Fabrication of a high sensitive Ag-nanoparticle substrate and its application to the detection of toxic substances

Surface Enhanced Raman Scattering (SERS) is typically observed with the substrate in a liquid medium and it has been proposed as a promising technique for detecting low levels of pollutants in liquids. A technique is presented for self-assembly to immobilize Ag nanoparticles (Ag-NPs), with diameters ranging from 100 to 800nm on a solid support. Experimental results have been obtained through experiments using Ag-NPs active substrates to detect Rhodamine 6G (R6G) and crystal violet in the deionized water. Further, the SERS spectrum and Raman spectrum of phoxim were also measured, showing the enhancement in the performance of the active substrate as a result

Statistical study of free magnetic energy and flare productivity of solar active regions

Photospheric vector magnetograms from Helioseismic and Magnetic Imager on board the Solar Dynamic Observatory are utilized as the boundary conditions to extrapolate both non-linear force-free and potential magnetic fields in solar corona. Based on the extrapolations, we are able to determine the free magnetic energy (FME) stored in active regions (ARs). Over 3000 vector magnetograms in 61 ARs were analyzed. We compare FME with ARs' flare index (FI) and find that there is a weak correlation ($<60\%$) between FME and FI. FME shows slightly improved flare predictability relative to total unsigned magnetic flux of ARs in the following two aspects: (1) the flare productivity predicted by FME is higher than that predicted by magnetic flux and (2) the correlation between FI and FME is higher than that between FI and magnetic flux. However, this improvement is not significant enough to make a substantial difference in time-accumulated FI, rather than individual flare, predictions.Comment: The paper was submitted to ApJ and it is accepted no

The optimisation of shot peen forming processes

An optimisation method based on an effective process model is presented. The calibrated and verified process model simulates peening on realistic components and provides a non-linear relationship between peening parameters and deflections. An optimal solution can be found by minimising the deviation of the computed deformed shape from the desired shape subject to certain constraints. This optimal solution of peening parameters can be directly used for practical operations. An optimisation example for forming a cylindrical shape on a 76x76x3 mm sample is provided. The experimental results demonstrate the applicability of the present optimisation method

Breakdown of the classical double copy for the effective action of dilaton-gravity at NNLO

We demonstrate that a recently proposed classical double copy procedure to construct the effective action of two massive particles in dilaton-gravity from the analogous problem of two color charged particles in Yang-Mills gauge theory fails at next-to-next-to-leading orders in the post-Minkowskian (3PM) or post-Newtonian (2PN) expansions

Calculations of microwave brightness temperature of rough soil surfaces: Bare field

A model for simulating the brightness temperatures of soils with rough surfaces is developed. The surface emissivity of the soil media is obtained by the integration of the bistatic scattering coefficients for rough surfaces. The roughness of a soil surface is characterized by two parameters, the surface height standard deviation sigma and its horizontal correlation length l. The model calculations are compared to the measured angular variations of the polarized brightness temperatures at both 1.4 GHz and 5 GHz frequences. A nonlinear least-squares fitting method is used to obtain the values of delta and l that best characterize the surface roughness. The effect of shadowing is incorporated by introducing a function S(theta), which represents the probability that a point on a rough surface is not shadowed by other parts of the surface. The model results for the horizontal polarization are in excellent agreement with the data. However, for the vertical polarization, some discrepancies exist between the calculations and data, particularly at the 1.4 GHz frequency. Possible causes of the discrepancy are discussed

Enhanced Raman Detection System based on a Hollow-core Fiber Probe design

This paper focus on an enhanced Raman-based detection probe and its performance evaluated. The probe employs a hollow-core fiber design to allow liquid micro-sample to be analyzed. The hollow-core fiber is used both to transmit the light signal used to excite the sample and to collect the Raman scattering signal received from the micro-sample under analysis. In order to maximize the performance of the system, various parameters have been studied experimentally, including the diameter and the height of the liquid sample in the probe. The aim has been optimizing both as a means to enhance the Raman scattering signal received from the liquid sample. As a result, a Raman-based detection probe using a reflector approach was developed and evaluated. This design enabling a greater area for interaction with the sample to be formed and to concentrate the excitation light into it. This then increases the efficiency of the light-liquid interaction and improves the collection efficiently of the forward Raman scattering light signal. With the use of this design, the detected Raman scattering signal was increased by a factor of 103~104 over what otherwise would be achieved. A key feature is that with the use of a hollow-core fiber to collect the liquid sample, only a very small volume is needed, making this well suited to practical applications where limited amounts of material are available e.g. biofluids or high value liquids. The system designed and evaluated thus provides the basis of an effective all-fiber Raman-based detection system, capable of being incorporated into portable analysis equipment for rapid detection and in-the-field use