, but subsequently growing needles, likely to be form I. At high Na-PMAA concentrations (0.73% w/w) we observe formation mostly of stable bubbles. In all samples at low laser peak power densities (<26 MW cm−2) we show for the first time using NPLIN that both crystals and bubbles can be nucleated with a single laser pulse. Measurements of the dependence of bubble or crystal count on laser pulse power indicate a common mechanistic origin for nucleation, which is cavitation due to laser heating of impurity nanoparticles. The bubbles observed are attributed to laser heating of the nanoparticles to high temperatures, resulting in gas formed by thermochemical reactions or gas that was previously dissolved in the solution. Our results provide new insight into the particle-heating mechanism for NPLIN, but whether stable bubbles play a defining role in the nucleation of crystals remains to be resolved
Nonphotochemical Laser-Induced Nucleation of Potassium Halides:Effects of Wavelength and Temperature
Non-Abelian Tensor Multiplet Equations from Twistor Space
We establish a Penrose-Ward transform yielding a bijection between
holomorphic principal 2-bundles over a twistor space and non-Abelian self-dual
tensor fields on six-dimensional flat space-time. Extending the twistor space
to supertwistor space, we derive sets of manifestly N=(1,0) and N=(2,0)
supersymmetric non-Abelian constraint equations containing the tensor
multiplet. We also demonstrate how this construction leads to constraint
equations for non-Abelian supersymmetric self-dual strings.Comment: v3: 23 pages, revised version published in Commun. Math. Phy
Role of Impurity Nanoparticles in Laser-Induced Nucleation of Ammonium Chloride
Results
of experiments on laser-induced nucleation (LIN) in supersaturated
(120%) aqueous ammonium chloride
solutions are presented. Measurement of the particle-size distribution
in unfiltered solutions near saturation (95%) indicates a population
of nanometer-scale species with a mean hydrodynamic diameter of 750
nm, which is almost entirely removed by single-pass filtration through
a polyÂ(ether sulfone) membrane (0.2 μm pores). Analysis of filter
residues reveals iron and phosphate as major impurities in the solute.
Experiments show that the number of nuclei induced by LIN can be reduced
substantially by preprocessing (filtering or long-term exposure to
laser pulses) and that this reduction can be reversed by intentional
doping with iron-oxide (Fe<sub>3</sub>O<sub>4</sub>) nanoparticles.
The use of surfactant to assist dispersion of the nanoparticles was
found to increase the number of laser-induced nuclei. We discuss the
results with reference to mechanisms of non-photochemical laser-induced
nucleation
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