FINITE ELEMENT ANALYSIS OF THE SEISMIC BEHAVIOR OF THE ASSEMBLED LIGHT STEEL FRAME- LIGHT WALL STRUCTURES

In order to meet the needs of the development of low-rise assembly structure in rural areas, a fabricated light-weight steel frame-composite light wall structure is proposed in this paper. The light-weight steel frames are used to bear the vertical loads. The single-row-reinforced recycled concrete wall-boards are used as lateral members to resist most of the horizontal earthquake loads. The wall-board, EPS (Expanded Polystyrene) insulation modules, and fly ash blocks form the thermally insulated wall. Four fabricated lightweight steel frame-composite light wall structures and one light-weight steel frame (FRA) structure were tested under the low cyclic loads. The influence of wall reinforcement spacing and structural form (be it fly ash block or not) on the seismic performance of this new structure was analysed and the damage process of the specimen was simulated using the ABAQUS® software. The results show that the light steel frames and the single-row-reinforced recycled concrete wall-board can work well together. Furthermore, the structure has two clear seismic lines. Due to the use of EPS insulation modules and fly ash blocks, the structure has good anti-seismic and thermal insulation abilities. Reducing the spacing of bars or compositing fly ash blocks can significantly improve the seismic performance of the structure. The finite element method (FEM) calculations agreed well with the experimental results, which validates the proposed model

Particle-Associated Polycyclic Aromatic Hydrocarbons (PAHs) in the Atmosphere of Hefei, China: Levels, Characterizations and Health Risks

Airborne PM2.5 and PM10 samples were collected in summertime (August 2015) and wintertime (December 2015-January 2016) in an industrial complex area in Hefei, China. The average concentrations of PM2.5 and PM10 (90.5 and 114.5 mu g/m(3), respectively) were higher than the regulated levels of China National Ambient Air Quality Standard (grade I) and the WHO Ambient (outdoor) Air Quality and Health Guideline Value. Seasonal variations in PM2.5/PM10 indicated that the secondary sources of particulate matters, formed by gas-to-particle conversion, were enhanced in summer due to longer time of solar radiation and higher temperature. The total concentrations of PM2.5- and PM10-associated PAHs were 5.89 and 17.70 ng/m(3) in summer as well as 63.41 and 78.26 ng/m(3) in winter, respectively. Both PM2.5- and PM10-associated PAHs were dominated by 4- to 6-ring PAHs, suggesting that the fossil fuel combustion and vehicle emissions were the primary sources of PAHs in atmospheric particulate matters in Hefei. The total concentration of PAHs had a slightly higher correlation coefficient with PM2.5 (R = 0.499, P < 0.05) than PM10 (R = 0.431, P > 0.05), indicating the higher association tendency of PAHs with PM2.5. The coefficient of divergence analysis showed that the compositions of PAH were quite different between summer and winter. Total BaP equivalent concentration (BaP-TEQ) for particulate-bound PAHs in winter (58.87 ng/m(3)) was higher than that in summer (5.53 ng/m(3)). In addition, particulate-bound PAHs in winter had an inhalation cancer risk (ICR) value of 2.8 x 10(-3), which was higher than the safe range (10(-4)-10(-6))

Robust Bioinspired MXene–Hemicellulose Composite Films with Excellent Electrical Conductivity for Multifunctional Electrode Applications

MXene-based structural materials with high mechanical robustness and excellent electrical conductivity are highly desirable for multifunctional applications. The incorporation of macromolecular polymers has been verified to be beneficial to alleviate the mechanical brittleness of pristine MXene films. However, the intercalation of a large amount of insulating macromolecules inevitably compromises their electrical conductivity. Inspired by wood, short-chained hemicellulose (xylo-oligosaccharide) acts as a molecular binder to bind adjacent MXene nanosheets together; this work shows that this can significantly enhance the mechanical properties without introducing a large number of insulating phases. As a result, MXene–hemicellulose films can integrate a high electrical conductivity (64,300 S m–1) and a high mechanical strength (125 MPa) simultaneously, making them capable of being high-performance electrode materials for supercapacitors and humidity sensors. This work proposes an alternative method to manufacture robust MXene-based structural materials for multifunctional applications

STUDY ON THE SEISMIC PERFORMANCE OF RECYCLED AGGREGATE CONCRETE-FILLED LIGHTWEIGHT STEEL TUBE FRAME WITH DIFFERENT ASSEMBLY JOINTS

In order to investigate the construction of column-to-beam joints and to understand the effect of recycled aggregate concrete (RAC) and cross-section of beams and columns on the seismic performance of recycled aggregate concrete-filled light steel tubular frame structure, four new types of assembly joints were proposed in this paper. A low cyclic loading test of six frame specimens was carried out. The failure characteristic, load bearing capacity, hysteresis property, ductility, strength and stiffness degradation, and energy dissipation were analysed. The damage process of the specimen was simulated using the ABAQUS software, and the results agreed well with those obtained from the experiments. The results showed that the construction pathway of the joints exhibited significant influence on the seismic performance of the frame. The proposed reinforced joint (using angle steel and stiffeners) significantly improved the bearing capacity, stiffness and energy dissipation capacity of the recycled aggregate concrete-filled steel tube frame. The seismic performance of the steel frame was improved, while the energy dissipation capacity increased by 635.7% using RAC filled in the steel tubes. Finally, by appropriately increasing the size of cross-section on the beams and columns can improve the bearing capacity, stiffness and ductility of the structure

Comparative effects of biochar-nanosheets and conventional organic-amendments on health risks abatement of potentially toxic elements via consumption of wheat grown on industrially contaminated-soil

Potentially toxic elements (PTEs) discharge to the soil environment through increased anthropogenic activities is a global threat. These l'Its can have harmful and chronic-persistent health effects on exposed populations through food consumption grown on contaminated soils. Efforts to investigate the transformation mechanism and accumulation behavior of PTEs in soil-plant system and their adverse health effects have focused extensively in previous studies. However, limited studies address biochar nano sheets (BCNs) as a potential soil amendment to reduced humans health risks through dietary intake of food-crop grown on PTE-contaminated soil. Here, we showed how BCNs cutback health hazards of PTEs through impacts on bioavailability and phytoaccumulation of PTEs, and their daily intake via consumption of wheat. When BCNs amendment was compared with both conventional organic amendments (COAs) and control, it significantly (P <= 0.05) reduced bioavailability and uptake of PTEs by wheat plants. Based on risk assessment results, the hazard indices (HIs) for PTEs in all treatments were <1, however, BCNs addition significantly (P <= 0.05) reduced risk level, when compared to control. Furthermore, the cancer risks for Cd, Cr and Ni over a lifetime of exposure were higher in all treatments than the tolerable limit (1.00E-4 to 1.00E-6), however BCNs addition significantly suppressed cancer risk compared to control. Conclusively, our results suggest that BCNs can be used as soil amendment to reduce potential risks of PTEs through consumption of food grown in PTE-contaminated soils. (C) 2017 Elsevier Ltd. All rights reserved

Combination of oncolytic adenovirus and luteolin exerts synergistic antitumor effects in colorectal cancer cells and a mouse model

In recent years, oncolytic viruses have attracted increasing interest due to their potent antitumor effects. Luteolin, a natural product, has additionally been observed to exhibit various pharmacological antitumor activities. Previously, a novel dual-targeting oncolytic adenovirus, complement decay-accelerating factor (CD55)-tumor necrosis factor ligand superfamily member 10 (TRAIL), was constructed, which exhibited significant growth inhibitory effects in various types of tumor cell. The present study investigated whether the combination of luteolin and CD55-TRAIL was able to exert a synergistic antitumor effect in colorectal carcinoma (CRC) cells. The cytotoxicity and tumor cell apoptosis mediated by combination treatment in CRC cells were detected via an MTT assay, Hoechst staining and western blotting, respectively. Tumor growth in vivo was examined in a CRC mouse xenograft model following various treatments. The results demonstrated that the addition of luteolin enhanced oncolytic adenovirus-mediated enhanced green fluorescent protein, early region 1A and TRAIL expression. The combination of CD55-TRAIL with luteolin synergistically inhibited tumor growth and promoted CRC cellular apoptosis in vitro and in vivo. Additionally, the combination of CD55-TRAIL with luteoli n significa ntly decrea sed cy totoxicit y in lung/bronchial normal epithelial cells, compared with single treatment

A hydrated deep eutectic electrolyte with finely-tuned solvation chemistry for high-performance zinc-ion batteries

Despite their cost-effectiveness and intrinsic safety, aqueous zinc-ion batteries have faced challenges with poor reversibility originating from various active water-induced side reactions. After systematically scrutinizing the effects of water on the evolution of solvation structures, electrolyte properties, and electrochemical performances through experimental and theoretical approaches, a hydrated deep eutectic electrolyte with a water-deficient solvation structure ([Zn(H2O)2(eg)2(otf)2]) and reduced free water content in the bulk solution is proposed in this work. This electrolyte can dramatically suppress water-induced side reactions and provide high Zn2+ mass transfer kinetics, resulting in highly reversible Zn anodes (∼99.6% Coulombic efficiency over 1000 cycles and stable cycling over 4500 h) and high capacity Zn//NVO full cells (436 mA h g−1). This work will aid the understanding of electrolyte solvation structure–electrolyte property–electrochemical performance relationships of aqueous electrolytes in aqueous zinc-ion batteries

Metal–organic frameworks and their derivatives for optimizing lithium metal anodes

Lithium metal anodes (LMAs) have been considered the ultimate anode materials for next-generation batteries. However, the uncontrollable lithium dendrite growth and huge volume expansion that can occur during charge and discharge seriously hinder the practical application of LMAs. Metal–organic framework (MOF) materials, which possess the merits of huge specific surface area, excellent porosity, and flexible composition/structure tunability, have demonstrated great potential for resolving both of these issues. This article first explores the mechanism of lithium dendrite formation as described by four influential models. Subsequently, based on an in-depth understanding of these models, we propose potential strategies for utilizing MOFs and their derivatives to suppress lithium dendrite growth. We then provide a comprehensive review of research progress with respect to various applications of MOFs and their derivatives to suppress lithium dendrites and inhibit volume expansion. The paper closes with a discussion of perspectives on future modifications of MOFs and their derivatives to achieve stable, dendrite-free lithium metal batteries

Trace Amounts of Triple-Functional Additives Enable Reversible Aqueous Zinc-Ion Batteries from a Comprehensive Perspective

Although their cost-effectiveness and intrinsic safety, aqueous zinc-ion batteries suffer from notorious side reactions including hydrogen evolution reaction, Zn corrosion and passivation, and Zn dendrite formation on the anode. Despite numerous strategies to alleviate these side reactions have been demonstrated, they can only provide limited performance improvement from a single aspect. Herein, a triple-functional additive with trace amounts, ammonium hydroxide, was demonstrated to comprehensively protect zinc anodes. The results show that the shift of electrolyte pH from 4.1 to 5.2 lowers the HER potential and encourages the in situ formation of a uniform ZHS-based solid electrolyte interphase on Zn anodes. Moreover, cationic NH4+ can preferentially adsorb on the Zn anode surface to shield the "tip effect" and homogenize the electric field. Benefitting from this comprehensive protection, dendrite-free Zn deposition and highly reversible Zn plating/stripping behaviors were realized. Besides, improved electrochemical performances can also be achieved in Zn//MnO2 full cells by taking the advantages of this triple-functional additive. This work provides a new strategy for stabilizing Zn anodes from a comprehensive perspective

When It's Heavier: Interfacial and Solvation Chemistry of Isotopes in Aqueous Electrolytes for Zn-ion Batteries

The electrochemical effect of isotope (EEI) of water is introduced in the Zn-ion batteries (ZIBs) electrolyte to deal with the challenge of severe side reactions and massive gas production. Due to the low diffusion and strong coordination of ions in D2O, the possibility of side reactions is decreased, resulting in a broader electrochemically stable potential window, less pH change, and less zinc hydroxide sulfate (ZHS) generation during cycling. Moreover, we demonstrate that D2O eliminates the different ZHS phases generated by the change of bound water during cycling because of the consistently low local ion and molecule concentration, resulting in a stable interface between the electrode and electrolyte. The full cells with D2O-based electrolyte demonstrated more stable cycling performance which displayed ∼100 % reversible efficiencies after 1,000 cycles with a wide voltage window of 0.8–2.0 V and 3,000 cycles with a normal voltage window of 0.8–1.9 V at a current density of 2 A g−1